4.6 Review

Research Progress on the Wear and Corrosion Resistant Plasma Electrolytic Oxidation Composite Coatings on Magnesium and Its Alloys

Related references

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Article Metallurgy & Metallurgical Engineering

In-situ LDHs growth on PEO coatings on AZ31 magnesium alloy for active protection: Roles of PEO composition and conversion solution

Gen Zhang et al.

Summary: In this study, plasma electrolytic oxidation (PEO) coatings on magnesium alloy were produced and followed by hydrothermal treatments to synthesize layered double hydroxides (LDHs) based nanocontainers. The synthesis of LDHs was performed in different growth solutions. The results showed that it was difficult to form LDHs on silicate-based PEO coating, while hydrothermal treatments in Al3+ containing solution played an important role in corrosion resistance for phosphate and silicate-based PEO coatings.

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Incorporation of LDH nanocontainers into plasma electrolytic oxidation coatings on Mg alloy

Yan Li et al.

Summary: This study achieved in-situ incorporation of layered double hydroxides (LDH) nanocontainers into plasma electrolytic oxidation (PEO) coatings on AZ91 Mg alloy. Fumarate was selected as the Mg corrosion inhibitor for exchange and intercalation into the nanocontainers, which were then incorporated into the coating. It was found that the presence of LDH nanocontainers increased the thickness and compactness of the coatings. The corrosion resistance of the coatings was greatly enhanced and stabilized by the loaded inhibitor and nanocontainers through ion-exchange when corrosion occurred.

JOURNAL OF MAGNESIUM AND ALLOYS (2023)

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The corrosion resistance of SiO2-hexadecyltrimethoxysilane hydrophobic coating on AZ91 alloy pretreated by plasma electrolytic oxidation

Tianlu Li et al.

Summary: In this study, a two-step treatment involving SiO2 gel and hexadecyltrimethoxysilane was used to modify PEO coatings on AZ91 alloy. The treatment effectively sealed the microholes in the PEO coating, resulting in a dense coating with improved hydrophobicity. The corrosion resistance of the substrate alloy was significantly enhanced, making it a promising approach for post-treatment of PEO coatings.

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Corrosion resistance and mechanisms of smart micro-arc oxidation/epoxy resin coatings on AZ31 Mg alloy: Strategic positioning of nanocontainers

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Corrosion resistance and anti-soiling performance of micro-arc oxidation/graphene oxide/stearic acid superhydrophobic composite coating on magnesium alloys

Dong Wang et al.

Summary: A micro-arc oxidation/graphene oxide/stearic acid (MAO/GO/SA) superhydrophobic composite coating with superior corrosion resistance was fabricated on a Mg alloy AZ91D using micro-arc oxidation technology, electrodeposition technique, and self-assembly technology. The coating exhibited excellent superhydrophobicity and corrosion resistance.

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Growth behavior and corrosion resistance of graphene oxide/MgAl Layered double hydroxide coating grown on micro-arc oxidation film of magnesium alloys

Yanning Chen et al.

Summary: The MgAl Layered double hydroxides (LDHs)/graphene oxide (GO) composite film was synthesized in situ on the micro-arc oxidation (MAO) film of AZ31 magnesium alloy using hydrothermal chemical conversion method. The growth behavior and corrosion properties of the composite film were investigated. The results showed that the composition and morphology of the composite film changed gradually with the extended hydrothermal treatment time, utilizing the self-dissolved cation in the MAO film as the LDHs source. The MAO/LG-12 h coating exhibited higher corrosion resistance (1.28 x 10-9 A/cm2) compared to the MAO coating (8.49 x 10-6 A/cm2), thanks to the synergistic effect of GO and LDHs.

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A self-healing corrosion protection coating with graphene oxide carrying 8-hydroxyquinoline doped in layered double hydroxide on a micro-arc oxidation coating

Yanning Chen et al.

Summary: In this study, a 8-HQ@GO composite was synthesized and incorporated into LDHs sheets, significantly improving the corrosion resistance of AZ31 alloy. The self-healing performance and anti-corrosion mechanism of the MAO-LDHs/HG coating were discussed, revealing its excellent corrosion resistance properties.

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Active corrosion protection of phosphate loaded PEO/LDHs composite coatings: SIET study

Gen Zhang et al.

Summary: This study produced a MgAl-layered double hydroxide and investigated its self-healing ability in a saline solution.

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Hydrothermal Sealing of Plasma Electrolytic Oxidation Coatings Developed on AZ31 Alloy

L. Toro et al.

Summary: In this study, the corrosion resistance of AZ31 magnesium alloy was improved by post-treating a PEO coating in different solutions. The morphology and chemical composition of the resulting coatings were analyzed, and it was found that pore sealing treatment in a solution containing a mixture of NaF and NaAlO2 significantly increased the corrosion resistance of the coating.

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Development of metal-organic framework (MOF) decorated graphene oxide/MgAl-layered double hydroxide coating via microstructural optimization for anti-corrosion micro-arc oxidation coatings of magnesium alloy

Yanning Chen et al.

Summary: An efficient and simple in-situ growth strategy has been discovered for the preparation of highly reproducible and continuous symbiotic ZIF-8-based anticorrosion coating using graphene oxide/MgAlNO 3 layered double hydroxides buffer layer. The prepared coating exhibits excellent stability and corrosion resistance.

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Corrosion and tribocorrosion resistance of MAO-based composite coating on AZ31 magnesium alloy

Siqin Liu et al.

Summary: In this paper, a multi-functional composite coating with low friction coefficient, high wear resistance, and excellent tribocorrosion resistance is fabricated on AZ31 Mg alloys. The composite coating exhibits better long-term corrosion resistance and wear and tribocorrosion resistance compared to the single micro-arc oxidation (MAO) coating. It can effectively protect the substrate from corrosion under sliding conditions.

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In situ growth of Mg-Zn-Al LDHs by ZIF-8 carrying Zn source and micro-arc oxidation integrated coating for corrosion and protection of magnesium alloys

Yanning Chen et al.

Summary: Preparing effective anti-corrosion coatings is essential for realistic large-scale applications. In this study, ZIF-8 was grown in situ on a pre-prepared MAO coating, and an integrated coating was formed using the Zn source in ZIF-8 and the Mg and Al in the MAO coating. The Mg-Zn-Al/Z LDHs coating was successfully formed by hydrothermal method and exhibited stronger corrosion protection ability compared to the MAO coating.

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Active anticorrosion and self-healing coatings: A review with focus on multi-action smart coating strategies

Inime Ime Udoh et al.

Summary: The development of smart coatings with potential for active anticorrosion and self-healing protection is essential for long-term performance of metallic structures in aggressive chemical environments. Stimuli-responsive functionalities help in controlling corrosion autonomously, enhancing coating life and functionality.

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Anticorrosive lanthanum embedded PEO/GPTMS coating on magnesium alloy by plasma electrolytic oxidation with silanization

Lkhagvaa Telmenbayar et al.

Summary: By adding different concentrations of lanthanum and using a GPTMS layer to modify PEO coatings, the corrosion resistance of the coatings can be significantly improved, reducing porosity and enhancing resistance to corrosive solutions.

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Microstructure and corrosion behavior of PEO-LDHs-SDS superhydrophobic composite film on magnesium alloy

Haiyang Wang et al.

Summary: The research demonstrates that the PEO-LDHs-SDS composite film exhibits excellent short-term and long-term protection performance, which can be attributed to the blocking effect of the super-hydrophobic surface, the sealing effect of LDHs on the micropores of the PEO film, and the readsorption and corrosion inhibition of SDS anions.

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Synergistic effect of graphene oxide/ternary Mg-Al-La layered double hydroxide for dual self-healing corrosion protection of micro-arc oxide coating of magnesium alloy

Yanning Chen et al.

Summary: This study aimed to achieve and improve the dual self-healing and corrosion resistance properties of Micro-arc oxidation (MAO) coatings. By incorporating ternary Mg-Al-La layered double hydroxides (LDHs) and graphene oxide (GO) into the coating, a hybrid coating with excellent anticorrosion ability and self-healing properties was formed. The coating exhibited strong barrier properties from GO and LDHs and was able to self-heal when exposed to corrosion ions, making it an effective corrosion protection material.

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Dual self-healing composite coating on magnesium alloys for corrosion protection

Siqin Liu et al.

Summary: This study developed a new self-healing composite coating for corrosion protection of magnesium alloy, utilizing the dual actions of the corrosion inhibitor M-16 in the MAO coating and PU modified by disulfide bonds. Results demonstrated that the inhibitor embedded in the MAO coating significantly improved the anti-corrosion performance of the scratched coating, while the self-healing PU coating showed excellent recovery capability after heat treatment.

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Improved Corrosion Protection of Magnesium Alloys AZ31B and AZ91 by Cold-Sprayed Aluminum Coatings

R. P. S. Chakradhar et al.

Summary: This study aimed to improve the corrosion resistance of two Mg alloys (AZ31B and AZ91) by using aluminum coatings deposited via a low pressure and temperature cold spray process. The results showed that the corrosion resistance increased with immersion time due to the formation of a protective oxide layer on the surface, making cold-sprayed aluminum coatings a promising candidate for enhancing the corrosion resistance of AZ31B and AZ91 Mg alloys compared to other thermal spray processes.

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Bioactive MAO/CS composite coatings on Mg-Zn-Ca alloy for orthopedic applications

Jinhe Dou et al.

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Enhanced corrosion resistance of magnesium alloy by plasma electrolytic oxidation plus hydrothermal treatment

Jinhe Dou et al.

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Investigation of wear behavior of graphite additive composite coatings deposited by micro arc oxidation-hydrothermal treatment on AZ91 Mg alloy

Ridvan Kucukosman et al.

Summary: Composite coatings were deposited on AZ91 magnesium alloys using MAO and MAO-hydrothermal treatment, improving wear resistance. Addition of graphite increased coating thickness and compactness, leading to relatively homogeneous surface morphologies. The graphite enrichment through HT significantly enhanced the wear resistance of the composite coatings.

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Optimization of Surface Properties of Plasma Electrolytic Oxidation Coating by Organic Additives: A Review

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