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PROGRESS IN PHOTOVOLTAICS
(2023)
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Shurong Wang et al.
Summary: To solve the problems of uncontrollable crystallization process and facile oxidation of Sn2+, a series of acetates are introduced into the perovskite precursor solution. Formamidine acetate (FAAc) is found to have strong C(sic)O-Sn coordination with Sn2+, which can stabilize the lattice structure, minimize defect states, and suppress the oxidation of Sn2+. By introducing FAAc into the precursor, the power conversion efficiency of the device is increased from initially 9.84% to 12.43%, and it can maintain 94% of its initial value for 2000 hours in N2 atmosphere. This work provides a feasible strategy for depositing high-quality tin perovskite films, which is crucial for related photovoltaics and other optoelectronic devices.
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Yanyan Zhang et al.
Summary: This study molecularly explored the chemistry of perovskite precursor solutions for the first time using in situ liquid time-of-flight secondary ion mass spectrometry. It identified that methylammonium, formamidinium cations, and I- anion are the drivers of aging chemistry. The introduction of Lewis bases triethyl phosphate and ethyl ethanesulfonate as additives protected the reactive cations from aging through weak interactions, with triethyl phosphate showing better long-term solution stability. The perovskite solar cell derived from a fresh triethyl phosphate-doped solution retained 92.23% of the conversion efficiency after 21 days of aging, achieving a high power conversion efficiency of 23.06%.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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He Dong et al.
Summary: This review examines the research milestones and optoelectronic devices of metal halide perovskites (MHPs) and emphasizes their unique optoelectronic features. It highlights the tunability of these features through regulating the phase, dimensionality, composition, and geometry of MHPs. The review also showcases the design of optoelectronic devices with target performance using the convenient property control of MHPs. Furthermore, it emphasizes the revolutionary applications of MHPs-based devices in existing optoelectronic systems, and it is expected to inspire novel research directions and widespread applications of MHPs in next-generation optoelectronics.
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Dongjie Wang et al.
Summary: This study demonstrates the fabrication of high-performance carbon-based mesoscopic perovskite solar cells (MPSCs) by adding an ionic liquid additive, methylammonium acetate (MAAc), into methylammonium lead triiodide (MAPbI(3)) perovskite. The addition of MAAc effectively controls the crystallization kinetics of MAPbI(3) and improves the crystallinity and defect density of the perovskite films. The optimized MAAc-engineered MPSCs achieve a champion power conversion efficiency (PCE) of 13.54% and demonstrate better air stability compared to control devices.
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Lei Gu et al.
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Yachao Du et al.
Summary: The incorporation of a low concentration of a novel ionic liquid successfully improves the defects, energy alignment at the interface, and stability of CsPbI3 perovskite solar cells fabricated via ambient blade-coating. The cells achieve high power conversion efficiency and impressive long-term ambient stability.
ADVANCED MATERIALS
(2022)
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Xiayan Chen et al.
Summary: In this study, the transformation of alpha-phase FAPbI(3) to delta-phase FAPbI(3) and the formation of an alpha/delta-phase junction were observed in hole-conductor-free triple-mesoscopic perovskite solar cells (PSCs) exposed to humid atmosphere. This junction exhibited a favorable band alignment and effectively suppressed charge recombination at the interface, leading to enhanced device performance.
CHEMISTRY OF MATERIALS
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Hao Gu et al.
Summary: This study reveals the mechanism of forming chemically stable perovskite precursor solutions using the MAAc protic ionic liquid solvent under ambient conditions. Stable perovskite colloids are formed through intermolecular hydrogen bonds and coordination interactions in the MAAc precursor solution. The interactions result in more stable perovskite colloids compared to traditional solvents.
Article
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Stuart Macpherson et al.
Summary: Understanding the nanoscopic chemical and structural changes is crucial for mitigating device degradation in emerging energy materials. Researchers have developed a multimodal microscopy toolkit to investigate the impact of phase impurities on the performance and longevity of formamidinium-rich perovskite absorbers. The study also demonstrates that manipulating these impurities can alleviate performance losses and intrinsic degradation processes.
Article
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Shaun Tan et al.
Summary: Optoelectronic devices rely on heterointerfaces between different semiconducting materials, and the energy-level alignment between them plays a crucial role in device performance. Surface treatments for perovskite solar cells can impact the energetics of the heterointerface, potentially affecting device stability. Balancing the pros and cons of surface treatments is essential for improving PSC stability.
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JOURNAL OF APPLIED PHYSICS
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Qi Jiang et al.
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Lu Liu et al.
Summary: This article investigates the interface issues of wide-bandgap perovskite solar cells and successfully improves energy conversion efficiency and indoor efficiency by designing a self-assembled monolayer as the interface layer. In addition, an all-perovskite tandem solar cell is configured, and a decent power conversion efficiency is achieved.
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Xuechen Zhu et al.
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Lingfeng Chao et al.
Summary: This study reports a strategy for directly fabricating stable alpha-phase of FAPbI(3) perovskite by controlling the precursor solution on the molecular level using methylammonium acetate (MAAc) ionic liquid. The results show that the strong interaction between Ac- and Pb2+ enables the relaxation of Pb-I bonds and allows the effective insertion of formamidinium iodide (FAI) into the perovskite framework. The resulting photovoltaic cell exhibits high efficiency and long-term stability.
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Huaxia Ban et al.
Summary: In this study, the addition of low concentrations of an ionic liquid, 1-ethyl-3-methylimidazolium acetate (EMIMAc), was found to effectively control deep-level defects in CsSnI3 perovskites, leading to improved performance of the solar cells. Experimental observations and theoretical simulations showed that EMIMAc can interact with and attract the surface undercoordinated Sn2+ ions, reducing the density of deep-level defects and suppressing nonradiative recombination. As a result, the CsSnI3 perovskite solar cells achieved a high power conversion efficiency of 8.54%, making them the most efficient reported CsSnI3 mesoporous perovskite solar cells to date.
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Minchao Qin et al.
Summary: Understanding the film formation mechanisms of metal halide perovskites is crucial for achieving high-quality perovskite films and high-performance devices. However, due to the complexity of perovskite composition, dimensionality, and processing conditions, this remains a great challenge.
ADVANCED MATERIALS
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Xiaojing Gu et al.
Summary: Iodine vacancies and undercoordinated Pb2+ are the main causes of nonradiative charge recombination in all-inorganic perovskite films, while passivation with histamine (HA) significantly reduces surface trap density and prolongs charge lifetime, leading to an increased solar cell efficiency.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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Shangshang Chen et al.
Summary: Research has shown that perovskite films prepared by one-step solution processes grow downward during thermal annealing, starting from an intermediate phase rather than from bottom to top. Understanding this vertical heterogeneity of perovskite films is crucial as it significantly impacts the efficiency and stability of perovskite solar cells.
Article
Chemistry, Multidisciplinary
Chao Liu et al.
Summary: The novel additive F-FAI enhances the crystallinity, defect passivation, and downshifts the Fermi level of MAPbI(3), thereby improving charge transfer and built-in field in printable triple mesoscopic PSCs. Additionally, F-FAI also promotes charge transport in MAPbI(3), resulting in a higher power conversion efficiency compared to devices with guanidinium iodide additives.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Multidisciplinary Sciences
Wei Hui et al.
Summary: A new method for synthesizing stable black-phase formamidinium lead iodide (α-FAPbI(3)) was reported, which enables the stable synthesis of α-FAPbI(3) under high temperature and humidity conditions, and maintains high efficiency under light stress.
Article
Chemistry, Physical
Xiayan Chen et al.
Summary: The reduction of dimensionality in the perovskite absorber within mesoporous carbon electrodes via post-treatments enhances device performance. Printable hole-conductor-free perovskite solar cells using MAPbI(3) and FAPbI(3) achieve high efficiencies and open-circuit voltages, providing a new strategy for research in printable solar cells.
ADVANCED ENERGY MATERIALS
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Xiongfeng Lin et al.
Summary: The introduction of a mesoporous charge-transporting layer into quasi-interdigitated back-contact perovskite devices leads to more efficient and balanced charge extraction dynamics, resulting in a high short-circuit current density of 21.3 mA cm(-2) and setting a record for this type of device architecture.
ADVANCED ENERGY MATERIALS
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Review
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Yi-Heng Zhang et al.
Summary: Perovskite solar cells have great potential to become commercial photovoltaic technology due to their high efficiency, low cost, and easy manufacturing. Interface engineering is crucial for optimizing device performance. This review discusses the progress in modifying anode and cathode materials in inverted devices, as well as proposes outlook and suggestions for future interface engineering.
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Ting Ji et al.
Summary: Perovskite solar cells have seen significant advancements in recent years, with a focus on the evolution of charge transporting materials like metal oxides and organic materials for electron transport, and small molecules and polymers for hole transport. The future development prospects for different types of charge transporting materials are also discussed in the review.
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Tongle Bu et al.
Summary: Efficient and stable perovskite layers are crucial for the commercialization of perovskite solar cells. A lead halide-templated crystallization strategy has been developed to print formamidinium-cesium lead triiodide perovskite films, achieving high-quality large-area films with controlled nucleation and growth. An unencapsulated device with 23% efficiency and excellent long-term thermal stability has been achieved, showcasing the potential for practical application in the future.
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Guixiang Li et al.
Summary: The use of n-butylammonium acetate (BAAc) to modulate tin coordination in the crystallization process results in more compact and preferentially oriented perovskite films. Perovskite solar cells processed with BAAc show higher power conversion efficiency and improved stability, paving the way for controlled tin-based perovskite crystallization in lead-free photovoltaics.
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Summary: Introducing molten salt spacers can produce phase-pure quantum wells and enhance the performance of solar cells. Two-dimensional Ruddlesden-Popper layered metal-halide perovskites have better stability and optoelectronic properties compared to their three-dimensional counterparts.
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