Journal
MOLECULAR CATALYSIS
Volume 549, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.mcat.2023.113424
Keywords
Pincer ruthenium complexes; Catalysis; N-alkylation reactions; Quinolines synthesis; Ruthenium hydride
Categories
Ask authors/readers for more resources
This article describes the synthesis and analysis of NNN-pincer type ruthenium complexes, which were characterized using various spectroscopic techniques and X-ray crystallography. These complexes were also capable of activating C-N bonds in C-N coupling processes. A total of 16 quinolines and 22 N-alkylated substrates were synthesized and characterized using NMR spectroscopy.
Amines, N-heterocyclic compounds, and their derivatives are ubiquitous in all naturally occurring compounds, particularly alkaloids, and are widely used in pharmaceuticals, agrochemicals, lubricants, and surfactants. The design of pincer type ligands and corresponding metal complexes is a fundamental step with a unique reactivity. In this article, the NNN-pincer type of ruthenium complexes were synthesized and analyzed using a variety of spectroscopic techniques, including UV-Visible, infrared, and NMR. The molecular structures of the complexes were examined by X-ray crystallography. These complexes were also employed to activate carbon and nitrogen (C-N bond) bonds in C-N coupling processes. This paper describes the synthetic approach, product purification, and spectroscopic characterization, and nuclear magnetic resonance (NMR) spectroscopy was used to demon-strate the catalytically synthesized substrates. A total number of 16 quinolines and 22 N-alkylated substrates were synthesized and characterized by NMR spectroscopic technique.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available