Mechanical Anisotropy of Injection-Molded PP/PS Polymer Blends and Correlation with Morphology

The molecular orientation formed by melt-forming processes depends strongly on the flow direction. Quantifying this anisotropy, which is more pronounced in polymer blends, is important for assessing the mechanical properties of thermoplastic molded products. For injection-molded polymer blends, this study used short-beam shear testing to evaluate the mechanical anisotropy as a stress concentration factor, and clarified the correlation between the evaluation results and the phase structure. Furthermore, because only shear yielding occurs with short-beam shear testing, the yielding conditions related to uniaxial tensile loading were identified by comparing the results with those of three-point bending tests. For continuous-phase PP, the phase structure formed a sea-island structure. The yield condition under uniaxial tensile loading was interface debonding. For continuous-phase PS, the phase structure was dispersed and elongated in the flow direction. The addition of styrene-ethylene-butadiene-styrene (SEBS) altered this structure. The yielding condition under uniaxial tensile loading was shear yielding. The aspect ratio of the dispersed phase was found to correlate with the stress concentration factor. When the PP forming the sea-island structure was of continuous phase, the log-complex law was sufficient to explain the shear yield initiation stress without consideration of the interfacial interaction stress.

Automated summary

The molecular orientation formed during melt-forming processes is strongly influenced by the flow direction. Quantifying this anisotropy, especially in polymer blends, is crucial for evaluating the mechanical properties of thermoplastic molded products. This study used short-beam shear testing to assess mechanical anisotropy as a stress concentration factor and established a correlation between the evaluation results and phase structure. Additionally, the study identified the yielding conditions related to uniaxial tensile loading by comparing the results with those of three-point bending tests.