4.7 Article

Engineering Properties of Novel Vertical Cutoff Wall Backfills Composed of Alkali-Activated Slag, Polymer-Amended Bentonite and Sand

Journal

POLYMERS
Volume 15, Issue 14, Pages -

Publisher

MDPI
DOI: 10.3390/polym15143059

Keywords

vertical cutoff wall backfill; polyacrylamide cellulose; hydraulic conductivity; strength

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This study investigates the engineering properties of a novel vertical cutoff wall backfill composed of reactive magnesia (MgO)-activated ground granulated blast furnace slag (GGBS), sodium-activated calcium bentonite amended with polyacrylamide cellulose (PAC), and clean sand (MSBS-PAC). Compared to backfills composed of MSBS, the MSBS-PAC backfill shows lower pH, dry density, higher void ratio, lower unconfined compressive strength and strain at failure, and lower hydraulic conductivity after 28-day and 90-day curing. The lower hydraulic conductivity of MSBS-PAC backfill is attributed to the improvement of pore structure and pore fluid environment by PAC amendment.
The workability, hydraulic conductivity, and mechanical properties are essential to contaminant containment performance of cementitious backfills in vertical cutoff walls at contaminated sites. This study aims to investigate the engineering properties of a novel vertical cutoff wall backfill composed of reactive magnesia (MgO)-activated ground granulated blast furnace slag (GGBS), sodium-activated calcium bentonite amended with polyacrylamide cellulose (PAC), and clean sand (referred to as MSBS-PAC). Backfills composed of MgO-activated GGBS, sodium-activated calcium bentonite, and clean sand (referred to as MSBS) were also tested for comparison purposes. A series of tests were conducted which included slump test, flexible-wall hydraulic conductivity test, and unconfined compression test. The pore size distributions of two types of backfills were investigated via the nuclear magnetic resonance (NMR) technique. The results showed the moisture content corresponding to the target slump height was higher for MSBS-PAC backfill than that for MSBS backfill. The MSBS-PAC backfill possessed lower pH, dry density, and higher void ratio at different standard curing times as compared to MSBS backfill. The unconfined compressive strength and strain at failure of the MSBS-PAC backfill were noticeable lower than those of the MSBS backfill. In contrast, the hydraulic conductivity of MSBS-PAC backfill was approximately one order of magnitude lower than that of the MSBS backfill, which was less than 10(-9) m/s after 28-day and 90-day curing. Lower hydraulic conductivity of MSBS-PAC backfill was attributed to the improvement of pore structure and pore fluid environment by PAC amendment.

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