Effect of Mischmetal Addition on Microstructure and Mechanical Properties of As-Cast and As-Rolled Mg-Sn-Ca Alloys

The microstructures and mechanical properties of Mg-3Sn-0.1Ca-xMM (mischmetal, x = 0.3, 0.6, and 0.9 wt.%) alloys were investigated. Optical microscopy (OM), scanning electron microscopy (SEM) and X-ray diffraction spectroscopy (XRD) were used to characterize the microstructures and phase constitutions of the cast and rolled alloys. Room temperature tensile tests were conducted to obtain the mechanical properties and macro-textures to evaluate the texture weakening effect results of the MM. The results show that an abundance of second phase formed, confirmed as the (Ca,MM)MgSn phase, and the volume fraction increased with the increasing MM addition. The tensile yield strength of the as-cast alloys increased with the MM addition, but the elongation decreased. All of the rolled Mg-3Sn-0.1Ca-xMM alloys showed a strong basal texture, and only slightly decreased in intensity after annealing treatment due to the particle-stimulated nucleation of recrystallization. The as-annealed Mg-3Sn-0.1Ca-0.6MM alloys exhibited the highest tensile strengths of 266.5 & PLUSMN; 3.3 MPa and 136.1 & PLUSMN; 3.7 MPa, which are mainly ascribed to grain refinement strengthening, Orowan strengthening and texture strengthening.

Automated summary

The microstructures and mechanical properties of Mg-3Sn-0.1Ca-xMM (mischmetal, x = 0.3, 0.6, and 0.9 wt.%) alloys were investigated. The addition of MM led to the formation of a second phase, resulting in increased tensile yield strength but decreased elongation. The annealed Mg-3Sn-0.1Ca-0.6MM alloy exhibited the highest tensile strengths, mainly attributed to grain refinement, Orowan strengthening, and texture strengthening.