☆ 4.7 Review

Nanoengineering Metal-Organic Frameworks and Derivatives for Electrosynthesis of Ammonia

NANO-MICRO LETTERS (2023)

Related references

Note: Only part of the references are listed.

Article Environmental Sciences

Capsulation of red emission chromophore into the CoZn ZIF as nanozymes for on-site visual cascade detection of phosphate ions, o-phenylenediamine, and benzaldehyde

Yaqiong Zhang et al.

Summary: In this study, a paper-based fluorescence-sensing system was proposed to accurately report the levels of multiple pollutants. The system showed great potential for detecting wastewater samples and had practical applications in confocal cell imaging and security inks.

SCIENCE OF THE TOTAL ENVIRONMENT (2023)

Add to Collection

Article Chemistry, Multidisciplinary

Electronic State and Microenvironment Modulation of Metal Nanoparticles Stabilized by MOFs for Boosting Electrocatalytic Nitrogen Reduction

Lulu Wen et al.

Summary: In this study, PdCu nanoparticles were encapsulated into a sulfonate functionalized metal-organic framework, UiO-66-SO3H, and their microenvironment was further modified by coating a hydrophobic polydimethylsiloxane (PDMS) layer. The resulting PdCu@UiO-S@PDMS catalyst exhibited high activity towards electrochemical nitrogen reduction reaction (NRR), surpassing other counterparts. Experimental and theoretical results revealed that the protonated and hydrophobic microenvironment provided protons for NRR and suppressed the competitive hydrogen evolution reaction, while the electron-rich PdCu sites favored the formation of the N2H* intermediate and reduced the energy barrier of NRR, contributing to its excellent performance.

ADVANCED MATERIALS (2023)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Rational Design of High-Flux, Eco-Friendly, and Versatile Superhydrophobic/Superoleophilic PDMS@ZIF-7/Cu3(PO4)2 Mesh with Self-Cleaning Property for Oil-Water Mixture and Emulsion Separation

Xu Xu et al.

Summary: Efficient oil-water separation is increasingly important in environmental treatment. This study presents a novel superhydrophobic/superoleophilic material, PDMS@ZIF-7/Cu3(PO4)2, for gravity-driven separation of oil-water mixture and emulsion. The material demonstrates improved superhydrophobicity, high permeation flux, and self-cleaning property. It shows exceptional separation efficiency and stability in various oil-water mixtures and emulsions, making it promising for cleaning emulsified wastewater.

INORGANIC CHEMISTRY (2023)

Add to Collection

Article Chemistry, Physical

Bismuth stabilized by ZIF derivatives for electrochemical ammonia production: Proton donation effect of phosphorus dopants

Qiaoling Wu et al.

Summary: This study successfully prepares a catalyst with nanoparticles of bismuth embedded in co-doped carbon nanoflakes (Bi/NPC), which exhibits excellent performance in electroreduction reactions with high NH3 yield rate, Faradaic efficiency, and stability. This is attributed to the electrocatalytic activity of bismuth, the inhibition of hydrogen evolution reactions, the enhanced N-2 adsorption and activation facilitated by N-doping, as well as the superior conductivity and large specific surface area of the carbon matrix.

NANO RESEARCH (2023)

Add to Collection

Article Chemistry, Multidisciplinary

Unveiling Hierarchical Dendritic Co3O4-SnO2 Heterostructure for Efficient Water Purification

Linhan Jian et al.

Summary: In this study, a hierarchical dendritic Co3O4-SnO2 heterostructure was prepared via a sequential hydrothermal process for treating refractory organics. The size of the ultrathin SnO2 nanosheets can be controlled by the time of the secondary hydrothermal process. Ti/Co3O4-SnO2-168h showed a photoelectrocatalysis degradation rate of approximately 93.3% for a high dye concentrate, with good long-term cyclability and durability. The proposed type-II heterojunction between Co3O4 and SnO2 prevents carrier recombination and enhances the generation of active species.

NANO LETTERS (2023)

Add to Collection

Article Nanoscience & Nanotechnology

Metal-Free 2D/2D van der Waals Heterojunction Based on Covalent Organic Frameworks for Highly Efficient Solar Energy Catalysis

Ge Yan et al.

Summary: A novel metal-free 2D/2D van der Waals heterojunction was successfully constructed by integrating a two-dimensional COF with ketoenamine linkage and defective hexagonal boron nitride. The presence of VDW heterojunction and introduced defects facilitated charge carriers separation and provided more reactive sites. The resulting heterojunction exhibited excellent solar energy catalytic activity for water splitting, surpassing the performance of pristine COF and other metal-free-based photocatalysts reported to date.

NANO-MICRO LETTERS (2023)

Add to Collection

Article Nanoscience & Nanotechnology

Identification of Dynamic Active Sites Among Cu Species Derived from MOFs@CuPc for Electrocatalytic Nitrate Reduction Reaction to Ammonia

Xue-Yang Ji et al.

Summary: Cu species (single-atom, clusters, and nanoparticles) with tunable loading are successfully prepared on N-doped TiO2/C using MOFs@CuPc precursors. The restructuration behavior among Cu species depends on Cu loading and reaction potential and exhibits an incompletely reversible transformation. Restructured CuN4&Cu-4 show high NH3 yield and selectivity due to optimal adsorption of NO3- and rapid conversion of *NH2OH to *NH2 intermediates.

NANO-MICRO LETTERS (2023)

Add to Collection

Review Nanoscience & Nanotechnology

Applications of Metal-Organic Frameworks and Their Derivatives in Electrochemical CO2 Reduction

Chengbo Li et al.

Summary: Metal-organic frameworks (MOFs) have shown great potential as efficient and selective electrocatalysts for electrochemical CO2 reduction. This review summarizes the recent progress in employing MOFs and their derivatives in CO2RR, focusing on the design strategies for electrocatalysts and electrolyzers, the reaction mechanisms for different CO2RR products, and the electrolyzer configurations. It also offers insights and perspectives for the future development of MOFs in electrochemical CO2 reduction, aiming to guide future research for large-scale applications.

NANO-MICRO LETTERS (2023)

Add to Collection

Article Chemistry, Multidisciplinary

High-efficiency electroreduction of nitrite to ammonia on a Cu@TiO2 nanobelt array

Ling Ouyang et al.

Summary: In this study, a high-efficiency electrocatalyst Cu@TiO2/TP was reported for NO2- reduction to produce high-value ammonia (NH3). The Cu@TiO2/TP catalyst exhibited outstanding catalytic performance in neutral solution, with a high NH3 yield (760.5 mu mol h(-1) cm(-2)) and excellent faradaic efficiency (95.3%). It also demonstrated good electrochemical stability during cyclic tests and long-term electrolysis.

CHEMICAL COMMUNICATIONS (2023)

Add to Collection

Review Engineering, Environmental

Promising energy-storage applications by flotation of graphite ores: A review

Ye Chen et al.

Summary: Graphite-based materials have gained significant attention and rapid development in the ore industry due to their structure and excellent conductivity. However, there is still a lack of a complete industrial chain from raw materials to commercial products. To accelerate the industrialization process, optimizing the beneficiation process is crucial for improving the valuable minerals by addressing the differences in their physical and chemical properties. This review focuses on the standard beneficiation methods and presents a comprehensive flotation process for high-quality graphite flake, and also discusses the energy storage applications of graphite-based materials.

CHEMICAL ENGINEERING JOURNAL (2023)

Add to Collection

Review Chemistry, Analytical

Luminescent Guests Encapsulated in Metal-Organic Frameworks for Portable Fluorescence Sensor and Visual Detection Applications: A Review

Xu Xu et al.

Summary: Metal-organic frameworks (MOFs) have significant structural advantages and are applicable in various fields. They can encapsulate a variety of luminescent guest species, giving them a broader luminescent capability. This review systematically introduces the applications of various LG@MOF sensors in fluorescence detection of ions, biomarkers, pesticides, and preservatives, as well as the development of portable visual fluorescence sensing applications. The challenges and potential for future growth in these sectors are also briefly discussed.

BIOSENSORS-BASEL (2023)

Add to Collection

Article Chemistry, Physical

Efficient and selective electrochemical reduction of nitrate to N2 by relay catalytic effects of Fe-Ni bimetallic sites on MOF-derived structure

Jie Sun et al.

Summary: Selective electrocatalytic conversion of NO3- to N-2 using metal-organic framework-derived electrocatalyst was achieved with high efficiency, meeting drinking water standards. The study elucidated reaction intermediates and mechanistic pathways, highlighting the crucial role of neighboring Fe-Ni catalytic sites in enhancing and selectively catalyzing the reaction.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Add to Collection

Article Chemistry, Multidisciplinary

MOF-Derived Cu3P nanoparticles coated with N-doped carbon for nitrogen fixation

Jian Li et al.

Summary: In this work, Cu3P@NC nanosheets were prepared via low-temperature pyrolysis-phosphating of Cu-MOFs and exhibited high ammonia yield rate and faradaic efficiency in the electrochemical nitrogen reduction reaction. The outstanding performance was attributed to the large electrochemical surface area and the defects induced by N doping.

CHEMICAL COMMUNICATIONS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

A TiO2-x nanobelt array with oxygen vacancies: an efficient electrocatalyst toward nitrite conversion to ammonia

Donglin Zhao et al.

Summary: This study reports that a TiO2-x nanobelt array with oxygen vacancies can convert nitrite into ammonia with high electrocatalytic efficiency and yield in alkaline solution.

CHEMICAL COMMUNICATIONS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Recent advances in electrocatalytic nitrite reduction

Xi Zhang et al.

Summary: This review highlights the recent progress and applications of electrochemical nitrite reduction, including the preparation of gaseous and liquid products, catalyst selection, and understanding of reaction mechanisms. The challenges and opportunities in this field are analyzed as well.

CHEMICAL COMMUNICATIONS (2022)

Add to Collection

Article Engineering, Environmental

MOF-derived Fe2O3@MoS2: An efficient electrocatalyst for ammonia synthesis under mild conditions

Chaoqun Ma et al.

Summary: This study presents a highly efficient electrocatalyst Fe2O3@-MoS2 for electrochemical ammonia synthesis (EAS) at ambient conditions. The Fe2O3@-MoS2 catalyst demonstrates remarkable ammonia yield and high faradaic efficiency, along with superior electrochemical stability. Density functional theory (DFT) calculations reveal that Fe2O3@-MoS2 is capable of activating inert N-2 molecules more effectively than MoS2.

CHEMICAL ENGINEERING JOURNAL (2022)

Add to Collection

Article Chemistry, Physical

Electrochemical Ammonia Synthesis via NO Reduction on 2D-MOF

Bin Huang et al.

Summary: This study systematically explored the application of a two-dimensional metal-organic framework (MOF) as an electrocatalyst for electrocatalytic NO reduction (ENOR) through density functional theory (DFT) calculations. The research found that Co-HAB MOF and Rh-HAB MOF are suitable candidates with good catalytic activity. Additionally, the study discovered that △G(*NO) can be used as a simple descriptor to screen suitable electrocatalysts.

CHEMPHYSCHEM (2022)

Add to Collection

Article Multidisciplinary Sciences

High-ammonia selective metal-organic framework-derived Co-doped Fe/Fe2O3 catalysts for electrochemical nitrate reduction

Shuo Zhang et al.

Summary: Metal-organic framework-derived cobalt-doped Fe@Fe2O3 catalyst shows high efficiency in electrochemical nitrate reduction and ammonia production, providing an important strategy in the design of electrocatalysts.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2022)

Add to Collection

Review Chemistry, Physical

2D Materials Bridging Experiments and Computations for Electro/Photocatalysis

Xu Zhang et al.

Summary: The exploration of catalysts for energy conversion is crucial for sustainable development, with a focus on the unique properties of 2D materials investigated through a combination of experiments and computations. Recent advances have led to the development and design of 2D electro/photocatalysts, bridging the gap between experimental and computational methods. Challenges in computations and experiments for 2D catalysts are also discussed.

ADVANCED ENERGY MATERIALS (2022)

Add to Collection

Article Chemistry, Physical

Achieving high selectivity for nitrate electrochemical reduction to ammonia over MOF-supported RuxOy clusters

Jiangzhou Qin et al.

Summary: Nitrate electroreduction to ammonia is a sustainable alternative strategy for ammonia synthesis and water pollution control. The design of efficient catalysts for selective conversion of nitrate to ammonia is highly needed. In this work, RuxOy clusters stabilized on nickel metal-organic frameworks are reported as catalysts with nearly 100% ammonia selectivity and high yield rates. The theoretical calculations show the potential of this novel strategy for green ammonia synthesis.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Add to Collection

Article Chemistry, Physical

Metal-organic framework supported Au nanoparticles with organosilicone coating for high-efficiency electrocatalytic N2 reduction to NH3

Hongming He et al.

Summary: The researchers have successfully designed a high-efficient electrocatalyst for nitrogen reduction reaction (NRR) that combines metal-organic frameworks (MOF) with Au nanoparticles (NPs), achieving high NH3 yield and Faradaic efficiency in ambient conditions and water medium.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Add to Collection

Article Chemistry, Physical

Metal-organic framework derived carbon-supported bimetallic copper-nickel alloy electrocatalysts for highly selective nitrate reduction to ammonia

Yong Liu et al.

Summary: This study successfully developed efficient catalysts for the reduction of nitrate to ammonia by fabricating a series of CuNi alloy nanoparticles embedded in nitrogen-doped carbon matrix. The catalysts exhibited excellent selectivity and faradaic efficiency, surpassing the performance of monometallic catalysts. The reaction mechanism and key intermediates were revealed through experimental and computational methods. This work provides a new synthetic route for bimetallic catalysts and enhances the understanding of the nitrate to ammonia reaction.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Interfacial Reduction Nucleation of Noble Metal Nanodots on Redox-Active Metal-Organic Frameworks for High-Efficiency Electrocatalytic Conversion of Nitrate to Ammonia

Minghang Jiang et al.

Summary: This study reports the construction of stable and redox-active zirconium metal-organic frameworks (Zr-MOFs) for electrochemically converting nitrate to ammonia. By utilizing the Zr-MOFs as catalysts, noble metal nanodots could be uniformly nucleated, leading to highly efficient electrocatalytic activity. The PdNDs/Zr-MOF catalyst exhibits the highest electrocatalytic activity.

NANO LETTERS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

A hybrid catalyst for efficient electrochemical N2 fixation formed by decorating amorphous MoS3 nanosheets with MIL-101(Fe) nanodots

Wan-Ying Xu et al.

Summary: In this study, a MIL-101(Fe)/MoS3 hybrid catalyst was successfully synthesized and showed excellent electrocatalytic activity and durability for the reduction of N-2 to NH3. The transformation of micro-sized MIL-101(Fe) precursors into ultra-small nanodots and anchoring them on MoS3 resulted in improved exposure of active centers and mass transfer, leading to enhanced catalytic activity and stability.

SCIENCE CHINA-CHEMISTRY (2022)

Add to Collection

Article Chemistry, Physical

Engineering Low-Coordination Single-Atom Cobalt on Graphitic Carbon Nitride Catalyst for Hydrogen Evolution

Xinghui Liu et al.

Summary: In this study, Co-g-C3N4/rGO single-atom catalysts (Co-CNG) were synthesized by coupling suitable single-atom cobalt with a promising substrate of g-C3N4/rGO. The Co-CNG exhibited comparable hydrogen evolution reaction (HER) performance with commercially available Pt/C samples and outperformed non-noble transition-metal catalysts. The presence of Co-N coordination structure was found to be responsible for the enhanced HER performance.

ACS CATALYSIS (2022)

Add to Collection

Article Chemistry, Physical

Overcoming Nitrogen Reduction to Ammonia Detection Challenges: The Case for Leapfrogging to Gas Diffusion Electrode Platforms

Martin Kolen et al.

Summary: This article presents a potential solution to the detection challenges in ammonia production by proposing the use of a gas diffusion electrode (GDE) cell design as a catalyst testing platform. By switching to the GDE cell design, the cost of crucial experiments can be reduced and the loss of NRR selectivity due to the inevitable drop in mass transport at low flow rates can be avoided.

ACS CATALYSIS (2022)

Add to Collection

Review Nanoscience & Nanotechnology

State of the Art and Prospects in Metal-Organic Framework-Derived Microwave Absorption Materials

Shuning Ren et al.

Summary: This review comprehensively discusses the recent research progress on metal-organic framework (MOF)-derived high-performance microwave absorption materials (MAMs), including the categorization, design principles, preparation methods, and the relationship between microwave absorption mechanisms and microstructures of MAMs. The current challenges and future prospects for MOF-derived MAMs are also discussed.

NANO-MICRO LETTERS (2022)

Add to Collection

Article Nanoscience & Nanotechnology

Filling Mesopores of Conductive Metal-Organic Frameworks with Cu Clusters for Selective Nitrate Reduction to Ammonia

Xiaojuan Zhu et al.

Summary: In this study, a metal cluster-conductive metal-organic framework (MOF) composite electrocatalyst Cu@CuHHTP is successfully constructed using an in situ synthetic strategy. Cu@CuHHTP exhibits superb performance for the electrocatalytic nitrate reduction reaction (NO3-RR) with a conversion rate of 85.81% and a selectivity for NH3 of 96.84%.

ACS APPLIED MATERIALS & INTERFACES (2022)

Add to Collection

Article Nanoscience & Nanotechnology

Defective UiO-66-NH2 Functionalized with Stable Superoxide Radicals toward Electrocatalytic Nitrogen Reduction with High Faradaic Efficiency

Xiaobo He et al.

Summary: This study achieved extremely high Faradaic efficiency and a high NH3 production rate by using defective UiO-66-NH2 catalyzed with stable superoxide radicals.

ACS APPLIED MATERIALS & INTERFACES (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Machine Learning for Electrocatalyst and Photocatalyst Design and Discovery

Haoxin Mai et al.

Summary: This article provides a comprehensive introduction and critical review of machine learning techniques used in electrocatalysis and photocatalysis research. It discusses the sources of electro/photocatalyst data, current approaches to representing these materials mathematically, and the most commonly used machine learning methods. The article also evaluates the quality and utility of electro/photocatalyst models and provides illustrations of how machine learning models are applied in novel electro/photocatalyst discovery and to elucidate reaction mechanisms. It serves as a guide for materials scientists in selecting machine learning methods for electrocatalysis and photocatalysis research.

CHEMICAL REVIEWS (2022)

Add to Collection

Editorial Material Chemistry, Physical

A Decade of Electrochemical Ammonia Synthesis

Marta C. Hatzell

ACS ENERGY LETTERS (2022)

Add to Collection

Article Chemistry, Physical

Hydrophobicity modulation on a ferriporphyrin-based metal-organic framework for enhanced ambient electrocatalytic nitrogen fixation

Hongming He et al.

Summary: This study explores a molecular-level post-modification strategy to enhance the performance of electrocatalytic N-2 fixation by introducing alkyl chains of varying lengths in a metal-organic framework. The best results achieved were a Faradaic efficiency of 70.7% and a NO3- yield of 110.9 mu g h(-1) mg(cat).(-1).

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Add to Collection

Article Engineering, Environmental

FeS2/MoS2@RGO hybrid materials derived from polyoxomolybdate-based metal-organic frameworks as high-performance electrocatalyst for ammonia synthesis under ambient conditions

Zemin Feng et al.

Summary: In this work, a one-pot hydrothermal synthesis process was used to successfully synthesize nanostructured bimetallic sulfides with the assistance of an iron-based metal-organic framework and a molybdenum-based polyoxometalate. The synthesized FeS2/MoS2@RGO catalyst showed excellent electrocatalytic activity and stability towards nitrogen reduction reaction in both acidic and alkaline solutions, with high Faradaic efficiency and NH3 yield rate.

CHEMICAL ENGINEERING JOURNAL (2022)

Add to Collection

Article Chemistry, Physical

Nitrite reduction over Ag nanoarray electrocatalyst for ammonia synthesis

Qian Liu et al.

Summary: In this study, an efficient electrocatalyst consisting of Ag nanoarray and NiO nanosheets array on carbon cloth as support was reported for the selective reduction of nitrite to ammonia. The catalyst exhibited high ammonia yield and Faradaic efficiency in alkaline solution.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Add to Collection

Review Nanoscience & Nanotechnology

Metal-Organic Framework Materials for Electrochemical Supercapacitors

Ziwei Cao et al.

Summary: This comprehensive review outlines the synthetic methods and electrochemical performances of metal-organic frameworks (MOFs), as well as their applications in the field of supercapacitors. The review highlights the advantages of MOFs-related materials and discusses the major challenges and opportunities for future research.

NANO-MICRO LETTERS (2022)

Add to Collection

Article Chemistry, Physical

MOF-derived metal sulfides for electrochemical energy applications

Yuxin Shi et al.

Summary: This review summarizes the recent progress in the synthesis, composition, structure, and reaction mechanisms of MOF-derived metal sulfides for batteries, supercapacitors, and electrocatalysis, highlighting their potential in improving catalytic activity and energy storage. The challenges and opportunities for future development in this field are also discussed, aiming to inspire the synthesis of more efficient and durable electrochemical energy storage and conversion systems.

ENERGY STORAGE MATERIALS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Atomically Precise Integration of Multiple Functional Motifs in Catalytic Metal-Organic Frameworks for Highly Efficient Nitrate Electroreduction

Yang Lv et al.

Summary: This study reports a catalytic metal-organic framework catalyst with multiple functional motifs, which can efficiently convert nitrate to ammonia. The catalyst has high-density reactive sites, selective reaction pathways, efficient multielectron transfer, and multiproton transport processes, leading to high yield rate, efficiency, and selectivity for ammonia production.

JACS AU (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Efficient ammonia synthesis via electroreduction of nitrite using single-atom Ru-doped Cu nanowire arrays

Ngoc Quang Tran et al.

Summary: In this study, the electrocatalytic reduction of NO2- ions to NH3 on a single-atom Ru-modified Cu nanowire array on a three-dimensional copper foam was successfully achieved under ambient conditions. The Ru-Cu NW/CF catalyst exhibited high faradaic efficiency and NH3 yield, which was approximately five times higher than that of the Cu NW/CF catalyst.

CHEMICAL COMMUNICATIONS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Advanced Electrocatalysis for Energy and Environmental Sustainability via Water and Nitrogen Reactions

Yi Li et al.

Summary: The passage discusses the importance of clean and efficient energy storage and conversion through sustainable water and nitrogen reactions, emphasizing the crucial role of electrochemical reactions in clean energy technologies and the significance of innovative electrocatalysis in boosting energy conversion efficiency.

ADVANCED MATERIALS (2021)

Add to Collection

Review Engineering, Environmental

Recent advances in non-noble metal electrocatalysts for nitrate reduction

Xi Zhang et al.

Summary: This review highlights the latest research progress in non-noble metal materials for electrochemical nitrate reduction, discussing mechanistic insights and strategies for improving performance.

CHEMICAL ENGINEERING JOURNAL (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Synergy of Bi2O3 and RuO2 Nanocatalysts for Low-Overpotential and Wide pH-Window Electrochemical Ammonia Synthesis

Qiaoling Wu et al.

Summary: In this study, nano-sized RuO2-Bi2O3 particles were synthesized on FEG, showing excellent NRR performance in acidic, neutral, and alkaline electrolytes with high NH3 yield and Faradaic efficiency achieved at low overpotentials. The synergistic effect between Bi2O3 and RuO2, as well as the binder-free characteristic and convenient electron transfer via graphene nanosheets, contribute to the superior NRR performance. This work highlights a new electrocatalyst design strategy that may inspire future development of low-cost and high-performance NRR electrocatalysts.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Add to Collection

Article Chemistry, Applied

Strongly coupled molybdenum phosphide@phosphorus-doped porous carbon derived from MOF used in N2 electroreduction under ambient conditions

Jihai Duan et al.

Summary: The study developed a highly efficient and cost-effective non-precious metal electrocatalyst, MoP@PPC octahedron, synthesized through a metal-organic framework-assisted strategy. The catalyst showed good performance and high ammonia yield rate in nitrogen reduction reaction, attributed to the synergistic effects of P-dopant, porous carbon, and stable MoP nanoparticle.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

Add to Collection

Editorial Material Chemistry, Physical

Electrocatalytic Nitrate Reduction for Sustainable Ammonia Production

Phebe H. van Langevelde et al.

Summary: Phebe van Langevelde, Ioannis Katsounaros, and Marc Koper are renowned researchers in the field of electrocatalysis and renewable energy. Their research interests span from fundamental aspects of electrocatalysis to physical electrochemistry and theoretical electrochemistry. They have received various national and international awards for their contributions to the field.

JOULE (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Identifying the Activity Origin of a Cobalt Single-Atom Catalyst for Hydrogen Evolution Using Supervised Learning

Xinghui Liu et al.

Summary: This study reveals that the activity of graphene-based Co single-atom catalysts towards hydrogen evolution reaction is attributed to their edge sites, and edge-rich Co single atoms were synthesized based on theoretical results. By applying supervised learning techniques, the measured synchrotron spectrum of Co single atoms was interpreted, showing consistent local environments with Athena fitting. Moreover, the edge-rich Co single-atom catalysts exhibit better electrocatalytic performance than commercial Pt/C at high current density, indicating the potential for rational design and structural analysis of nanocatalysts.

ADVANCED FUNCTIONAL MATERIALS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

The Role of Defects in Metal-Organic Frameworks for Nitrogen Reduction Reaction: When Defects Switch to Features

Islam E. Khalil et al.

Summary: The focus of research is on designing efficient electrocatalysts through defect engineering, with metal-organic frameworks (MOFs) and their derivatives gaining interest for providing more active sites to enhance electrochemical reactions. The paper summarizes in situ characterization techniques for defects, common methods for creating defects in MOFs, recent advances in MOF-based electrocatalysts for NRR, and proposes challenges and outlook for defects in MOFs for NRR.

ADVANCED FUNCTIONAL MATERIALS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Electrocatalytic Refinery for Sustainable Production of Fuels and Chemicals

Cheng Tang et al.

Summary: The emerging electrocatalytic refinery (e-refinery) is a more sustainable and environmentally friendly strategy for converting renewable feedstocks and energy sources into transportable fuels and chemicals. Challenges remain in understanding mechanistic aspects and materials design for complex reactions in e-refinery processes.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Single-Atom Catalysts Derived from Metal-Organic Frameworks for Electrochemical Applications

Lianli Zou et al.

Summary: This review summarizes the progress in the synthesis of MOF-derived SACs and their electrochemical applications. The synthetic approaches based on MOFs, characterization techniques for SACs, and their electrochemical applications including ORR, OER, HER, CO2RR, NRR, and other energy-related reactions are discussed. Insights into the current challenges and future prospects of this field are also briefly presented.

SMALL (2021)

Add to Collection

Article Chemistry, Applied

Main group metal elements for ambient-condition electrochemical nitrogen reduction

Ying Sun et al.

Summary: Electrocatalytic N-2 reduction has the potential to reduce greenhouse gas emissions and environmental pollution, but faces challenges in conversion efficiency. Main group metal-based catalysts show promising prospects for ammonia production, but a comprehensive review of their applications in electrochemical ammonia production is still lacking.

JOURNAL OF ENERGY CHEMISTRY (2021)

Add to Collection

Article Multidisciplinary Sciences

Restructuring highly electron-deficient metal-metal oxides for boosting stability in acidic oxygen evolution reaction

Xinghui Liu et al.

Summary: This study successfully enhanced the stability and performance of catalysts in acidic media by introducing electron-deficient metal surfaces, providing a new strategy for the design of other metal-semiconductor nanocatalysts.

NATURE COMMUNICATIONS (2021)

Add to Collection

Article Nanoscience & Nanotechnology

Oxygen Vacancy Engineering of MOF-Derived Zn-Doped Co3O4 Nanopolyhedrons for Enhanced Electrochemical Nitrogen Fixation

Lulu Wen et al.

Summary: Introducing oxygen vacancies is considered an effective method to accelerate the nitrogen reduction reaction, and Zn-Co3O4 nanopolyhedrons with abundant oxygen vacancies and high catalytic performance have been successfully prepared in this study. The catalyst shows high ammonia yield and faradaic efficiency, as well as excellent stability.

ACS APPLIED MATERIALS & INTERFACES (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Designing MOF Nanoarchitectures for Electrochemical Water Splitting

Ben Zhang et al.

Summary: This paper presents the most pivotal advances in engineering MOF nanoarchitectures for efficient electrochemical water splitting. It summarizes the design of catalytic centers for MOF-based/derived electrocatalysts and discusses breakthroughs in catalytic activities, identification of highly active sites, and fundamental mechanisms. Additionally, it provides comprehensive commentary on current primary challenges and future perspectives in water splitting and its commercialization for hydrogen production.

ADVANCED MATERIALS (2021)

Add to Collection

Article Chemistry, Inorganic & Nuclear

In Situ Derived Bi Nanoparticles Confined in Carbon Rods as an Efficient Electrocatalyst for Ambient N2 Reduction to NH3

Fengyi Wang et al.

Summary: This study introduces a high-efficiency electrocatalyst Bi NPs@CRs for artificial NH3 synthesis with high FE and large NH3 yield, as well as high electrochemical durability.

INORGANIC CHEMISTRY (2021)

Add to Collection

Review Chemistry, Physical

Low-dimensional non-metal catalysts: principles for regulating p-orbital-dominated reactivity

Si Zhou et al.

Summary: This review highlights the use of low-dimensional non-metal materials, with p-block elements as active sites, for clean energy production. It discusses the mechanisms and principles for controlling reactivity in different non-metal systems and provides perspectives and challenges for developing high-efficiency non-metal catalysts.

NPJ COMPUTATIONAL MATERIALS (2021)

Add to Collection

Article Chemistry, Physical

Structural Reconstruction of Ce-MOF with Active Sites for Efficient Electrocatalytic N2 Reduction

Peixin Liu et al.

Summary: The study demonstrated the electrochemical synthesis of ammonia using metal-organic frameworks on a copper mesh substrate. The Ce-MOF underwent structural reconstruction at negative potential and formed catalytically active CeO2, providing insights for the rational design of MOF-based electrocatalysts.

ACS APPLIED ENERGY MATERIALS (2021)

Add to Collection

Article Nanoscience & Nanotechnology

Single-Atom Fe-N4 on a Carbon Substrate for Nitrogen Reduction Reaction

Yiwen Liu et al.

Summary: The study reports an Fe-N/C catalyst that can convert nitrogen into ammonia under environmental conditions, improving the activity of electrochemical nitrogen reduction reaction.

ACS APPLIED NANO MATERIALS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Nanoengineering Metal-Organic Framework-Based Materials for Use in Electrochemical CO2 Reduction Reactions

Yingji Zhao et al.

Summary: Using metal-organic frameworks (MOFs) for electrochemical CO2 reduction reaction (CO2RR) processes has attracted considerable research attention due to their atomically dispersed active sites, large surface area, high porosity, controllable morphology, and remarkable tunability. The improvement of conductivity, introduction of active centers, and formation of carbon-based single-atom catalysts (SACs) from well-defined MOFs have been explored for the development of CO2 conversion. The review summarizes the progress on pristine MOFs, MOF hybrids, and MOF-derived carbon-based SACs for the electrocatalytic reduction of CO2, and discusses the limitations and potential improvement directions in this field of research.

SMALL (2021)

Add to Collection

Article Chemistry, Physical

Enhanced electrocatalytic nitrogen reduction reaction performance by interfacial engineering of MOF-based sulfides FeNi2S4/NiS hetero-interface

Peng-Yu Liu et al.

Summary: The study successfully increased the yield and selectivity of NH3 in nitrogen reduction reaction by constructing FeNi2S4/NiS hetero-interface electrocatalysts with unique electronic structures through interface engineering. This research provides a new avenue for electrocatalytic research.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Add to Collection

Article Chemistry, Physical

N, S synergistic effect in hierarchical porous carbon for enhanced NRR performance

Jin Wang et al.

Summary: This paper studied a high-efficiency non-metallic catalyst for the electrocatalytic synthesis of NH3, prepared using a sulfur-modified N-doped MOF, achieving high ammonia yield and optimal efficiency, with excellent long-term durability.

CARBON (2021)

Add to Collection

Article Chemistry, Physical

Model MoS2@ZIF-71 interface acts as a highly active and selective electrocatalyst for catalyzing ammonia synthesis

Jihai Duan et al.

Summary: The study introduces a MoS2@ZIF-71 electrocatalyst that can effectively inhibit the hydrogen evolution reaction and enhance the yield and efficiency of nitrogen reduction reaction, thus promoting the development of electrochemical ammonia under ambient conditions.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2021)

Add to Collection

Article Chemistry, Physical

Carbon nitride-supported CuCeO2 composites derived from bimetal MOF for efficiently electrocatalytic nitrogen fixation

Kang Ye et al.

Summary: This study successfully developed a composite material of CuCeO2@NC with abundant oxygen vacancies, which exhibited outstanding electrocatalytic performance and selectivity for the electrochemical nitrogen fixation in ammonia production.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Add to Collection

Review Nanoscience & Nanotechnology

Recent Advances on MOF Derivatives for Non-Noble Metal Oxygen Electrocatalysts in Zinc-Air Batteries

Yuting Zhu et al.

Summary: MOF-derived non-noble metal-oxygen electrocatalysts play a crucial role in ZABs, and their performance is influenced by material structure. Research in this field mainly focuses on oxygen reduction and oxygen evolution reactions, with evolving catalyst design strategies aiming to enhance performance and address challenges.

NANO-MICRO LETTERS (2021)

Add to Collection

Review Nanoscience & Nanotechnology

Design Engineering, Synthesis Protocols, and Energy Applications of MOF-Derived Electrocatalysts

Amr Radwan et al.

Summary: The significant progress of MOFs-derived electrocatalysts in ORR, OER, and HER applications is mainly attributed to their high-porosity structure, large surface area, and abundant active centers.

NANO-MICRO LETTERS (2021)

Add to Collection

Review Nanoscience & Nanotechnology

Carbon-Based MOF Derivatives: Emerging Efficient Electromagnetic Wave Absorption Agents

Xue Zhang et al.

Summary: Metal-organic framework (MOF) derivatives show great potential in the field of electromagnetic wave (EMW) absorption due to their unique properties, satisfying diverse application requirements. Despite facing challenges, MOF derivatives exhibit outstanding performance in light weight, broad bandwidth, and robust loss capacity, offering possibilities for further research and development.

NANO-MICRO LETTERS (2021)

Add to Collection

Article Chemistry, Applied

Facile synthesis of bimetallic N-doped carbon hybrid material for electrochemical nitrogen reduction

Linchuan Cong et al.

JOURNAL OF ENERGY CHEMISTRY (2021)

Add to Collection

Article Chemistry, Physical

Metal-Organic Frameworks for Electrocatalysis: Catalyst or Precatalyst?

Weiran Zheng et al.

ACS ENERGY LETTERS (2021)

Add to Collection

Article Chemistry, Physical

How Can the Electrode Influence the Formation of the Solid Electrolyte Interface?

Ying Li et al.

Summary: The stable formation of electrode-electrolyte interface (EEI) is crucial for achieving high performance in rechargeable batteries. The choice of electrode material plays a critical role in catalyzing the reduction of electrolyte, which influences the formation of solid electrolyte interface (SEI) and ultimately affects battery performance. Direct and indirect factors on electrodes can influence the catalytic effects on electrolyte reduction, and selective regulations can be achieved through electrode design optimization.

ACS ENERGY LETTERS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Recent advances in electrocatalysis with phthalocyanines

Shaoxuan Yang et al.

Summary: The applications of phthalocyanines (Pcs) in electrocatalysis have attracted attention due to their advantages of low cost, facile synthesis, and good chemical stability. Pcs offer high tailorability and structural diversity, making them promising for optimization in electrochemical devices and for various electrochemical reactions. Further research is needed to explore the structure-composition catalytic activity relationships of different Pc materials for future practical applications.

CHEMICAL SOCIETY REVIEWS (2021)

Add to Collection

Review Nanoscience & Nanotechnology

Composition Optimization and Microstructure Design in MOFs-Derived Magnetic Carbon-Based Microwave Absorbers: A Review

Honghong Zhao et al.

Summary: Magnetic carbon-based composites are ideal for electromagnetic absorption, but their properties are highly dependent on precursors. Therefore, it is necessary to develop methods to effectively regulate the electromagnetic properties of these composites.

NANO-MICRO LETTERS (2021)

Add to Collection

Review Nanoscience & Nanotechnology

Rational Design of MOF-Based Materials for Next-Generation Rechargeable Batteries

Zhengqing Ye et al.

Summary: Metal-organic framework (MOF)-based materials show great potential for next-generation rechargeable batteries due to their high porosity, tunable compositions, diverse structures, and versatile functionalities. MOFs can serve as electrodes, separators, and even electrolytes in various battery systems, highlighting their unique roles in improving electrochemical performance. Controllable synthesis and mechanisms for enhancing electrochemical performance of diverse MOF-based materials are key principles discussed for future battery applications.

NANO-MICRO LETTERS (2021)

Add to Collection

Review Chemistry, Physical

Catalytically active sites of MOF-derived electrocatalysts: synthesis, characterization, theoretical calculations, and functional mechanisms

Zibo Zhai et al.

Summary: This paper reviews the recent progress in MOF-derived electrocatalysts, focusing on the characterization of catalytically active sites, functional mechanisms, and performance validation of various reactions. The synthesis methods, including alloy and composite formation, edge-defect/oxygen vacancy engineering, as well as advanced characterization techniques and theoretical calculations are discussed. The paper also analyzes technical challenges and proposes further research directions for the development of practical MOF-derived electrocatalysts in the future.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Add to Collection

Article Chemistry, Physical

Rigid two-dimensional indium metal-organic frameworks boosting nitrogen electroreduction at all pH values

Yuntong Sun et al.

Summary: With a rigid structure and two-dimensional architecture, the indium metal-organic framework (In-MOF) nanosheets were successfully synthesized for nitrogen electroreduction with excellent activity and stability. These nanosheets exhibit high ammonia yield rates and faradic efficiencies under different pH conditions, making them promising low-cost and efficient electrocatalysts for industrial applications. The reaction mechanism of nitrogen electroreduction was also elucidated, providing valuable insights for the design of all-pH nitrogen reduction electrocatalysts.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Nitrate electroreduction: mechanism insight, in situ characterization, performance evaluation, and challenges

Yuting Wang et al.

Summary: Excessive nitrate ions in the environment pose a significant threat to human health by disrupting the natural nitrogen cycle. Nitrate electroreduction, utilizing green electrons as reductants, shows promise due to its ability to operate under ambient conditions. Understanding the nitrate reaction mechanism is crucial for designing efficient electrocatalysts for selective nitrate reduction.

CHEMICAL SOCIETY REVIEWS (2021)

Add to Collection

Article Materials Science, Multidisciplinary

Ampoule method fabricated sulfur vacancy-rich N-doped ZnS electrodes for ammonia production in alkaline media

Da-Ming Feng et al.

Summary: This study successfully developed an N-doped ZnS electrocatalyst through modulating the surface of the zinc electrode, which showed excellent catalytic activity and selectivity for electrocatalytic nitrogen reduction reaction. The electrocatalyst also exhibited high stability and advanced performance compared to other metal sulfide electrocatalysts.

MATERIALS FOR RENEWABLE AND SUSTAINABLE ENERGY (2021)

Add to Collection

Article Chemistry, Physical

Selective nitrogen reduction to ammonia on iron porphyrin-based single-site metal-organic frameworks

Meiyu Cong et al.

Summary: The study successfully constructed and evaluated single-site metal-organic frameworks as efficient electrocatalysts for N-2 reduction into valuable ammonia, with Fe-TCPP displaying superior performance due to effective N-2 activation at the Fe site. These findings provide insights into designing highly active catalysts for artificial N-2 fixation.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Add to Collection

Article Chemistry, Multidisciplinary

A two-dimensional MXene-supported metal-organic framework for highly selective ambient electrocatalytic nitrogen reduction

Xingyou Liang et al.

Summary: The study successfully prepared a ZIF-67@Ti3C2 catalyst for efficient electrochemical synthesis of ammonia, demonstrating excellent NH3 yield and good Faraday efficiency. The successful preparation of this catalyst expands the application of the MXene family in the electrochemical nitrogen reduction reaction.

NANOSCALE (2021)

Add to Collection

Article Chemistry, Physical

Nitrogen reduction through confined electro-catalysis with carbon nanotube inserted metal-organic frameworks

Yang Lv et al.

Summary: Carbon-based nanomaterials are widely used in electro-catalysis due to their low cost, high conductivity, and stability. A confined electrocatalysis strategy using carbon nanotubes inserted into porous metal-organic frameworks has been developed to enhance the production of ammonia and improve the faradaic efficiency in the electrochemical nitrogen reduction reaction. Among the tested materials, NCNT@MIL-101(Fe) showed the highest activity, while CNT@MIL-101(Fe) achieved the best faradaic efficiency.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Add to Collection

Article Engineering, Environmental

Enhanced reduction of nitrate by noble metal-free electrocatalysis on P doped three-dimensional Co3O4 cathode: Mechanism exploration from both experimental and DFT studies

Jianan Gao et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Add to Collection

Article Chemistry, Physical

Turning Water from a Hindrance to the Promotor of Preferential Electrochemical Nitrogen Reduction

Charlynn Sher Lin Koh et al.

CHEMISTRY OF MATERIALS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Electrocatalysis of N2 to NH3 by HKUST-1 with High NH3 Yield

Yueming Cao et al.

CHEMISTRY-AN ASIAN JOURNAL (2020)

Add to Collection

Article Chemistry, Physical

Boosting Selective Nitrate Electroreduction to Ammonium by Constructing Oxygen Vacancies in TiO2

Ranran Jia et al.

ACS CATALYSIS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

A Generalized Surface Chalcogenation Strategy for Boosting the Electrochemical N2 Fixation of Metal Nanocrystals

Chengyong Yang et al.

ADVANCED MATERIALS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

ZIF-Induced d-Band Modification in a Bimetallic Nanocatalyst: Achieving Over 44 % Efficiency in the Ambient Nitrogen Reduction Reaction

Howard Yi Fan Sim et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Article Chemistry, Physical

Tuning electronic structure of PdZn nanocatalyst via acid-etching strategy for highly selective and stable electrolytic nitrogen fixation under ambient conditions

Min Ma et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

Add to Collection

Article Chemistry, Multidisciplinary

CoS2 Nanoparticles-Embedded N-Doped Carbon Nanobox Derived from ZIF-67 for Electrocatalytic N2-to-NH3 Fixation under Ambient Conditions

Peipei Wei et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Add to Collection

Article Materials Science, Multidisciplinary

NH2-MIL-88B-Fe for electrocatalytic N2 fixation to NH3 with high Faradaic efficiency under ambient conditions in neutral electrolyte

Xuerui Yi et al.

JOURNAL OF MATERIALS SCIENCE (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Efficient Ammonia Electrosynthesis from Nitrate on Strained Ruthenium Nanoclusters

Jie Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Physical

Co3(hexahydroxytriphenylene)2: A conductive metal-organic framework for ambient electrocatalytic N2 reduction to NH3

Wei Xiong et al.

NANO RESEARCH (2020)

Add to Collection

Article Nanoscience & Nanotechnology

Unsaturated p-Metal-Based Metal-Organic Frameworks for Selective Nitrogen Reduction under Ambient Conditions

Yang Fu et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Add to Collection

Article Nanoscience & Nanotechnology

Bismuth-Based Free-Standing Electrodes for Ambient-Condition Ammonia Production in Neutral Media

Ying Sun et al.

NANO-MICRO LETTERS (2020)

Add to Collection

Article Electrochemistry

Metal-Organic-Framework-Derived Cobalt-Doped Carbon Material for Electrochemical Ammonia Synthesis under Ambient Conditions

Anmin Liu et al.

CHEMELECTROCHEM (2020)

Add to Collection

Article Chemistry, Physical

Highly efficient urea-anodizing to promote the electrochemical nitrogen reduction process

Ying Hou et al.

CATALYSIS SCIENCE & TECHNOLOGY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Single-Atom Cu Catalysts for Enhanced Electrocatalytic Nitrate Reduction with Significant Alleviation of Nitrite Production

Tonghe Zhu et al.

SMALL (2020)

Add to Collection

Article Chemistry, Physical

A zero-dimensional nickel, iron-metal-organic framework (MOF) for synergistic N2 electrofixation

Jingjing Duan et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Polyoxometalate-based metal-organic framework-derived bimetallic hybrid materials for upgraded electrochemical reduction of nitrogen

Xinming Wang et al.

GREEN CHEMISTRY (2020)

Add to Collection

Article Chemistry, Physical

Chemically coupled NiCoS/C nanocages as efficient electrocatalysts for nitrogen reduction reactions

Xueke Wu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Add to Collection

Article Chemistry, Physical

An MOF-derived C@NiO@Ni electrocatalyst for N2 conversion to NH3 in alkaline electrolytes

Shijian Luo et al.

SUSTAINABLE ENERGY & FUELS (2020)

Add to Collection

Article Chemistry, Physical

Facile synthesis of a Ru-dispersed N-doped carbon framework catalyst for electrochemical nitrogen reduction

Ziqi Zhang et al.

CATALYSIS SCIENCE & TECHNOLOGY (2020)

Add to Collection

Article Chemistry, Physical

ZIF-supported AuCu nanoalloy for ammonia electrosynthesis from nitrogen and thin air

Xian-Wei Lv et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Add to Collection

Article Chemistry, Physical

Bimetallic Mo-Co nanoparticles anchored on nitrogen-doped carbon for enhanced electrochemical nitrogen fixation

Yizhen Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Add to Collection

Article Nanoscience & Nanotechnology

Surface-defective FeS2 for electrochemical NH3 production under ambient conditions

Daming Feng et al.

NANO MATERIALS SCIENCE (2020)

Add to Collection

Article Chemistry, Physical

Long-term electrocatalytic N2 fixation by MOF-derived Y-stabilized ZrO2: insight into the deactivation mechanism

Shijian Luo et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Add to Collection

Article Chemistry, Physical

Bimetal-MOF nanosheets as efficient bifunctional electrocatalysts for oxygen evolution and nitrogen reduction reaction

Weixin Li et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Add to Collection

Article Chemistry, Physical

Bimetallic metal-organic framework-derived MoFe-PC microspheres for electrocatalytic ammonia synthesis under ambient conditions

Silong Chen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Add to Collection

Article Chemistry, Physical

Atomically Dispersed Single Ni Site Catalysts for Nitrogen Reduction toward Electrochemical Ammonia Synthesis Using N2 and H2O

Shreya Mukherjee et al.

SMALL METHODS (2020)

Add to Collection

Article Nanoscience & Nanotechnology

MOF-Derived Co3O4@NC with Core-Shell Structures for N2 Electrochemical Reduction under Ambient Conditions

Shijian Luo et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Enhanced Electrocatalytic N2 Reduction via Partial Anion Substitution in Titanium Oxide-Carbon Composites

Qing Qin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Physical

Nitrogen-coordinated single Fe sites for efficient electrocatalytic N2 fixation in neutral media

Fang Lu et al.

NANO ENERGY (2019)

Add to Collection

Editorial Material Chemistry, Physical

How to Effectively Utilize MOFs for Electrocatalysis

Song Jin

ACS ENERGY LETTERS (2019)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Metal-organic frameworks (MOFs) and their composites as electrodes for lithium battery applications: Novel means for alternative energy storage

Vishal Shrivastav et al.

COORDINATION CHEMISTRY REVIEWS (2019)

Add to Collection

Article Materials Science, Multidisciplinary

High Faraday efficiency for electrochemical nitrogen reduction reaction on Co@N-doped carbon derived from a metal-organic framework under ambient conditions

Fengxiang Yin et al.

MATERIALS LETTERS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Nanoporous Gold Embedded ZIF Composite for Enhanced Electrochemical Nitrogen Fixation

Yijie Yang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Greatly Improving Electrochemical N2 Reduction over TiO2 Nanoparticles by Iron Doping

Tongwei Wu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Ammonia Synthesis Under Ambient Conditions: Selective Electroreduction of Dinitrogen to Ammonia on Black Phosphorus Nanosheets

Lili Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Physical

Rational Design of Fe-N/C Hybrid for Enhanced Nitrogen Reduction Electrocatalysis under Ambient Conditions in Aqueous Solution

Ying Wang et al.

ACS CATALYSIS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction

Hengcong Tao et al.

CHEM (2019)

Add to Collection

Article Nanoscience & Nanotechnology

Nitrogen (N), Phosphorus (P)-Codoped Porous Carbon as a Metal-Free Electrocatalyst for N2 Reduction under Ambient Conditions

Pengfei Song et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Add to Collection

Article Chemistry, Physical

Efficient Electrocatalytic N2 Fixation with MXene under Ambient Conditions

Yaru Luo et al.

JOULE (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Defect engineering in earth-abundant electrocatalysts for CO2 and N2 reduction

Qichen Wang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

Add to Collection

Article Chemistry, Physical

ZIF-67-Derived Cobalt/Nitrogen-Doped Carbon Composites for Efficient Electrocatalytic N2 Reduction

Yunnan Gao et al.

ACS APPLIED ENERGY MATERIALS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Boosting electrocatalytic nitrogen fixation via energy-efficient anodic oxidation of sodium gluconate

Lu Zhao et al.

CHEMICAL COMMUNICATIONS (2019)

Add to Collection

Article Chemistry, Physical

Electrochemical reduction of N2 to ammonia on Co single atom embedded N-doped porous carbon under ambient conditions

Yanming Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Add to Collection

Article Chemistry, Physical

Single-atom catalysts templated by metal-organic frameworks for electrochemical nitrogen reduction

Rui Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Add to Collection

Review Chemistry, Physical

Challenges and prospects in the catalysis of electroreduction of nitrogen to ammonia

Bryan H. R. Suryanto et al.

NATURE CATALYSIS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Titanium Phosphonate Based Metal-Organic Frameworks with Hierarchical Porosity for Enhanced Photocatalytic Hydrogen Evolution

Hui Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Add to Collection

Review Chemistry, Multidisciplinary

MOF-derived nanohybrids for electrocatalysis and energy storage: current status and perspectives

Hong Zhang et al.

CHEMICAL COMMUNICATIONS (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Magnetic functionalities in MOFs: from the framework to the pore

Guillermo Minguez Espallargas et al.

CHEMICAL SOCIETY REVIEWS (2018)

Add to Collection

Article Materials Science, Multidisciplinary

Recent advances in gas storage and separation using metal-organic frameworks

Hao Li et al.

MATERIALS TODAY (2018)

Add to Collection

Review Multidisciplinary Sciences

Beyond fossil fuel-driven nitrogen transformations

Jingguang G. Chen et al.

SCIENCE (2018)

Add to Collection

Article Chemistry, Physical

Facile Ammonia Synthesis from Electrocatalytic N2 Reduction under Ambient Conditions on N-Doped Porous Carbon

Yanming Liu et al.

ACS Catalysis (2018)

Add to Collection

Article Chemistry, Physical

Metal-organic framework- derived nitrogen-doped highly disordered carbon for electrochemical ammonia synthesis using N2 and H2O in alkaline electrolytes

Shreya Mukherjee et al.

NANO ENERGY (2018)

Add to Collection

Article Multidisciplinary Sciences

Favoring the unfavored: Selective electrochemical nitrogen fixation using a reticular chemistry approach

Hiang Kwee Lee et al.

SCIENCE ADVANCES (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Achieving a Record-High Yield Rate of 120.9 μgNH3 mgcat-1. h-1 for N2 Electrochemical Reduction over Ru Single-Atom Catalysts

Zhigang Geng et al.

ADVANCED MATERIALS (2018)

Add to Collection

Article Chemistry, Physical

Hierarchical Cobalt Phosphide Hollow Nanocages toward Electrocatalytic Ammonia Synthesis under Ambient Pressure and Room Temperature

Wenhan Guo et al.

SMALL METHODS (2018)

Add to Collection

Article Materials Science, Multidisciplinary

Highly efficient metal-organic-framework catalysts for electrochemical synthesis of ammonia from N2 (air) and water at low temperature and ambient pressure

Xinran Zhao et al.

JOURNAL OF MATERIALS SCIENCE (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Challenges in reduction of dinitrogen by proton and electron transfer

Cornelis J. M. van der Ham et al.

CHEMICAL SOCIETY REVIEWS (2014)

Add to Collection

© Peeref 2019-2024. All rights reserved.