☆ 4.8 Review

Prospective Application, Mechanism, and Deficiency of Lithium Bis(oxalate)Borate as the Electrolyte Additive for Lithium-Batteries

ADVANCED ENERGY MATERIALS (2023)

Related references

Note: Only part of the references are listed.

Article Chemistry, Physical

Conductive Li+ Moieties-Rich Cathode Electrolyte Interphase with Electrolyte Additive for 4.6 V Well-Cycled Li||LiCoO2 Batteries

Kanglong Guo et al.

Summary: Increasing the cut-off voltage of cathodes improves the energy density of Li||LiCoO2 batteries, but also leads to rapid battery degradation due to oxidation and deterioration. However, by using bis-(benzenesulfonyl)imide (BBSI) as an additive, a uniform and highly Li+ conductive cathode electrolyte interphase (CEI) is constructed, which stabilizes the batteries at 4.6 cut-off voltage and exhibits superior cycling and high-rate performance. The CEI, consisting of LiF and conductive Li+ moieties, improves Li+ migration, alleviates cathode degradation, and reduces other secondary degradation factors. Li||LiCoO2 batteries with 1% BBSI-containing electrolyte sustain 81.30% of initial capacity after 300 cycles at 0.5C, and 88.27% of initial capacity even after 500 cycles at 2C/3C.

ADVANCED ENERGY MATERIALS (2023)

Add to Collection

Article Chemistry, Physical

A High Energy-Density, Cobalt-Free, Low-Nickel LiNi0.7Mn0.25Al0.05O2 Cathode with a High-Voltage Electrolyte for Lithium-Metal Batteries

Richard Sim et al.

Summary: This study demonstrates the use of a localized saturated electrolyte (LSE) to enable stable cycling of a cobalt-free, low-nickel layered-oxide cathode LiNi0.7Mn0.25Al0.05O2 (NMA-70) to higher voltages (4.6 V) in a lithium-metal battery. Compared to the baseline LP57 electrolyte, the LSE extends the cycle life from approximately 100 cycles to approximately 400 cycles before reaching 80% capacity retention. The use of LSE reduces active material loss, overpotential growth, and gas evolution, thereby improving the safety characteristics of the cell.

ADVANCED ENERGY MATERIALS (2023)

Add to Collection

Article Nanoscience & Nanotechnology

Unraveling the Dynamic Interfacial Behavior of LiCoO2 at Various Voltages with Lithium Bis(oxalato)borate for Lithium-Ion Batteries

Meihua Hong et al.

Summary: The electrochemical behavior of SEI formed by LiBOB on LCO is investigated at different cutoff voltages. LiBOB can suppress side reactions by forming SEI, but the SEI decomposes at high voltages, causing a decrease in electrochemical performance.

ACS APPLIED MATERIALS & INTERFACES (2022)

Add to Collection

Article Chemistry, Physical

Elucidating the Effect of Borate Additive in High-Voltage Electrolyte for Li-Rich Layered Oxide Materials

Yixuan Li et al.

Summary: This study reports the use of lithium bis-(oxalate)borate (LiBOB) as an electrolyte additive to improve the cycling stability in high voltage lithium-rich layered oxide (LRLO)/graphite full cells. The cell with LiBOB-containing electrolyte exhibits high initial capacity and no capacity decay or voltage fade after multiple cycles.

ADVANCED ENERGY MATERIALS (2022)

Add to Collection

Article Nanoscience & Nanotechnology

Dilute Electrolyte to Mitigate Capacity Decay and Voltage Fading of Co-Free Li-Rich Cathode for Next-Generation Li-Ion Batteries

Depeng Song et al.

Summary: This study presents a novel dilute electrolyte based on Co-free Li-rich cathodes, overcoming the limitations of cycling decay and voltage fading in Li-ion batteries. The Co-free Li-rich cathode demonstrates the best electrochemical performance among Li-rich cathodes, with outstanding cycling stability and suppressed voltage fading.

ACS APPLIED MATERIALS & INTERFACES (2022)

Add to Collection

Article Multidisciplinary Sciences

Origin of structural degradation in Li-rich layered oxide cathode

Tongchao Liu et al.

Summary: Utilizing Li- and Mn-rich (LMR) cathode materials can increase battery energy density. However, voltage decay issues impede commercialization. In this study, it is revealed that nanostrain and lattice displacement accumulate continuously during operation, leading to structure degradation and oxygen loss, which cause rapid voltage decay. The heterogeneous nature of LMR cathodes results in pernicious phase displacement/strain. Mesostructural design is proposed as a strategy to mitigate lattice displacement and achieve stable voltage and capacity profiles.

NATURE (2022)

Add to Collection

Article Chemistry, Physical

Sustained releasing superoxo scavenger for tailoring the electrode-electrolyte interface on Li-rich cathode

Baodan Zhang et al.

Summary: This research reveals that the enrichment of superoxo-related species on the surface of Li-rich layered oxide (LRLO) cathode can significantly aggravate electrolyte degradation and affect the structure of the cathode-electrolyte interface (CEI). By introducing a boron-containing electrolyte additive, LiBOB, the stability of the CEI can be enhanced with cross-linking and polymeric components derived from BOB. Additionally, LiDFOB acts as a scavenger for superoxo species, effectively eliminating nucleophilic attack. The work highlights the importance of in-situ superoxo scavenging process and prompts the reconsideration of electrolyte design/modification principles for LRLO cathodes.

ENERGY STORAGE MATERIALS (2022)

Add to Collection

Article Chemistry, Physical

Restraining the Octahedron Collapse in Lithium and Manganese Rich NCM Cathode toward Suppressing Structure Transformation

Zhou Xu et al.

Summary: This study proposes a facile and efficient surface strategy to stabilize the layered structure of LMRNCM by regulating the chemical bond interaction between the PAN binder and the LMRNCM particles. The experimental results show that this modification strategy can improve the energy density retention, initial Coulombic efficiency, and rate capacity of the LMRNCM samples.

ADVANCED ENERGY MATERIALS (2022)

Add to Collection

Article Chemistry, Physical

Highly stable surface and structural origin for lithium-rich layered oxide cathode materials

Guohua Li et al.

Summary: Surface/interfacial engineering plays a critical role in optimizing the electrochemical performance of Li-rich layered oxides (LLOs). This study investigates the surface structure of LLOs and performs surface engineering to enhance their stability and prevent voltage decay. The results show that an integrated spinel/rock salt surface structure forms on the LLO surface, leading to improved cycle stability and low voltage decay. The modified LLO cathode retains a high capacity after 2000 cycles, indicating the stability of the surface layer. The findings suggest that the ISR surface concept and the surface modification method have great potential for the commercialization of LLOs in battery applications.

NANO ENERGY (2022)

Add to Collection

Article Chemistry, Physical

High Voltage LiCoO2 Cathodes with High Purity Lithium Bis(oxalate) Borate (LiBOB) for Lithium-Ion Batteries

Yaprak Subas et al.

Summary: The addition of high-purity lithium bis(oxalate) borate as an electrolyte additive improves the cycling performance and rate capability of lithium-ion batteries by forming a protective solid electrolyte interface, preventing electrolyte decomposition and structural changes.

ACS APPLIED ENERGY MATERIALS (2022)

Add to Collection

Article Chemistry, Physical

On the Beneficial Impact of Li2CO3 as Electrolyte Additive in NCM523 ∥ Graphite Lithium Ion Cells Under High-Voltage Conditions

Sven Klein et al.

Summary: The addition of Li2CO3 to the electrolyte can prevent capacity decay in batteries at high temperatures, improving the cycling performance and preventing TM deposition and Li metal formation on graphite.

ADVANCED ENERGY MATERIALS (2021)

Add to Collection

Article Chemistry, Physical

Tailoring electrolyte to enable high-rate and super-stable Ni-rich NCM cathode materials for Li-ion batteries

Fangyuan Cheng et al.

Summary: The study shows that detrimental effects on the electrochemical performances of high-capacity nickel-rich layered oxide cathode LiNi0.8Co0.1Mn0.1O2 can be limited by forming a uniform inorganic/polymer cathode-electrolyte interface (CEI) through in-situ electrochemical oxidation of trace dual additives in traditional carbonate-based electrolytes. This CEI film not only eliminates adverse cathode-electrolyte interface reactions and prevents electrolyte penetration into grain boundaries, but also inhibits the formation of inactive rock salt phase on the material surface.

NANO ENERGY (2021)

Add to Collection

Article Chemistry, Physical

Hydrolysis of LiPF6-Containing Electrolyte at High Voltage

Mingzhu Liu et al.

Summary: By combining theoretical and experimental approaches, this study identified the direct reaction between water and PF6- as the main source of corrosive HF in Li-ion batteries. This hydrolysis process is accelerated by high voltage, highlighting the need for effective mitigation strategies to stabilize LiPF6-based electrolytes for high voltage LIBs. Clarifying this important electrolyte failure mechanism points to the potential for improved battery performance and longevity.

ACS ENERGY LETTERS (2021)

Add to Collection

Article Chemistry, Physical

Guide to Water Free Lithium Bis(oxalate) Borate (LiBOB)

Ceren Zor et al.

Summary: This study synthesized high purity water free LiBOB with fewer processing steps and characterized both the anhydrous and monohydrate phases to address instability issues under ambient conditions. Protective measures were discussed to ensure proper handling and performance in real electrochemical systems.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Add to Collection

Article Chemistry, Physical

A Multifunctional Dual-Salt Localized High-Concentration Electrolyte for Fast Dynamic High-Voltage Lithium Battery in Wide Temperature Range

Shuangshuang Lin et al.

Summary: This study introduces a multifunctional high-concentration electrolyte containing fluorocarbonate, which shows excellent performance under high voltage and low temperature conditions, providing a new approach for designing high-performance lithium batteries.

ADVANCED ENERGY MATERIALS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

High-voltage liquid electrolytes for Li batteries: progress and perspectives

Xiulin Fan et al.

Summary: The energy density of LIBs has been increased threefold since their introduction, but the capacity of transition metal oxide cathodes is approaching its limit due to stability limitations of electrolytes. To further enhance energy density, new high-capacity and high-voltage cathode materials need to be explored, and graphite anodes may need to be replaced. One of the main challenges for future development is the development of new electrolyte compositions that can accommodate high-voltage cathodes and anodes while ensuring the stability of the batteries.

CHEMICAL SOCIETY REVIEWS (2021)

Add to Collection

Article Materials Science, Multidisciplinary

Exploring the redox decomposition of ethylene carbonate-propylene carbonate in Li-ion batteries

Jiaxiang Zhang et al.

Summary: This study investigated the oxidation stability and reductive decomposition of ethylene carbonate and propylene carbonate in lithium-ion battery electrolytes using quantum calculations, revealing differences in their reductive decomposition and potential impact on the quality of the solid-electrolyte interphase (SEI) based on these solvents. The findings of this study could guide the design of new electrolyte systems to enhance the performance of Li-ion batteries.

MATERIALS ADVANCES (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Formulation of Blended-Lithium-Salt Electrolytes for Lithium Batteries

Gaojie Xu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Article Chemistry, Physical

An Antiaging Electrolyte Additive for High-Energy-Density Lithium-Ion Batteries

Jung-Gu Han et al.

ADVANCED ENERGY MATERIALS (2020)

Add to Collection

Article Chemistry, Physical

Study on boron-containing electrolytes at extra-high temperatures for lithium-ion batteries

Li Yang et al.

SUSTAINABLE ENERGY & FUELS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Lithium bis(oxalate)borate additive in the electrolyte to improve Li-rich layered oxide cathode materials

Zi Xiao et al.

MATERIALS CHEMISTRY FRONTIERS (2020)

Add to Collection

Article Chemistry, Physical

LiPF6 Stabilizer and Transition-Metal Cation Scavenger: A Bifunctional Bipyridine-Based Ligand for Lithium-Ion Battery Application

Hao Jia et al.

CHEMISTRY OF MATERIALS (2019)

Add to Collection

Article Chemistry, Physical

Ambient-Pressure Relithiation of Degraded LixNi0.5Co0.2Mn0.3O2 (0 < x < 1) via Eutectic Solutions for Direct Regeneration of Lithium-Ion Battery Cathodes

Yang Shi et al.

ADVANCED ENERGY MATERIALS (2019)

Add to Collection

Article Nanoscience & Nanotechnology

Stabilizing a High-Voltage Lithium-Rich Layered Oxide Cathode with a Novel Electrolyte Additive

Jianlian Lan et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Add to Collection

Article Electrochemistry

Enabling fast charging of high energy density Li-ion cells with high lithium ion transport electrolytes

Zhijia Du et al.

ELECTROCHEMISTRY COMMUNICATIONS (2019)

Add to Collection

Review Chemistry, Physical

Film-forming electrolyte additives for rechargeable lithium-ion batteries: progress and outlook

Huajun Zhao et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Add to Collection

Article Chemistry, Physical

Effects of LiBOB on salt solubility and BiF3 electrode electrochemical properties in fluoride shuttle batteries

Asuman Celik Kucuk et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Add to Collection

Article Chemistry, Physical

Effect of trace hydrofluoric acid in a LiPF6 electrolyte on the performance of a Li-organic battery with an N-heterocycle based conjugated microporous polymer as the cathode

Zhangxin Chen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Add to Collection

Article Chemistry, Physical

Modulation of solid electrolyte interphase of lithium-ion batteries by LiDFOB and LiBOB electrolyte additives

Shiqiang Huang et al.

APPLIED SURFACE SCIENCE (2018)

Add to Collection

Article Electrochemistry

Unraveling the role of LiFSI electrolyte in the superior performance of graphite anodes for Li-ion batteries

Sung-Jin Kang et al.

ELECTROCHIMICA ACTA (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Electrode-electrolyte interfaces in lithium-based batteries

Xingwen Yu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes - a critical review

Chun Zhan et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Add to Collection

Article Chemistry, Physical

A novel lithium difluoro(oxalate) borate and lithium hexafluoride phosphate dual-salt electrolyte for Li-excess layered cathode material

Xiaofei Bian et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2018)

Add to Collection

Article Chemistry, Physical

Dendrite-Free and Performance-Enhanced Lithium Metal Batteries through Optimizing Solvent Compositions and Adding Combinational Additives

Xing Li et al.

ADVANCED ENERGY MATERIALS (2018)

Add to Collection

Article Chemistry, Physical

High Voltage Operation of Ni-Rich NMC Cathodes Enabled by Stable Electrode/Electrolyte Interphases

Wengao Zhao et al.

ADVANCED ENERGY MATERIALS (2018)

Add to Collection

Article Chemistry, Physical

Mn versus Al in Layered Oxide Cathodes in Lithium-Ion Batteries: A Comprehensive Evaluation on Long-Term Cyclability

Wangda Li et al.

ADVANCED ENERGY MATERIALS (2018)

Add to Collection

Article Chemistry, Physical

Extending the Service Life of High-Ni Layered Oxides by Tuning the Electrode-Electrolyte Interphase

Jianyu Li et al.

ADVANCED ENERGY MATERIALS (2018)

Add to Collection

Article Chemistry, Physical

MnPO4-Coated Li(Ni0.4Co0.2Mn0.4)O2 for Lithium(-Ion) Batteries with Outstanding Cycling Stability and Enhanced Lithiation Kinetics

Zhen Chen et al.

ADVANCED ENERGY MATERIALS (2018)

Add to Collection

Article Energy & Fuels

Compatibility between Lithium Bis(oxalate)borate-Based Electrolytes and a LiFe0.6Mn0.4PO4/C Cathode for Lithium-Ion Batteries

Qiuping Zhao et al.

ENERGY TECHNOLOGY (2017)

Add to Collection

Article Chemistry, Physical

Mechanisms for electrochemical performance enhancement by the salt-type electrolyte additive, lithium difluoro(oxalato)borate, in high-voltage lithium-ion batteries

Jiho Cha et al.

JOURNAL OF POWER SOURCES (2017)

Add to Collection

Article Electrochemistry

Synergistic Effect of LiPF6 and LiBF4 as Electrolyte Salts in Lithium-Ion Cells

L. D. Ellis et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Energy storage applications of biomass-derived carbon materials: batteries and supercapacitors

Yong-Ping Gao et al.

NEW JOURNAL OF CHEMISTRY (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Fluorinated Electrolytes for Li-Ion Batteries: The Lithium Difluoro(oxalato)borate Additive for Stabilizing the Solid Electrolyte Interphase

Lan Xia et al.

ACS OMEGA (2017)

Add to Collection

Article Nanoscience & Nanotechnology

Effect of Lithium Borate Additives on Cathode Film Formation in LiNi0.5Mn1.5O4/Li Cells

Yingnan Dong et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Add to Collection

Article Electrochemistry

Mixed Salts of LiFSI and LiODFB for Stable LiCoO2-Based Batteries

Xuehui Shangguan et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2016)

Add to Collection

Article Electrochemistry

Hydrolysis of Ethylene Carbonate with Water and Hydroxide under Battery Operating Conditions

Michael Metzger et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2016)

Add to Collection

Article Chemistry, Physical

Compatibility of lithium difluoro(sulfato)borate-based electrolyte for LiMn2O4 cathode

Shiyou Li et al.

APPLIED SURFACE SCIENCE (2015)

Add to Collection

Article Chemistry, Physical

Comparative study of lithium bis(oxalato) borate and lithium bis(fluorosulfonyl) imide on lithium manganese oxide spinel lithium-ion batteries

Renheng Wang et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2015)

Add to Collection

Article Chemistry, Physical

Comparative study on lithium borates as corrosion inhibitors of aluminum current collector in. lithium bis(fluorosulfonyl)imide electrolytes

Kisung Park et al.

JOURNAL OF POWER SOURCES (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Preparation of LiBOB via rheological phase method and its application to mitigate voltage fade of Li-1.16[Mn0.75Ni0.25](0.84)O-2 cathode

Fang Lian et al.

RSC ADVANCES (2015)

Add to Collection

Article Electrochemistry

Vinyl sulfones as SEI-forming additives in propylene carbonate based electrolytes for lithium-ion batteries

Ralf Wagner et al.

ELECTROCHEMISTRY COMMUNICATIONS (2014)

Add to Collection

Article Electrochemistry

Synergistic effect between lithium bis(fluorosulfonyl)imide (LiFSI) and lithium bis-oxalato borate (LiBOB) salts in LiPF6-based electrolyte for high-performance Li-ion batteries

Longfei Zhang et al.

ELECTROCHIMICA ACTA (2014)

Add to Collection

Article Chemistry, Physical

Electrochemical performances of a novel lithium bis(oxalate)borate-based electrolyte for lithium-ion batteries with LiFePO4 cathodes

Xiaoling Cui et al.

IONICS (2014)

Add to Collection

Article Chemistry, Physical

Compatibility of Graphite with 1,3-(1,1,2,2-Tetrafluoroethoxy)propane and Fluoroethylene Carbonate as Cosolvents for Nonaqueous Electrolyte in Lithium-Ion Batteries

Guochun Yan et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2014)

Add to Collection

Article Chemistry, Physical

A systematic study of well-known electrolyte additives in LiCoO2/graphite pouch cells

David Yaohui Wang et al.

JOURNAL OF POWER SOURCES (2014)

Add to Collection

Article Electrochemistry

Performance Enhancement of 4.8 V Li1.2Mn0.525Ni0.175Co0.1O2 Battery Cathode Using Fluorinated Linear Carbonate as a High-Voltage Additive

Hieu Quang Pham et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2014)

Add to Collection

Article Electrochemistry

Anodic Aluminum Dissolution in Conducting Salt Containing Electrolytes for Lithium-Ion Batteries

Andreas Hofmann et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2014)

Add to Collection

Article Electrochemistry

Using a lithium bis(oxalato) borate additive to improve electrochemical performance of high-voltage spinel LiNi0.5Mn1.5O4 cathodes at 60 °C

Se-Young Ha et al.

ELECTROCHIMICA ACTA (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Improved Performances of Nanosilicon Electrodes Using the Salt LiFSI: A Photoelectron Spectroscopy Study

Bertrand Philippe et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Add to Collection

Article Electrochemistry

Improving the Performance of Graphite/ LiNi/0.5Mn1.5O4 Cells at High Voltage and Elevated Temperature with Added Lithium Bis(oxalato) Borate (LiBOB)

Mengqing Xu et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2013)

Add to Collection

Article Electrochemistry

Effect of Added LiBOB on High Voltage (LiNi0.5Mn1.5O4) Spinel Cathodes

Swapnil Dalavi et al.

ELECTROCHEMICAL AND SOLID STATE LETTERS (2012)

Add to Collection

Article Electrochemistry

A tetraethylene glycol dimethylether-lithium bis(oxalate)borate (TEGDME-LiBOB) electrolyte for advanced lithium ion batteries

Dong-Ju Lee et al.

ELECTROCHEMISTRY COMMUNICATIONS (2012)

Add to Collection

Article Chemistry, Physical

Surface layer formation of LiCoO2 thin film electrodes in non-aqueous electrolyte containing lithium bis(oxalate)borate

Masaki Matsui et al.

JOURNAL OF POWER SOURCES (2012)

Add to Collection

Article Electrochemistry

Effect of LiBOB Additive on the Electrochemical Performance of LiCoPO4

V. Aravindan et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2012)

Add to Collection

Article Chemistry, Physical

Lithium bis(fluorosulfonyl)imide (LiFSI) as conducting salt for nonaqueous liquid electrolytes for lithium-ion batteries: Physicochemical and electrochemical properties

Hong-Bo Han et al.

JOURNAL OF POWER SOURCES (2011)

Add to Collection

Article Chemistry, Physical

LiPF6 and lithium oxalyldifluoroborate blend salts electrolyte for LiFePO4/artificial graphite lithium-ion cells

Zhian Zhang et al.

JOURNAL OF POWER SOURCES (2010)

Add to Collection

Article Chemistry, Physical

Effect of mixed LiBOB and LiPF6 salts on electrochemical and thermal properties in LiMn2O4 batteries

Deng-Tswen Shieh et al.

JOURNAL OF POWER SOURCES (2007)

Add to Collection

Article Chemistry, Physical

Surface layer formed on silicon thin-film electrode in lithium bis(oxalato) borate-based electrolyte

Nam-Soon Choi et al.

JOURNAL OF POWER SOURCES (2007)

Add to Collection

Article Electrochemistry

Comparison of the thermal stability of lithiated graphite in LiBOB EC/DEC and in LiPF6 EC/DEC

J Jiang et al.

ELECTROCHEMICAL AND SOLID STATE LETTERS (2003)

Add to Collection

© Peeref 2019-2024. All rights reserved.