4.7 Article

Quantifying the effects of hydrogen concentration and cooling rates on porosity formation in Al-Li alloys

Journal

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
Volume 26, Issue -, Pages 1938-1954

Publisher

ELSEVIER
DOI: 10.1016/j.jmrt.2023.08.017

Keywords

Hydrogen; Porosity; Solidification; Al-Li alloy; Cellular automaton; Tomography; Casting

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This study quantitatively analyzed the porosity morphology in aluminum-lithium alloys using X-CT. A cellular automaton model was employed to predict the porosity distribution, and it was found that the reduction of hydrogen porosity significantly improved the mechanical properties of the vacuum-cast aluminum-lithium alloy.
The addition of Li to Al alloys produces such benefits as a 6% increase of modulus and a 3% weight reduction upon adding 1 wt% Li, and yet it has led to difficulties for manufacturing due to the highly active Li and 25 times equilibrium [H] concentration in the liquid at elevated temperatures. In this study, the 3D porosity morphology was quantified using the X-ray computed tomography (X-CT) from both sand gravity and vacuum castings. A cellular automaton model has been adopted to predict porosity distribution as a function of equilibrium hydrogen concentration and thermal boundary conditions. Combining experimental and simulation results, it was found that the mechanical properties of vacuum casting Al-Li alloy have been improved significantly due to the reduction of hydrogen porosity. The prediction of porosity as a function of hydrogen levels and cooling conditions agrees well with experiments, and porosity has been found to decrease Young's modulus and initiating cracks in Al-Li alloys. & COPY; 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

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