In Situ Growth of CdZnS Nanoparticles@Ti3C2Tx MXene Nanosheet Heterojunctions for Boosted Visible-Light-Driven Photocatalytic Hydrogen Evolution

Using natural light energy to convert water into hydrogen is of great significance to solving energy shortages and environmental pollution. Due to the rapid recombination of photogenerated carriers after separation, the efficiency of photocatalytic hydrogen production using photocatalysts is usually very low. Here, efficient CdZnS nanoparticles@Ti3C2Tx MXene nanosheet heterojunction photocatalysts have been successfully prepared by a facile in situ growth strategy. Since the CdZnS nanoparticles uniformly covered the Ti3C2Tx Mxene nanosheets, the agglomeration phenomenon of CdZnS nanoparticles could be effectively inhibited, accompanied by increased Schottky barrier sites and an enhanced migration rate of photogenerated carriers. The utilization efficiency of light energy can be improved by inhibiting the recombination of photogenerated electron-hole pairs. As a result, under the visible-light-driven photocatalytic experiments, this composite achieved a high hydrogen evolution rate of 47.1 mmol h(-1) g(-1), which is much higher than pristine CdZnS and Mxene. The boosted photocatalytic performances can be attributed to the formed heterojunction of CdZnS nanoparticles and Ti3C2Tx MXene nanosheets, as well as the weakened agglomeration effects.

Automated summary

Using a facile in situ growth strategy, efficient CdZnS nanoparticles@Ti3C2Tx MXene nanosheet heterojunction photocatalysts have been successfully prepared, which effectively inhibits the agglomeration of CdZnS nanoparticles and enhances the migration rate of photogenerated carriers. This composite achieved a high hydrogen evolution rate of 47.1 mmol h(-1) g(-1) under visible-light-driven photocatalytic experiments, surpassing pristine CdZnS and Mxene due to the formed heterojunction and weakened agglomeration effects.