4.6 Article

Studying the kinetic parameters of BaTi5O11 by using the thermoluminescence technique

Journal

ARABIAN JOURNAL OF CHEMISTRY
Volume 16, Issue 11, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.arabjc.2023.105247

Keywords

Sol-gel; Thermoluminescence; Dosimetry

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This study investigates the thermoluminescence characteristics of chemically prepared monoclinic barium titanate. The results show that the thermoluminescence glow curve consists of 6 electron traps, with trap depths ranging from 0.94 to 1.40 eV and peak temperatures between 380.4 and 560.5 K. The study confirms the potential of barium titanate for beta dosimetry.
The present study discusses the thermoluminescence (TL) characteristics of monoclinic barium titanate (BaTi5O11) which is chemically prepared using the sol-gel technique. The crystallinity is confirmed by X-ray diffraction, and the oxidation state of each element, morphology, and particle size of the prepared powder are chemically probed by different spectroscopic tools including X-ray Photoelectron Spectroscopy and Energy dispersive X-Ray spectroscopy. The sample is irradiated by a beta (b)-source with different applied doses in the range of 1.1--385 Gy. The kinetic parameters which correspond to the charge carrier traps were determined. The analysis methods indicated that the TL glow curve of BaTi5O11 consists of 6 overlapped peaks corresponding to 6 electron traps. The values for the trap depth are found to be in the range 0.94-1.40 eV and the TL glow peaks are located between 380.4 and 560.5 K. The study confirms the potential of BaTi5O11 for b-dosimetry (c) 2023 Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

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