Boric Acid as A Low-Temperature Graphitization Aid and Its Impact on Structure and Properties of Cellulose-Based Carbon Fibers

In the present paper, a scalable, economically feasible, and continuous process for making cellulose-based carbon fibers (CFs) is described encompassing precursor spinning, precursor additivation, thermal stabilization, and carbonization. By the use of boric acid (BA) as an additive, the main drawback of cellulose-based CFs, i.e., the low carbon yield, is overcome while maintaining a high level of mechanical properties. This is demonstrated by a systematic comparison between CFs obtained from a BA-doped and an un-doped cellulose precursor within a temperature range for carbonization between 1000 and 2000 degrees C. The changes in chemical composition (via elemental analysis) and physical structure (via X-ray scattering) as well as the mechanical and electrical properties of the resulting CFs were investigated. It turned out that, in contrast to current opinion, the catalytic effect of boron in the formation of graphite-like structures sets in already at 1000 degrees C. It becomes more and more effective with increasing temperature. The catalytic effect of boron significantly affects crystallite sizes (La, Lc), lattice plane spacings (d002), and orientation of the crystallites. Using BA, the carbon yield increased by 71%, Young's modulus by 27%, and conductivity by 168%, reaching 135,000 S/m. At the same time, a moderate decrease in tensile strength by 25% and an increase in density of 14% are observed.

Automated summary

This study presents a scalable, economically feasible, and continuous process for producing cellulose-based carbon fibers (CFs). By adding boric acid as an additive, the low carbon yield of cellulose-based CFs is overcome while maintaining high mechanical properties. The catalytic effect of boron significantly affects the physical and chemical properties of the resulting CFs.