Journal
MOLECULAR CATALYSIS
Volume 550, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.mcat.2023.113480
Keywords
Donor-acceptor cyclopropanes; Gallium phthalocyanines; Ionic complexes; Aromatic aldehydes; Catalysis; Stereoselectivity
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Cationic gallium phthalocyanine (RPcGa+) catalysts with weakly coordinating anions SbF6- and Sb2F11 -/Sb3F16 - were developed and applied in the catalytic chemistry of donor-acceptor cyclopropanes and related substrates.
Cationic gallium phthalocyanine (RPcGa+) catalysts with SbF6- and Sb2F11 - /Sb3F16 - weakly coordinating anions were developed and used in the catalytic chemistry of donor-acceptor (D-A) cyclopropanes and related substrates. For the first time, these processes were implemented on the examples of [3 + 2]-cycloaddition/annulation reactions of D-A cyclopropanes and styrylmalonates with various aldehydes, as well as some other transformations with different substrates.
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