Related references
Note: Only part of the references are listed.
Article
Multidisciplinary Sciences
Qinghe Cao et al.
Summary: The authors propose a gradient design for zinc anodes that prevents side reactions and dendrite growth. This design allows for long-term stable zinc anodes at high currents/capacities, which is a significant challenge for practical rechargeable zinc-ion batteries.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Ran Zhao et al.
Summary: This study reports a unique strategy to improve the energy density and lifespan of AZBs by simultaneously regulating cation and anion fluxes using a microporous material. The as-synthesized protective layer effectively repels sulfate infiltration and homogenizes Zn ion flux, achieving a dendrite-free morphology. The protected anode exhibits a long lifespan, deep Zn plating/stripping, and high current tolerance, providing a low-cost remedy for practical scale-up of AZBs.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Tingting Wei et al.
Summary: The adsorption of 1,4-dioxane on the Zn anode surface can improve the stability and cycling performance of ZIBs by inhibiting dendrite growth and side reactions. ZIBs with the addition of 1,4-dioxane showed a long-term cycling stability of 1000 hours and good reversibility. This study provides a promising modulation strategy at the molecular level for high-performing Zn anodes.
Article
Chemistry, Multidisciplinary
Nengze Wang et al.
Summary: A zincophobic electrolyte containing succinonitrile (SN) additive is proposed in this study, showing a lower affinity for zinc but a stronger affinity for solid-state interphase (SEI). The SN electrolyte allows the accumulation of zinc hydroxide sulfate (ZHS) horizontally to form a dense SEI protective layer, effectively reducing corrosion and dendrite growth. The zincophobic SN electrolyte exhibits excellent performance with high Coulombic efficiency and stable cycles, making it a promising option for zinc metal batteries.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Yanze Li et al.
Summary: A Cu-modified Ti3C2Cl2 MXene (Cu-MXene) as a protective coating on Zn anode is prepared, which provides massive nucleation sites and uniform charge distribution for homogeneous Zn deposition. The hydrophobic coating prevents side reactions and corrosion, leading to stable and reversible Zn plating/stripping with extended cycling life and high coulombic efficiency.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Mingquan Liu et al.
Summary: A novel molecular engineering strategy was proposed for the in situ construction of N/P/O-doped HD-HPCs via the direct carbonization of multiple-heteroatom-rich hypermolecules. This strategy has multiple advantages and is environmentally friendly.
SCIENCE CHINA-MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Jingjing Yang et al.
Summary: This review comprehensively summarizes the recent progress of interphase modulation in zinc-ion batteries (ZIBs), aiming to achieve high-performance ZIBs with prolonged lifespan and high reversibility. It provides a systematic guideline for constructing ideal artificial layers.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Chunlin Xie et al.
Summary: Developing a stable and dendrite-free zinc anode is crucial for the commercialization of zinc metal batteries. However, the understanding of zinc dendrite formation mechanism is still insufficient. This study reveals that interfacial heterogeneous deposition induced by lattice defects and epitaxial growth limited by residual stress are intrinsic causes for zinc dendrite formation. An annealing reconstruction strategy is proposed to eliminate lattice defects and stresses, achieving dense epitaxial electrodeposition of zinc anode. The resulting annealed zinc anodes exhibit dendrite-free morphology and improved electrochemical cycling stability. This work provides a new mechanism for future research on zinc anode modification by highlighting the importance of lattice defects and residual stresses.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Dan Xie et al.
Summary: A high-quality and ZnF2-riched inorganic/organic hybrid solid electrolyte interface (SEI) layer was constructed on the surface of Zn metal anode (ZMA) by introducing multifunctional fluoroethylene carbonate (FEC) into aqueous electrolyte. The addition of FEC effectively regulated the solvated structure of Zn2+ and hindered the formation of dendrites, thus suppressing dendrites growth and parasitic reactions. The ZMA in FEC-included ZnSO4 electrolyte exhibited a long cycle life and stable coulombic efficiency.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Green & Sustainable Science & Technology
Heng Jiang et al.
Summary: Rechargeable aqueous zinc batteries are gaining popularity in stationary storage applications due to their safety, cost-effectiveness, scalability, and low carbon footprint. However, the challenge of hydrogen evolution reaction (HER) at the zinc surface hinders the utilization of this reversible redox chemistry. In this study, a concentrated electrolyte design is developed to eliminate HER and achieve high Coulombic efficiency for Zn plating/stripping. The hybrid electrolyte not only enables the formation of a protective solid electrolyte interphase but also enhances battery performance, allowing for sustainable energy storage with high energy density.
NATURE SUSTAINABILITY
(2023)
Article
Chemistry, Multidisciplinary
Wenyong Chen et al.
Summary: In this study, a maltose-based hybrid electrolyte with hydrogen bond-functionalized massive solvation modules is constructed to address the poor cyclic stability of zinc-ion batteries. The solvation modules promote uniform deposition of zinc at the anode interface and hinder parasitic reactions through hydrogen bond confinement. Meanwhile, they prevent structural collapse at the cathode interface and maintain low interfacial activation energy during cycling. The resultant full batteries retain 84.2% of their initial specific capacity after 400 continuous cycles at a low current density of 50 mA g(-1).
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Physical
Tian Chen Li et al.
Summary: Adding carbonyl-containing organic solvents can enhance the reversibility of zinc-ion batteries and improve their cycling stability and capacity retention.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Lei Zhang et al.
Summary: Aqueous Zn-ion batteries have the potential for large-scale energy storage due to their safety and cost-effectiveness. The addition of nettle extract helps to guide uniform zinc deposition on the anode, effectively suppressing dendrite growth and improving battery performance over extended cycling. This approach of engineering zincophilic sites through plant extracts opens up new possibilities for dendrite-free zinc anodes.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Licheng Miao et al.
Summary: The introduction of a hydrophobic carbonate cosolvent in rechargeable aqueous zinc batteries can address the irreversible issues of Zn metal anodes by breaking the water's H-bond network, replacing solvating H2O, and creating a dendrite-free Zn2+-plating behavior. This efficient strategy with a hydrophobic cosolvent offers a promising direction for designing aqueous battery chemistries.
Article
Chemistry, Multidisciplinary
Dao-Sheng Liu et al.
Summary: A novel 3 m Zn(CF3SO3)2 electrolyte was used to improve the cycling performance and specific capacity of aqueous vanadium-based zinc-ion batteries. By manipulating the solvation structure of the electrolyte, the batteries showed super-stable cycling performance and high specific capacity.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Fangwang Ming et al.
Summary: This work proposes a hybrid electrolyte induced by the salting-in effect as an effective strategy to achieve a highly reversible zinc anode with good stability and compatibility. By altering the solvation structure and reducing parasitic side reactions, this electrolyte ensures a stable zinc anode with excellent cycling stability.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Yan Xu et al.
Summary: A nucleophilic interfacial layer (NIL) was developed to achieve a stable Zn anode for aqueous Zn batteries, resulting in improved performance and extended lifespan.
Article
Chemistry, Physical
Zhenyu Miao et al.
Summary: Aqueous Zn-ion batteries have the potential for large scale energy storage due to their low cost and safe operation. However, the dendritic growth of Zn limits their cycle life. This study introduces threonine as an electrolyte additive, which inhibits the dendritic growth of Zn and improves the cycling performance and energy efficiency of the batteries.
Article
Chemistry, Multidisciplinary
Chuyuan Lin et al.
Summary: Ammonium acetate is used as an electrolyte additive to enhance the performance of aqueous zinc-ion batteries. It can adsorb on the zinc electrode surface and regulate the electrolyte pH, effectively suppressing side reactions and dendrite formation. The batteries with ammonium acetate exhibit stable operation and long lifespan at high current densities.
Article
Chemistry, Physical
Chang Li et al.
Summary: This study introduces a novel additive that effectively solves the issues in aqueous zinc-metal batteries, leading to excellent cycling performance and efficient zinc deposition.
Article
Chemistry, Physical
Yan Wu et al.
Summary: This research presents a strategy to improve the stability and reversibility of dilute aqueous zinc metal batteries by engineering the electrolyte. The engineered electrolyte shows high cyclic performance and dendrite-free morphology. This electrolyte structural engineering provides a promising direction for designing high reversibility and long-cycling life aqueous zinc metal batteries.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Tianyi Zhou et al.
Summary: The introduction of PASP as an electrolyte additive for aqueous rechargeable zinc batteries can address the issues of dendrite growth and side-reactions, leading to improved cyclic stability and high Coulombic efficiency.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Kang Zhao et al.
Summary: This study demonstrates the potential of cyclodextrins (CDs) as electrolyte additives for rechargeable Zn batteries. The addition of alpha-CD improves the stability and kinetics of Zn plating and stripping by adsorbing on the Zn surface and suppressing water-induced side reactions. This finding provides insight into the use of supramolecular macrocycles for enhancing the performance of aqueous battery chemistry.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Jianghong Yang et al.
Summary: In this study, a high donor number solvent, tetramethylurea (TMU), was introduced as an additive in the electrolyte to enable a highly reversible zinc metal anode. The TMU effectively inhibited zinc corrosion and suppressed parasitic reactions, reduced water activity, and facilitated rapid zinc ion transport, resulting in stable zinc plating/stripping cycling and long battery lifetime.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Junnan Hao et al.
Summary: This study reveals the challenges in aqueous Zn-ion batteries and proposes a new electrolyte strategy to address these issues. Experimental results demonstrate that the strategy can achieve high reversibility and long lifespan for Zn-ion batteries.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Huanyan Liu et al.
Summary: This research proposes a novel metal-organic complex interphase strategy to address the corrosion and dendrite issues in aqueous Zn metal batteries. By forming complex interphases between metal Zn and phytic acid, the deposition of Zn is made more uniform and the Coulombic efficiency is significantly improved, leading to enhanced stability and cycling lifetime of Zn metal batteries.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Physical
Runzhi Qin et al.
Summary: The addition of ethylene glycol as an additive in aqueous electrolyte effectively inhibits the short-circuit issue induced by zinc dendrite growth in zinc-ion batteries, leading to longer cycling lifespan. By modifying the solvation sheath of zinc ions, the diffusion rate of zinc ions is reduced, promoting a uniform deposition morphology.
Article
Chemistry, Multidisciplinary
Junnan Hao et al.
Summary: A similar antisolvent strategy has been used to enhance Zn reversibility and suppress dendrite growth in Zn plating/stripping, with promising results shown in 50% methanol electrolyte. This low-cost strategy can be easily applied to other solvents, demonstrating practical universality and potential for enhancing performance in electrochemistry and energy storage research.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Shiying Li et al.
Summary: The research investigates the influence of surface structure on the nucleation and deposition of Zn by reconstructing the surface structure of a Zn-metal anode with Sn crystal textures. The high-affinity Zn binding sites of Sn and the high surface energy ensure better wettability from the deposits and promote the lateral growth of Zn crystals, leading to improved stability and cycling performance of the Zn-metal anode.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Cong Huang et al.
Summary: The research shows that saccharin (Sac) as an electrolyte additive can regulate the electrical double layer (EDL) structure on the zinc anode, forming a unique solid electrolyte interphase (SEI) that effectively modulates zinc deposition behavior and prevents side reactions, thus improving battery performance.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Peng Sun et al.
Summary: The addition of glucose in ZnSO4 electrolyte can improve the performance of Zn ion batteries by suppressing Zn dendrite growth and side reactions, enhancing stability.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Physical
Mengdie Yan et al.
Summary: This study demonstrates the improvement of zinc anodes in low-cost aqueous electrolytes by adding polymers of different polarities, resulting in over 1300 hours of operation time and high Coulombic efficiency under 2 mA/cm², 2 mAh/cm² conditions.
ACS ENERGY LETTERS
(2021)
Article
Chemistry, Physical
Qiu Zhang et al.
Summary: This study presents synthetic electrolyte/cathode design strategies for low-temperature aqueous Zn batteries, revealing the fundamental correlations between anion chemistries and freezing point depression of water. By utilizing a chaotropic anion, CF3SO3-, a low-temperature zinc electrolyte with high ionic conductivity is achieved, enabling high-performance Zn parallel to V2O5 batteries to deliver a high specific capacity at -30 degrees C with excellent capacity retention after cycles.
ACS ENERGY LETTERS
(2021)
Article
Chemistry, Physical
Ying Zhang et al.
Summary: The unique 2D Zn-Sb3P2O14 protective layer effectively addresses the issues of dendrite growth and side reactions of metallic zinc in aqueous batteries, enabling stable electron deposition and high Coulombic efficiency.
Article
Chemistry, Multidisciplinary
Xiaohui Zeng et al.
Summary: Inspired by the bio-adhesion principle, a stable SEI layer of polydopamine was successfully constructed on a Zn anode, offering multifunctional features that regulate Zn nucleation, enhance Zn-ion conductivity, and block interfacial side reactions. This approach significantly improved the performance and stability of rechargeable aqueous zinc-ion batteries.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Yuzhu Chu et al.
Summary: The in situ construction of a composite SEI mainly composed of Zn-3(PO4)(2) and ZnF2 (ZCS) effectively suppresses Zn dendrite growth and accelerates Zn2+ transference and deposition kinetics in aqueous Zn-ion batteries. By taking advantage of the instability of KPF6 in an aqueous environment, an in situ ZCS is successfully built on the Zn anode through a PF6- anion-induced chemical strategy, showing enhanced reversibility and excellent electrochemical performance. This work not only paves a new way for designing a desirable SEI on the Zn anode, but also may guide the interface engineering of other systems to overcome intrinsic defects in constructing favorable interphases.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Xiaotan Zhang et al.
Summary: The CNG membrane, serving as a desolvation layer, effectively prevents water molecules from contacting the zinc anode, thereby delaying water-induced corrosion reactions and promoting redirected zinc deposition through deanionization shock. The flexible and toughened nature of the CNG membrane allows it to withstand strong forces and accommodate surface fluctuations of the zinc anode during plating/stripping processes, resulting in enhanced Coulombic efficiency and extended cycle life.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Junnan Hao et al.
ADVANCED MATERIALS
(2020)
Article
Multidisciplinary Sciences
Qi Zhang et al.
NATURE COMMUNICATIONS
(2020)
Article
Chemistry, Physical
Wenbin Guo et al.
ENERGY STORAGE MATERIALS
(2020)
Article
Chemistry, Physical
Yuexiu Du et al.
JOURNAL OF POWER SOURCES
(2020)
Article
Chemistry, Multidisciplinary
Longsheng Cao et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2020)
Article
Chemistry, Multidisciplinary
Lu Zhang et al.
ADVANCED FUNCTIONAL MATERIALS
(2019)
Article
Chemistry, Multidisciplinary
Qi Zhang et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2019)
Article
Chemistry, Multidisciplinary
Zhiming Zhao et al.
ENERGY & ENVIRONMENTAL SCIENCE
(2019)
Article
Chemistry, Physical
Fei Wang et al.
Article
Chemistry, Multidisciplinary
Allen Pei et al.
