☆ 4.8 Article

Acridine PNP-Pincer Ligands Enabling Transition Metal-Catalyzed Photoreactions

ACS CATALYSIS (2023)

Related references

Note: Only part of the references are listed.

Article Chemistry, Multidisciplinary

Photoinduced Regioselective Olefination of Arenes at Proximal and Distal Sites

Argha Saha et al.

Summary: The Fujiwara-Moritani reaction has made a significant contribution to contemporary C-H activation protocols. By establishing a photoredox catalytic system, the regioselective Fujiwara-Moritani reaction can be achieved through visible light without the need for silver salts and thermal energy. This sustainable protocol has importance in synthesizing natural products, chiral molecules, drugs, and diversifying functionalizations.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Add to Collection

Article Multidisciplinary Sciences

A visible-light activated secondary phosphine oxide ligand enabling Pd-catalyzed radical cross-couplings

Takahito Kuribara et al.

Summary: Ligand design plays a crucial role in enhancing the performance of light-enabled catalytic processes. In this study, the authors synthesized a visible-light-activated secondary phosphine oxide ligand and applied it to Pd-catalyzed radical cross-coupling reactions. Through molecular design aided by computational calculations, the ligand enables ligand-to-Pd(II) and Pd(0)-to-ligand single-electron transfer under visible-light irradiation, facilitating radical cross-coupling reactions.

NATURE COMMUNICATIONS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Shining Visible Light on Reductive Elimination: Acridine-Pd-Catalyzed Cross-Coupling of Aryl Halides with Carboxylic Acids

Naoyuki Toriumi et al.

Summary: This study reports the design of a photosensitizing ligand for single transition-metal catalysis under visible-light irradiation, which has been successfully applied to the cross-coupling reaction of aryl halides with carboxylic acids. The ligand allows the use of different aryl halides and light wavelengths for the reaction. Experimental and theoretical studies reveal that photoinduced electron transfer promotes the reductive elimination reaction in the excited state.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Add to Collection

Article Multidisciplinary Sciences

Pd-catalyzed formal Mizoroki-Heck coupling of unactivated alkyl chlorides

Geun Seok Lee et al.

Summary: The use of alkyl chlorides in Pd-catalyzed Mizoroki-Heck coupling reactions remains a challenging issue due to the high thermodynamic barrier of alkyl chloride activation and the propensity of alkylpalladium complexes to undergo undesired beta-hydride elimination. However, this study demonstrates that alkyl chlorides, including tertiary ones, can efficiently participate in Mizoroki-Heck cross-coupling reactions under mild conditions via photoinduced Pd catalysis, offering great potential for late-stage functionalizations and molecular complexity.

NATURE COMMUNICATIONS (2021)

Add to Collection

Review Chemistry, Physical

Cooperative photoredox and palladium catalysis: recent advances in various functionalization reactions

Maniklal Shee et al.

Summary: The recent resurgence of synergistic palladium and visible-light-induced photoredox catalysis has transformed Pd-catalyzed organic synthesis by enabling unconventional bond formation modes and accessing various elusive reaction pathways under mild conditions. The combination of suitable photocatalysts with active Pd catalysts has been utilized to create efficient dual catalytic systems for cross-coupling reactions, leading to enhancements in reaction rate, conditions, functional group compatibility, and substrate scopes. This Minireview discusses the advances in cooperative catalytic reactions, showcasing their unique mechanistic features and selective examples for substrate scopes.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Oxidative Addition to Palladium(0) Made Easy through Photoexcited-State Metal Catalysis: Experiment and Computation

Rajesh Kancherla et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Decarboxylative Heck-Type Coupling of Activated Aliphatic Carboxylic Acids Enabled by Visible Light

Maximilian Koy et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

Add to Collection

Article Chemistry, Organic

Heck Reaction of Electronically Diverse Tertiary Alkyl Halides

Dania Kurandina et al.

ORGANIC LETTERS (2018)

Add to Collection

Article Chemistry, Organic

Irradiation-Induced Palladium-Catalyzed Decarboxylative Heck Reaction of Aliphatic N-(Acyloxy)phthalimides at Room Temperature

Guang-Zu Wang et al.

ORGANIC LETTERS (2018)

Add to Collection

Article Chemistry, Physical

Synthesis of Pyrazines and Quinoxalines via Acceptorless Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes

Prosenjit Daw et al.

ACS CATALYSIS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Irradiation-Induced Heck Reaction of Unactivated Alkyl Halides at Room Temperature

Guang-Zu Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Visible Light-Induced Room-Temperature Heck Reaction of Functionalized Alkyl Halides with Vinyl Arenes/Heteroarenes

Daria Kurandina et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Photoinduced Formation of Hybrid Aryl Pd-Radical Species Capable of 1,5-HAT: Selective Catalytic Oxidation of Silyl Ethers into Silyl Enol Ethers

Marvin Parasram et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Enantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis

Zhiwei Zuo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Redox-Neutral α-Allylation of Amines by Combining Palladium Catalysis and Visible-Light Photoredox Catalysis

Jun Xuan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Decarboxylative Allylation of Amino Alkanoic Acids and Esters via Dual Catalysis

Simon B. Lang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Room-Temperature C-H Arylation: Merger of Pd-Catalyzed C-H Functionalization and Visible-Light Photocatalysis

Dipannita Kalyani et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Add to Collection

Article Multidisciplinary Sciences

Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis

David A. Nagib et al.

NATURE (2011)

Add to Collection

Article Multidisciplinary Sciences

Discovery of an α-Amino C-H Arylation Reaction Using the Strategy of Accelerated Serendipity

Andrew McNally et al.

SCIENCE (2011)

Add to Collection

Article Multidisciplinary Sciences

Merging photoredox catalysis with organocatalysis: The direct asymmetric alkylation of aldehydes

David A. Nicewicz et al.

SCIENCE (2008)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Photo-activation of Pd-catalyzed Sonogashira coupling using a Ru/bipyridine complex as energy transfer agent

Masahisa Osawa et al.

DALTON TRANSACTIONS (2007)

Add to Collection

Article Chemistry, Multidisciplinary

Photocatalytic hydrogen production from hantzsch 1,4-dihydropyridines by platinum(II) terpyridyl complexes in homogeneous solution

D Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)

Add to Collection

© Peeref 2019-2024. All rights reserved.