4.8 Article

Porous ternary complex metal oxide nanoparticles converted from core/shell nanoparticles

Journal

NANO RESEARCH
Volume 9, Issue 4, Pages 996-1004

Publisher

TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-016-0987-z

Keywords

ternary complex metal oxide; porous; nanoparticle; lithium-ion battery; core/shell nanoparticles

Funding

  1. National Science Foundation Electronic and Photonic Materials [1206425]
  2. Iowa State University
  3. Eastern Scholar Program
  4. Division Of Materials Research
  5. Direct For Mathematical & Physical Scien [1206425] Funding Source: National Science Foundation

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We demonstrate an easy and scalable low-temperature process to convert porous ternary complex metal oxide nanoparticles from solution-synthesized core/shell metal oxide nanoparticles by thermal annealing. The final products demonstrate superior electrochemical properties with a large capacity and high stability during fast charging/discharging cycles for potential applications as advanced lithium-ion battery (LIB) electrode materials. In addition, a new breakdown mechanism was observed on these novel electrode materials.

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