Related references
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Review
Chemistry, Physical
Meltem Gor Bolen
Summary: The purpose of this review is to summarize the characterization and properties of porous silicon (PS) for hydrogen storage. The study highlights the importance of hydrogen as an intermediate product in silicon porosification technology. It explores the nature of hydrogen bonding in PS and its potential for hydrogen storage, providing valuable insights for understanding and future solutions.
Review
Chemistry, Physical
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Andrey Nikolaev et al.
Summary: This paper studies the possibility of electrochemical purification of PbCl2 from PbO and the effective control of oxide ions concentration in molten PbCl2 at 520°C. Potentiostatic electrolysis was used to remove oxide additions from the melt, and linear and square-wave voltammetry dependencies were recorded. Empirical linear dependencies of the anode peak current on PbO concentration were obtained, which can be used for in-situ control over PbO concentration in the melt. The deep electrochemical purification of PbCl2 melt from molten oxide was achieved.
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Article
Chemistry, Physical
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Summary: The abilities and capacities of silicon and carbon nanocages as battery anodes were studied to propose new nano-compounds for battery electrodes with suitable performance. The electrochemical parameters of carbon and silicon nanocages as battery anodes were examined and compared using computational models. The addition of halogen atoms (F and Cl) to Si-38 and C-38 as battery anodes improved their capacity according to theoretical models. The interaction energies between nanostructures and F and Cl atoms, as well as the interaction energies between nanostructures and Li and Mg, were calculated using theoretical models. Finally, F-Si-38 and Cl-Si-38 nanocages were suggested as suitable nanostructures for utilization as battery electrodes.
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Chemistry, Physical
Savita Rani et al.
Summary: Metallic nanoparticles deposited on semiconductor nanowires, known as heterostructures, enhance optical and optoelectrical characteristics through the interaction between surface plasmons and nanowires. Silicon nanowires (SiNWs) were synthesized using metal-assisted chemical etching and then silver nanoparticles (AgNPs) were deposited on the SiNWs using electroless deposition. The flexibility of the nanowire structures allows for the incorporation of multiple metallic nanoparticles, making them useful for various applications in nanotechnology. The deposition of AgNPs on SiNWs results in improved light absorption, increased surface area, and enhanced charge carrier mobility, making this substrate important for next-generation photovoltaic cells.
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Chemistry, Physical
Nacera Rachedi et al.
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Chemistry, Physical
Timofey Gevel et al.
Summary: This study investigates the kinetics of silicon electrodeposition in the KCl-K2SiF6 molten system and demonstrates that the presence of fluoride ions allows for the required amount of silicon ions. Additionally, silicon electrodeposition is shown to be a reversible 4-electron process.
Article
Electrochemistry
Yu Ustinova et al.
Summary: The possibility of silicon electrodeposition from low-melting LiCl-KCl-CsCl-K2SiF6 electrolytes was studied. The stability of a silicon-containing additive and the rate constant of SiF4 release were found to be temperature dependent. The electrochemical behavior of K2SiF6 in the melts was irreversible and proceeded through a 4-electron reaction. Dendritic silicon deposits were obtained under selected deposition parameters.
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Summary: The study investigates the direct electrochemical reduction of silicon dioxide in molten CaCl2 as an alternative production process of solar silicon, through catalyst-mediated doping. The research demonstrates controllable p-type or n-type doping and a photoresponse of doped silicon under irradiation. The mechanism of catalyst-mediated doping is proposed to elucidate the doping level.
ELECTROCHIMICA ACTA
(2021)
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Summary: The electrodeposition of crystalline Si films on graphite substrates in molten salts was studied, with investigations on factors influencing film properties such as K2SiF6 concentration and current density. The type and characteristics of the deposited Si films were determined by impurities and experimental conditions, showing varying conductivity types under different conditions. The study sheds light on the importance of controlling parameters for electrodeposited Si film properties.
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