Enhanced Water Absorbency and Water Retention Rate for Superabsorbent Polymer via Porous Calcium Carbonate Crosslinking

To improve the water absorbency and water-retention rate of superabsorbent materials, a porous calcium carbonate composite superabsorbent polymer (PCC/PAA) was prepared by copolymerization of acrylic acid and porous calcium carbonate prepared from ground calcium carbonate. The results showed that the binding energies of C-O and C=O in the O 1s profile of PCC/PAA had 0.2 eV and 0.1-0.7 eV redshifts, respectively, and the bonding of -COO- groups on the surface of the porous calcium carbonate led to an increase in the binding energy of O 1s. Furthermore, the porous calcium carbonate chelates with the -COO- group in acrylic acid through the surface Ca2+ site to form multidirectional crosslinking points, which would increase the flexibility of the crosslinking network and promote the formation of pores inside the PCC/PAA to improve the water storage space. The water absorbency of PCC/PAA with 2 wt% porous calcium carbonate in deionized water and 0.9 wt% NaCl water solution increased from 540 g/g and 60 g/g to 935 g/g and 80 g/g, respectively. In addition, since the chemical crosslinker N,N '-methylene bisacrylamide is used in the polymerization process of PCC/PAA, N,N '-methylene bisacrylamide and porous calcium carbonate enhance the stability of the PCC/PAA crosslinking network by double-crosslinking with a polyacrylic acid chain, resulting in the crosslinking network of PCC/PAA not being destroyed after water absorption saturation. Therefore, PCC/PAA with 2 wt% porous calcium carbonate improved the water-retention rate by 244% after 5 h at 60 degrees C, and the compressive strength was approximately five-times that of the superabsorbent without porous calcium carbonate.

Automated summary

By preparing a porous calcium carbonate composite superabsorbent polymer, the water absorbency and water-retention rate of the superabsorbent material can be improved. The porous calcium carbonate forms multidirectional crosslinking points with the -COO- groups in acrylic acid, increasing the flexibility of the crosslinking network and promoting the formation of internal pores to enhance water storage space. Additionally, the double-crosslinking of the crosslinking agent and porous calcium carbonate enhances the stability of the crosslinking network.