4.8 Article

Polymer-assisted self-assembly of gold nanoparticle monolayers and their dynamical switching

Journal

NANOSCALE
Volume 8, Issue 35, Pages 15864-15869

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6nr05199e

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Funding

  1. UK Engineering and Physical Sciences Research Council [EP/G060649/1, EP/L027151/1]
  2. ERC [LINASS 320503]
  3. Leverhulme Trust
  4. Engineering and Physical Sciences Research Council [EP/G060649/1, EP/L027151/1] Funding Source: researchfish
  5. EPSRC [EP/G060649/1, EP/L027151/1] Funding Source: UKRI

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Dynamic switching of plasmonic monolayers built of gold nanoparticles (AuNPs) is achieved using nano-coatings of poly(isopropyl acrylamide) (PNIPAM). The distance between AuNPs can be dynamically tuned through the repeatable expansion and contraction of the PNIPAM shells at different temperatures, which results in rapid switching of the optical properties of the AuNP monolayer.

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