4.7 Article

Temperature and Pressure Sensing Using an Optical Platform Based on Upconversion Luminescence in NaSrY(MoO4)3 Codoped with Er3+ and Yb3+ Nanophosphors

Journal

ACS APPLIED NANO MATERIALS
Volume 6, Issue 20, Pages 19431-19442

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsanm.3c04031

Keywords

optical sensors; light-to-heat conversion; luminescent manometer and thermometer; luminescence intensityratio; thermal coupling level; Stark sublevel

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Highly sensitive Er3+-doped sensor nanophosphors have been developed for temperature and pressure sensing. These materials are based on thermally coupled energy levels and show higher sensitivity compared to traditional materials.
Multifunctional materials are needed for multidimensional stimuli-sensing devices to monitor equipment in complicated working situations. Energy upconverting (UC) nanophosphors doped with rare earth ions are widely studied as materials for optical temperature and pressure sensors working via the control of fluorescence (luminescence) intensity ratio. Nonetheless, most Er3+-doped materials still have limited sensitivity of optical detection. In the present study, we attempted to develop high-sensitivity Er3+-doped sensor nanophosphors based on thermally coupled energy levels & horbar;TCLs (Stark components) for temperature and pressure sensing purposes. On the basis of different pairs of TCLs, especially those from the Stark sublevels of H-2(11/2) and S-4(3/2), the multiple temperature and pressure sensing performances were evaluated. The sensitivities of the pressure and temperature detection modes that are calculated using the selected Stark sublevels are noticeably greater than those based on the traditional TCLs (based on the whole bands). The findings of our study demonstrate a pioneering method for the creation of optically active, multifunctional materials and their integration into optoelectronic devices, specifically for the purpose of serving as remote sensors for low-pressure (vacuum) and -temperature measurements.

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