Manipulating Molecular Self-Assembly Process at the Solid-Liquid Interface Probed by Scanning Tunneling Microscopy

The phenomenon of ordered self-assembly on solid substrates is a topic of interest in both fundamental surface science research and its applications in nanotechnology. The regulation and control of two-dimensional (2D) self-assembled supra-molecular structures on surfaces have been realized through applying external stimuli. By utilizing scanning tunneling microscopy (STM), researchers can investigate the detailed phase transition process of self-assembled monolayers (SAMs), providing insight into the interplay between intermolecular weak interactions and substrate-molecule interactions, which govern the formation of molecular self-assembly. This review will discuss the structural transition of self-assembly probed by STM in response to external stimuli and provide state-of-the-art methods such as tip-induced confinement for the alignment of SAM domains and selective chirality. Finally, we discuss the challenges and opportunities in the field of self-assembly and STM.

Automated summary

This article discusses the phenomenon of ordered self-assembly on solid substrates, and its importance in both fundamental surface science research and its applications in nanotechnology. By utilizing scanning tunneling microscopy (STM), researchers can investigate the structural transition of self-assembled molecules and provide advanced methods for controlling and regulating self-assembly structures.