4.8 Article

Ln2F2(OH2)(MoO3)2(SeO3)2: Promising Multifunctional Nonlinear Optical Materials Created by Partial Fluorination Strategy under Corrosion Resistant Supercritical Reactions

Related references

Note: Only part of the references are listed.
Article Chemistry, Multidisciplinary

The Antiperovskite-Type Oxychalcogenides Ae3Q[GeOQ3] (Ae = Ba, Sr; Q = S, Se) with Large Second Harmonic Generation Responses and Wide Band Gaps

Shaoxin Cui et al.

Summary: This study successfully synthesized a series of antiperovskite-type oxychalcogenides with excellent performance. These materials have unique structures that can achieve large SHG response, wide band gap, and suitable birefringence. They provide a new exemplification for the design of high-performance IR NLO materials.

ADVANCED SCIENCE (2023)

Article Chemistry, Multidisciplinary

The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)4

Peng-Fei Li et al.

Summary: A new UV nonlinear optical selenite material, Y3F(SeO3)(4), has been synthesized by fluorination control of the centrosymmetric compounds. It shows excellent comprehensive properties with high SHG intensity, wide band gap, short UV cut-off edge, and high thermal stability.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Article Chemistry, Multidisciplinary

Multi-Stimuli Responsive Luminescence and Domino Phase Transition of Hybrid Copper Halides with Nonlinear Optical Switching Behavior

Jiajing Wu et al.

Summary: Two different phases of organic-inorganic hybrid copper-based halides, alpha- and beta-Gua(3)Cu(2)I(5), were successfully synthesized and demonstrated to possess reversible photoluminescence conversion and nonlinear optical switching properties under external stimulus. The structural phase transition can be triggered not only by heat, but also by crystalline-phase-recognition and mechanical force. These findings are of great significance for the future exploration of multi-responsive phase transition materials.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Article Chemistry, Multidisciplinary

Simple yet extraordinary: Super-polyhedra-built 3D chalcogenide framework of Cs5Ga9S16 with excellent infrared nonlinear optical performance

Hong Chen et al.

Summary: A novel ternary chalcogenide, Cs5Ga9S16, with a wide energy gap (4.05 eV) and sufficient second-harmonic-generation coefficient (0.7 x AgGaS2) has been successfully synthesized. It exhibits favorable phase-matching feature, high laser-induced damage threshold, and a broad transparent region, making it a promising candidate for infrared nonlinear optical materials.

CHINESE CHEMICAL LETTERS (2023)

Article Chemistry, Inorganic & Nuclear

ε-La(IO3)3: A Polar Iodate with High Thermal Stability and a Large Second-Harmonic-Generation Response Obtained by a Supercritical Hydrothermal Method

Dandan Wang et al.

Summary: The synthesis conditions at high temperature and high pressure are favorable for the exploration of new compounds. In this work, a new polar iodate, epsilon-La(IO3)(3), is obtained using a supercritical hydrothermal method. epsilon-La(IO3)(3) possesses high thermal stability and exhibits a wide band gap. Due to its noncentrosymmetric arrangement, epsilon-La(IO3)(3) shows second-harmonic-generation (SHG) response.

INORGANIC CHEMISTRY (2023)

Article Chemistry, Multidisciplinary

Cs3[(BOP)2(B3O7)3]: A Deep-Ultraviolet Nonlinear Optical Crystal Designed by Optimizing Matching of Cation and Anion Groups

Haonan Liu et al.

Summary: We designed a new mixed-coordinated borophosphate crystal, CBPO, which achieves a balance between large second harmonic generation response and large birefringence. CBPO crystal possesses a large SHG response, large birefringence, and stable three-dimensional anion framework. CBPO will be the next generation of DUV NLO crystals.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Article Optics

Achieving the full-wavelength phase-matching for efficient nonlinear optical frequency conversion in C(NH2)3BF4

Miriding Mutailipu et al.

Summary: Researchers propose a full-wavelength phase-matching crystal that can avoid phase-mismatching throughout its entire optical transparency range. The anisotropic bonding strength in the energy dimension is confirmed to be the key to achieve this ability. They demonstrate a guanidinium tetrafluoroborate crystal that can be phase-matched over its entire optical transparency range, generating harmonic light as short as 193.2 nm. This work lays the foundation for finding a new class of crystals with full-wavelength phase-matching and provides a high-performance crystal for generating 266 nm light.

NATURE PHOTONICS (2023)

Article Chemistry, Multidisciplinary

A Rare-Earth Selenite with Unexpectedly Well-Balanced Ultraviolet Nonlinear Optical Functionality, Sc(HSeO3)3

Zhiyong Bai et al.

Summary: Establishing high-performance ultraviolet (UV) nonlinear optical (NLO) selenite crystals with well-balanced properties is challenging due to their strong absorption for UV light. In this study, a rare-earth selenite, Sc(HSeO3)(3), with excellent UV NLO properties is introduced. The crystal exhibits remarkably well-balanced UV-NLO functionality, making it a new example of discovering novel UV NLO selenite materials.

SMALL (2023)

Article Chemistry, Multidisciplinary

Cd2Nb2Te4O15: A Novel Pseudo-Aurivillius-Type Tellurite with Unprecedented Nonlinear Optical Properties and Excellent Stability

Qiang Wang et al.

Summary: Oxides with weak second harmonic generation (SHG) effects are hindering their development as mid-infrared (mid-IR) nonlinear optical (NLO) materials. This study reports on a polar NLO tellurite, CNTO, which exhibits a 31 times larger SHG response compared to the largest reported metal tellurite, KH2PO4. CNTO also possesses a large band gap, wide optical transparency window, superior birefringence, high laser-induced damage threshold, and strong acid and alkali resistance, making it a promising mid-IR NLO material.

SMALL (2023)

Article Chemistry, Multidisciplinary

[K2PbX][Ga7S12] (X = Cl, Br, I): The First Lead-Containing Cationic Moieties with Ultrahigh Second-Harmonic Generation and Band Gaps Exceeding the Criterion of 2.33 eV

Wen-Fa Chen et al.

Summary: Compared with the anionic group theory, it is found that in nonlinear optical materials, second-harmonic generation is mainly caused by anionic groups. Structural regulation of the cationic groups in salt-inclusion chalcogenides is performed to enhance their contribution to the NLO effects. The introduction of stereochemically active lone-electron-pair Pb2+ cation to NLO SICs results in highly oriented frameworks with the largest phase-matching SHG intensities among all SICs.

ADVANCED SCIENCE (2023)

Article Chemistry, Multidisciplinary

Perfectly Encoding π-Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence

Xianghe Meng et al.

Summary: This study successfully characterized a series of rare earth cyanurates crystals and achieved strong SHG response, short UV cutoff, and applicable birefringence by introducing rare earth coordination-controlled anions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Article Materials Science, Multidisciplinary

A survey of stereoactive oxysalts for linear and nonlinear optical applications

Peng-Fei Li et al.

Summary: Stereoactive oxysalts exhibit excellent nonlinear optical properties due to the stereo-chemically active lone pair electrons. This comprehensive review summarizes recent advancements in stereoactive oxysalts, focusing on their structures and linear/nonlinear optical applications. Over a thousand newly reported compounds are surveyed and classified into five categories based on the centered cations. Stereoactive oxysalts are promising candidates for advanced functional materials, and this review provides valuable perspectives for their development. Furthermore, it serves as a comprehensive reference for researchers studying optical properties of stereoactive oxysalts materials.

MATERIALS TODAY PHYSICS (2023)

Article Materials Science, Multidisciplinary

Rb3B11P2O23: Materials Design of a New Chemically Benign Deep-Ultraviolet Nonlinear Optical Material

Haonan Liu et al.

Summary: KBBF is currently the only material capable of producing deep-ultraviolet coherent light, but its rigid growth characteristics and high toxicity make safe growth a major challenge. This study reports a new chemically benign deep-ultraviolet nonlinear optical crystal RBPO, which inherits the structural genes of KBBF and demonstrates comparable optical properties. RBPO can overcome the processing limitations of KBBF and has the potential to become the next generation of deep-ultraviolet nonlinear optical crystals.

ACS MATERIALS LETTERS (2023)

Article Chemistry, Physical

Nonlinear optical properties of a new polar bismuth tellurium oxide fluoride, Bi3F(TeO3)(TeO2F2)3

Jee Yoon Chung et al.

Summary: A novel noncentrosymmetric polar compound Bi3F(TeO3)(TeO2F2)(3) with wide band gap and large SHG counts was synthesized, showing asymmetric geometric features due to polyhedra with lone pair cations. UV-vis spectral data and SHG measurements were used to study the optical properties of the compound.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Chemistry, Physical

Noncentrosymmetric chalcohalide K2Ba3Ge3S9Cl2: A new nonlinear optical material with remarkable laser-induced damage threshold

Wenfeng Zhou et al.

Summary: The newly synthesized chalcohalide K2Ba3Ge3S9Cl2 has a unique structure with a wide band gap and high laser-induced damage threshold, making it a potential excellent nonlinear optical material.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Chemistry, Multidisciplinary

Ultrawide Bandgap and Outstanding Second-Harmonic Generation Response by a Fluorine-Enrichment Strategy at a Transition-Metal Oxyfluoride Nonlinear Optical Material

Tianhui Wu et al.

Summary: This study successfully constructed a non-centrosymmetric nonlinear optical material KNOF, with an extremely high F/O ratio, exhibiting an extremely wide band gap and a strong SHG response, as well as sufficient birefringence for applications. The dominant roles of partially fluorinated and totally fluorinated clusters in achieving an enlarged band gap in KNOF have been clarified by first-principles calculations.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Chemistry, Multidisciplinary

Enhancement of Birefringence in Borophosphate Pushing Phase-Matching into the Short-Wavelength Region

Wenbin Zhang et al.

Summary: Borophosphates are widely studied for their short ultraviolet cutoff edge, but their weak polarizability anisotropy hinders their application in the ultraviolet and deep-UV regions. This study successfully synthesized seven borophosphates with improved birefringence by introducing birefringent functional groups. Among them, Rb3B8PO16 exhibited promising UV non-linear optical properties and KB6PO10(OH)4 showed excellent birefringence in the deep-UV region.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Chemistry, Multidisciplinary

Ln2(SeO3)2(SO4)(H2O)2 (Ln=Sm, Dy, Yb): A Mixed-Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy Properties

Ebube E. Oyeka et al.

Summary: By using mixed-ligand design, we have developed a new chemical pathway for creating lanthanide materials with noncentrosymmetric chiral properties and multiple functionalities, exhibiting excellent performance in terms of optical nonlinearity and magnetic anisotropy.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Chemistry, Multidisciplinary

Hg2(SeO3)(SO4): the first sulfate selenite with large birefringence explored from d10 transition metal compounds

Peng-Fei Li et al.

Summary: In this study, three new birefringent materials were successfully synthesized in the d(10) transition metal sulfate selenite system using mild hydrothermal methods. The structures and properties of these compounds were investigated.

MATERIALS CHEMISTRY FRONTIERS (2022)

Article Chemistry, Physical

Effect of Sm3+ concentration and excitation wavelength on spectroscopic properties of GdPO4:Sm3+ phosphor

G. Ouertani et al.

Summary: Gd(1-x)SmxPO4 ((1, 2, 3 and 5 mol%) nanophosphors were synthesized via combustion route, and their phase structure and morphology were identified using various analysis techniques. The luminescence properties were investigated, showing different emission characteristics depending on the concentration of Sm3+.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Inorganic & Nuclear

Series of Luminescent Lanthanide MOFs with Regular SHG Performance

Yating Wan et al.

Summary: This study synthesized a series of lanthanide metal-organic frameworks with a specific ligand and investigated the interference of the SHG signal. It was found that Ln-MOFs with noncentrosymmetric C2 space group exhibit SHG property, depending on the type of metal atoms, pumping wavelength, and crystal size. The systematic study provides interesting results and enriches the research scope of nonlinear optics and materials science.

INORGANIC CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies

Jin Chen et al.

Summary: SHG causes frequency doubling of light and requires noncentrosymmetry. By assembling polar units in an additive fashion, outstanding SHG performance can be achieved in NCS crystals.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

Article Chemistry, Multidisciplinary

Be2(BO3)(IO3): The First Anion-mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response

Guang Peng et al.

Summary: A new metal borate-iodate NLO crystal, BBIO, was synthesized with strong SHG response and large birefringence. The study also suggests that BBIO may optimize growth habits via van der Waals forces. Opportunities in KBBF structural engineering were demonstrated in this research.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π-Conjugated Phosphate

Jingyu Guo et al.

Summary: This study successfully synthesized two new compounds with large birefringence, especially Sn2PO4I, showing greater birefringence than other borates and phosphates, even surpassing commercial crystals. This breakthrough in inorganic compound birefringence provides a new direction for future exploration of materials with high birefringence.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Giant Second-Harmonic Generation Response and Large Band Gap in the Partially Fluorinated Mid-Infrared Oxide RbTeMo2O8F

Yilei Hu et al.

Summary: This study reports a novel nonlinear optical material RbTeMo2O8F with strong SHG responses and a wide band gap, exhibiting the largest SHG values among all metal tellurites, along with a wide optical transparency window and significant birefringence.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance

Bin-Wen Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses

Youchao Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

Advances in tailoring luminescent rare-earth mixed inorganic materials

Jing Liu et al.

CHEMICAL SOCIETY REVIEWS (2018)

Article Chemistry, Multidisciplinary

Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials

T. Thao Tran et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Finding the Next Deep-Ultraviolet Nonlinear Optical Material: NH4B4O6F

Guoqiang Shi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Materials Science, Multidisciplinary

A new cerium iodate infrared nonlinear optical material with a large second-harmonic generation response

Lei Xiao et al.

JOURNAL OF MATERIALS CHEMISTRY C (2017)

Article Materials Science, Multidisciplinary

Luminescence properties of La2O2S:Tb3+ phosphors and phosphor-embedded polymethylmethacrylate films

Lixi Wang et al.

MATERIALS & DESIGN (2017)

Article Chemistry, Multidisciplinary

BiFSeO3: An Excellent SHG Material Designed by Aliovalent Substitution

Ming-Li Liang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Inorganic & Nuclear

Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites

Su-Yun Zhang et al.

INORGANIC CHEMISTRY (2010)

Article Chemistry, Multidisciplinary

Multicolor tuning of (Ln, P)-Doped YVO4 nanoparticles by single-wavelength excitation

Feng Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Article Chemistry, Inorganic & Nuclear

New luminescent solids in the Ln-W(Mo)-Te-O-(Cl) systems

Hai-Long Jiang et al.

INORGANIC CHEMISTRY (2007)

Article Chemistry, Multidisciplinary

Single-crystal structure validation with the program PLATON

AL Spek

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2003)