Sequential Cyanation of Polythiophenes: Tuning Charge Carrier Polarity in Organic Electrochemical Transistors

Polythiophenes, built on head-to-head (HH) linked 3,3 & PRIME;-oligomer ethylene glycol-2,2 & PRIME;-bithiophene (gT2), have simple chemical structure, good backbone planarity, and relatively high-lying the lowest unoccupied molecular orbital (LUMO) energy levels, hence showing excellent p-type performance in organic electrochemical transistors (OECTs) with & mu;C* of several hundred F cm-1 V-1 s-1. In this study, sequential cyano substitution is utilized to enable transformation of charge carrier polarity from p-type to n-type in OECTs, based on the parent polythiophene g4T2-T2. With the increase of cyano group number, the polythiophenes exhibit gradually lowered LUMO levels from -2.55 to -3.90 eV. As a result, from g4T2-T2 to CNg4T2-CNT2, the p-type performance dramatically diminishes accomplished by the enhancement of n-type one when applied in OECTs. To the authors' delight, polymer CNg4T2-CNT2 with the highest content of cyano groups exhibits a remarkable n-type & mu;C* of 27.01 F cm-1 V-1 s-1 and high gm,norm of 6.75 S cm-1 with negligible p-type character. This study demonstrates that sequential cyano substitution provides a powerful approach for developing high-performance n-type polymers for OECT applications. Combining the synergetic effects of intramolecular noncovalent S & BULL;& BULL;& BULL;O interaction and cyano functionalization, the polymers show significantly decreased p-type performance accompanied by enhanced n-type one from g4T2-T2 to CNg4T2-CNT2 when applied in organic electrochemical transistors (OECTs). Among them, CNg4T2-CNT2 with the highest content of cyano groups exhibits highly promising n-type OECT performance. image

Automated summary

In this study, sequential cyano substitution is used to transform the charge carrier polarity from p-type to n-type in organic electrochemical transistors (OECTs). The polythiophenes exhibit gradually lowered LUMO levels with the increase of cyano group number. Among them, polymer CNg4T2-CNT2 with the highest content of cyano groups shows highly promising n-type OECT performance.