Journal
DATA IN BRIEF
Volume 49, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.dib.2023.109303
Keywords
sII gas hydrates; Methane-propane gas mixture; Thermodynamic hydrate inhibitor; Urea; Phase equilibria; Powder X-ray diffraction
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The equilibrium conditions of sII methane/propane hydrates were experimentally determined for the C3H8/CH4-H2O-urea system. The equilibrium dissociation temperatures and pressures of sII hydrates were measured in a wide range. The effect of urea concentration on sII C3H8/CH4 hydrates was analyzed. The phase composition of the samples was analyzed by powder X-ray diffractometry.
The equilibrium conditions of sII methane/propane hydrates have been experimentally determined for the C3H8/CH4-H2O-urea system. The equilibrium dissociation temperatures and pressures of sII hydrates span a wide P,T-range (266.7-293.9 K; 0.87-9.49 MPa) and were measured by varying the feed mass fraction of urea in solution from 0 to 50 mass%. The experimental points at feed urea concentration <= 40 mass% correspond to the V-L-w-H equilibrium (gas-aqueous urea solution-gas hydrate). A four-phase V-L-w-H-S-u equilibrium (with an additional phase of solid urea) was observed because the solubility limit of urea in water was reached for all points at a feed mass fraction of 50 mass% and for one point at 40 mass% (266.93 K). Gas hydrate equilibria were measured using a high-pressure rig GHA350 under isochoric conditions with rapid fluid stirring and slow ramp heating of 0.1 K/h. Each measured point represents complete dissociation of the sII hydrate. The phase equilibrium data was compared with the literature reported for the C3H8/CH4-H2O and CH4-H2O-urea systems. A comprehensive analysis of the thermodynamic inhibition effect of urea to sII C3H8/CH4 hydrates on pressure and concentration of the inhibitor was carried out. The phase composition of the samples was analyzed by powder X-ray diffractometry at 173 K. (c) 2023TheAuthor(s). Published by Elsevier Inc. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/
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