4.8 Article

Achieving excellent bandwidth absorption by a mirror growth process of magnetic porous polyhedron structures

Journal

NANO RESEARCH
Volume 9, Issue 6, Pages 1813-1822

Publisher

TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-016-1074-1

Keywords

symmetrical hexagonal cone structure; Fe2O3/BaCO3; single crystal; porous magnetic absorber; effective frequency bandwidth

Funding

  1. National Natural Science Foundation of China [11575085]
  2. Aeronautics Science Foundation of China [2014ZF52072]
  3. Funding for Outstanding Doctoral Dissertation in NUAA [BCXJ15-09]
  4. Open Research Fund of Jiangsu Provincial Key Laboratory for Nanotechnology of Nanjing University
  5. Priority Academic Program Development of Jiangsu Higher Education Institutions

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A symmetrical Fe2O3/BaCO3 hexagonal cone structure having a height of 10 mu m and an edge length of similar to 4 mu m is reported, obtained using a common solvothermal process and a mirror growth process. Focused ion beam and high-resolution transmission electron microscopy techniques revealed that alpha-Fe2O3 was the single crystal feature present. Ba ions contributed to the formation of symmetrical structures exhibited in the final composites. Subsequently, porous magnetic symmetric hexagonal cone structures were used to study the observed intense electromagnetic wave interference. Electromagnetic absorption performance studies at 2-18 GHz indicated stronger attenuation electromagnetic wave ability as compared to other shapes such as spindles, spheres, cubes, and rods. The maximum absorption frequency bandwidth was at 7.2 GHz with a coating thickness d = 1.5 mm. Special structures and the absence of BaCO3 likely played a vital role in the excellent electromagnetic absorption properties described in this research.

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