4.8 Article

3D printing thermoplastic polyurethane hierarchical cellular foam with outstanding energy absorption capability

Journal

ADDITIVE MANUFACTURING
Volume 76, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.addma.2023.103770

Keywords

3D printing; Thermoplastic polyurethane; Hierarchical cellular structure; Energy absorption

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This paper combines 3D printing with supercritical CO2 foaming technology to develop a novel strategy for manufacturing lightweight hierarchical structures. By adjusting the printing parameters, the thickness of the shell layer and the size of the core layer's cells can be changed, thereby improving the mechanical properties and energy absorption efficiency of the printed foam, and it has a broad range of applications.
In this paper, 3D printing is combined with supercritical CO2 foaming technology as a novel strategy for the manufacture of thermoplastic polyurethane (TPU) lightweight hierarchical structure, which has the advantages of high specific strength of microcellular foam and free design of 3D printing structure at the same time. More critically, the microstructure of the hierarchical structure presents a shell and core structure similar to the turtle shell, with the thickness of the shell layer and the size of the core layer's cells adjustable with 3D printing parameters, leading to changes in the mechanical properties of the printed foam. In further energy absorption tests, the hierarchical cellular honeycomb with high specific strength exhibits enhanced the specific energy absorption (SEA) by 9.56% compared with the unfoamed honeycomb. In addition, the SEA of TPU hierarchical cellular honeycomb can be adjusted in the range of 0.214-0.377 J/cm3 by changing the printing parameters, with the maximum energy absorption efficiency up to 0.383. Combined with the advantages of 3D printing personalization make the hierarchical cellular foam promising for a broad range of applications in fields such as personal shielding, energy absorption, and transportation.

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