4.6 Article

Experimental Investigation of Calcium-Doped Zinc Aluminate Nanoparticles as a Promising Material for Microwave Applications

Journal

ACS OMEGA
Volume 8, Issue 41, Pages 38064-38071

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsomega.3c03983

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This article explores the feasibility and performance of Ca-doped ZnAl(2)O(4) ceramic nanoparticles prepared by sol-gel method in the fabrication of microstrip patch antennas (MPAs). The experimental results show that Ca-doped ZnAl(2)O(4) ceramic nanoparticles possess exceptional dielectric characteristics, making them suitable for microwave applications.
Miniaturization of microstrip patch antennas (MPAs) is vital in applications such as wireless networks, mobile devices, global positioning satellites, and upcoming wireless terminals. This miniaturization has led to a demand for new materials with higher permittivity compared to the existing ones. Zinc aluminate (ZnAl2O4) ceramic is an exceptional and versatile material in this context, thanks to its high dielectric permittivity and low tangent loss, making it suitable for microwave applications. This article explores the feasibility of sol-gel-prepared Ca-doped ZnAl(2)O(4)ceramic nanoparticles to be useful in fabricating a MPA. These nanoparticles were examined using X-ray diffraction, which confirmed their polycrystalline structure, and the morphological investigation evidenced the spherical grains having a mean diameter of 16 nm. The dielectric permittivity of the ZnAl2O4Ca nanoparticles is 21.11, with a tangential loss of 0.0247. A prototype MPA made by using Ca-doped ZnAl(2)O(4 )nanoparticles showed a return loss of -20.92 dB at a resonance frequency of 6.8 GHz with a bandwidth of 600 MHz. These results indicate that Ca-doped ZnAl(2)O(4)ceramic nanoparticles possess exceptional dielectric characteristics, which make them a promising candidate for MPA applications.

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