Journal
CHEMPLUSCHEM
Volume -, Issue -, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.202300559
Keywords
carbon dioxide; cyclic carbonates; epoxides; indium catalysts
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This study reports a potential route for synthesizing cyclic carbonates through the coupling reaction of epoxides with carbon dioxide. The researchers discovered that a complex containing indium metal and tert-butyl substituents exhibited the highest catalytic activity and selectivity under solvent-free conditions.
Cyclic carbonates have received significant interests for uses as reagents, solvents, and monomers. The coupling reaction of epoxides with carbon dioxide (CO2) to produce cyclic carbonate is an attractive route which can significantly reduce greenhouse gas emissions and environmental hazards. Herein, a series of five indium chloride complexes supported by inden Schiff-base ligands were reported along with four X-ray crystal structures. The constrained five-membered rings were added to the ligands to enhance the coordination of epoxides to the In metal. From the catalyst screening, In inden complex having tert-butyl substituents and propylene backbone in combination with tetrabutylammonium bromide (TBAB) exhibited the highest catalytic activity (TON up to 1017) for propylene oxide/CO2 coupling reaction with >99 % selectivity for cyclic carbonate under solvent-free conditions. In addition, the catalyst was shown to be active at atmospheric pressure of CO(2 )at room temperature. The catalyst system can be applied to various internal and terminal epoxide substrates to exclusively produce the corresponding cyclic carbonates.
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