Bimetallic Molecular Catalyst Design for Carbon Dioxide Reduction

The core challenge in developing cost-efficient catalysts for carbon dioxide (CO2) conversion mainly lies in controlling its complex reaction pathways. One such strategy exploits bimetallic cooperativity, which relies on the synergistic interaction between two metal centers to activate and convert the CO2 substrate. While this approach has seen an important trend in heterogeneous catalysis as a handle to control stabilities of surface intermediates, it has not often been utilized in molecular and heterogenized molecular catalytic systems. In this review, we gather general principles on how natural CO2 activating enzymes take advantage of bimetallic strategy and how phosphines, cyclams, polypyridyls, porphyrins, and cryptates-based homo- and hetero-bimetallic molecular catalysts can help understand the synergistic effect of two metal centers.

Automated summary

The core challenge of developing cost-efficient catalysts for CO2 conversion lies in controlling its complex reaction pathways. This review gathers general principles on how natural CO2 activating enzymes utilize bimetallic strategy and how various homo- and hetero-bimetallic molecular catalysts can help understand the synergistic effect of two metal centers.