Room-Temperature Electron-Hole Condensation in Direct-Band-Gap Semiconductor Nanocrystals

An electron-hole liquid (EHL) is a collective nonequilibrium macroscopic quantum state of matter arising from the condensation of charge carriers in the form of a droplet. However, achieving the EHL state in a direct-band-gap material at room temperature is extremely difficult due to the excess thermal energy, short carrier lifetime, and low binding energy. Herein, we report the experimental observation of an EHL in a direct-band-gap coupled metal-halide perovskite-nanocrystal film by exploiting the electronphonon interaction at room temperature. The helicity-resolved transient-absorption measurements above a critical carrier density of approximately 1018 cm-3 reveal the EHL below the exciton and biexciton states. These results are consistent with our theoretical calculations of the ground-state energy and the thermodynamic phase diagram. The condensation and evaporation times of the EHL are approximately 0.80 ps and approximately 60 ps, respectively. Our study hopefully paves the way for many-body correlations in optical processes and may offer exceptional opportunities to develop futuristic quantum technologies.

Automated summary

We report the experimental observation of an electron-hole liquid (EHL) in a direct-band-gap perovskite-nanocrystal film at room temperature by exploiting the electron-phonon interaction. The helicity-resolved transient-absorption measurements reveal the EHL below the exciton and biexciton states. The condensation and evaporation times of the EHL are approximately 0.80 ps and approximately 60 ps, respectively. Our study offers opportunities for developing futuristic quantum technologies.