Journal
ACS MATERIALS LETTERS
Volume 5, Issue 8, Pages 2039-2046Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsmaterialslett.3c00569
Keywords
-
Categories
Ask authors/readers for more resources
Commercial perfluorosulfonic acid polymers undergo nanophase separation, forming proton-conductive channels that result in high conductivity. Researchers have successfully transferred this phase separation behavior to phosphonic acid functionalized ionomers by synthesizing a di-block-co-polymer containing phosphonated polypentafluorostyrene and flexible polyoctylstyrene. The resulting membrane outperforms a phosphonated pentafluorostyrene blend in terms of conductivity and water uptake.
Nanophase separationinto hydrophobic and hydrophilicdomains incommercial perfluorosulfonic acid polymers promotes high conductivityby forming proton-conductive channels within a matrix. To transferthis beneficial phase separation to phosphonic acid functionalizedionomers, we combine phosphonated polypentafluoro-styrene andflexible polyoctylstyrene in a di-block-co-polymer. We introduce astepwise approach, including mesophase simulations, synthesis, andspectroscopic imaging. After the required block lengths were calculated,controlled radical polymerization led to a narrowly distributed block-co-polymer.The respective block-co-polymer membrane outperforms a phosphonatedpentafluorostyrene blend concerning conductivity and water uptake.Stained membrane cross-sections revealed bicontinuous nanophase separationin the 13 to 25 nm range in transmission electron microscopy. Theion-conducting phosphonated polymer block assembled into an isotropic,three-dimensional gyroidal network across the membrane. Our stepwiseapproach is transferable toward other block-co-polymer systems featuringdifferent monomers or functional groups. Applying the proposed principlesallows for the prediction of structure-related phase separation whilereducing the amount of synthesis work.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available