4.8 Article

Tailoring grain boundary stability of zinc-titanium alloy for long-lasting aqueous zinc batteries

Related references

Note: Only part of the references are listed.
Article Multidisciplinary Sciences

Constructing robust heterostructured interface for anode-free zinc batteries with ultrahigh capacities

Xinhua Zheng et al.

Summary: The design of a two-dimensional antimony/antimony-zinc alloy heterostructured interface enables dendrite-free Zn deposition with high areal capacity and energy density.

NATURE COMMUNICATIONS (2023)

Editorial Material Chemistry, Physical

A path forward for the translational development of aqueous zinc-ion batteries

Yuan Shang et al.

JOULE (2023)

Article Chemistry, Physical

Investigation on diffusion characteristics and mechanical properties of Ti-Zn system

Yongkang Tan et al.

Summary: A solid-state diffusion technique was used to systematically study the diffusion kinetics of a Ti-Zn binary system in the temperature range of 573-648 K. The number of detected product phases in the diffusion region increased with increasing annealing temperature, resulting in four intermetallic compounds. The diffusion coefficients and activation energies of the intermetallic compounds were estimated, and the mechanical properties were investigated using nanoindentation characterization technology and first-principles calculations.

INTERMETALLICS (2023)

Article Chemistry, Multidisciplinary

A Novel 3D Li/Li9Al4/Li-Mg Alloy Anode for Superior Lithium Metal Batteries

Yijuan Li et al.

Summary: A novel 3D Al/Mg/Li alloy (AM-Li) anode is designed and constructed to improve the surface stability, cycling stability, and rate capability in lithium metal batteries. The optimized AM-Li|AM-Li symmetric cell exhibits low polarization voltage (< 20 mV) and good cycling stability for more than 1600 h. Moreover, the AM-Li|NCM811 full cell shows excellent rate capability and cyclability with a high capacity retention of 90.8% after 100 cycles at 0.5 C.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Physical

Perspective Ten concerns of Zn metal anode for rechargeable aqueous zinc batteries

Xiaoyu Yu et al.

Summary: Based on fair experiments, we propose ten critical concerns on ZMAs, including scientific concepts misunderstanding, non-scientific engineering factors affecting CE assessment, influence mechanisms of coating modifications, and limitations of characterization tools. We not only raise existing dilemmas but also provide solutions. This perspective aims to awaken research status on aqueous zinc batteries and provide constructive guidance for energy storage challenges.

JOULE (2023)

Article Chemistry, Physical

Decoupling, quantifying, and restoring aging-induced Zn-anode losses in rechargeable aqueous zinc batteries

Shengda D. Pu et al.

Summary: Rechargeable aqueous zinc batteries offer low cost, safety, and good cycling capacity, largely due to the water-compatible Zn-metal anode. However, Zn anodes corrode in aqueous electrolytes. This study successfully decouples and quantifies the aging-induced contributions toward anode degradation in mildly acidic aqueous electrolytes, demonstrating that the physical screening effect of evolved gases is the bigger contributor to the efficiency loss of these batteries.

JOULE (2023)

Article Chemistry, Multidisciplinary

Unraveling the Rate-Dependent Stability of Metal Anodes and Its Implication in Designing Cycling Protocol

Zhen Hou et al.

Summary: A high current rate accelerates dendrite formation and reduces the cycle life of metal anodes, but a moderate current rate can actually increase deposition/stripping stability. This anomaly is due to the dual and contradictory roles of high current rates in kinetics and thermodynamics. By controlling the nucleation-growth process, the lifetime of metal deposition/stripping can be significantly increased.

ADVANCED FUNCTIONAL MATERIALS (2022)

Review Chemistry, Multidisciplinary

Design Strategies for High-Energy-Density Aqueous Zinc Batteries

Pengchao Ruan et al.

Summary: This review comprehensively summarizes the rational design strategies of high-energy-density zinc batteries, critically analyzes the positive effects and potential issues of these strategies, and outlines the challenges and perspectives for further development.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Multidisciplinary Sciences

Open challenges and good experimental practices in the research field of aqueous Zn-ion batteries

Giorgia Zampardi et al.

Summary: Aqueous zinc-ion batteries have potential as stationary storage systems for power-grid applications, but certain challenges need to be addressed and experimental practices need to be aligned with industrial working conditions to promote their commercialization.

NATURE COMMUNICATIONS (2022)

Article Chemistry, Multidisciplinary

Toward Hydrogen-Free and Dendrite-Free Aqueous Zinc Batteries: Formation of Zincophilic Protective Layer on Zn Anodes

Lin Hong et al.

Summary: This study successfully addresses the issues of dendrite growth and hydrogen evolution reaction on zinc metal anodes in Zn-ion batteries by developing a uniform and robust metallic Sb protective layer. The modified Zn anodes exhibit excellent cycling stability with dendrite-free and hydrogen-free behaviors.

ADVANCED SCIENCE (2022)

Editorial Material Chemistry, Physical

Soft Shorts Hidden in Zinc Metal Anode Research

Qing Li et al.

JOULE (2022)

Article Multidisciplinary Sciences

Corrosion as the origin of limited lifetime of vanadium oxide-based aqueous zinc ion batteries

Yangmoon Kim et al.

Summary: Aqueous zinc ion batteries are gaining popularity for large-scale energy storage due to their safety, cost, and scalability. However, the limited cyclability and poor calendar life of vanadium oxide-based batteries hinder their practical adoption. This study reveals that the formation of an inactive zinc pyrovanadate phase on the cathode surface is the main cause of limited sustainability and is correlated with the corrosion of the zinc metal anode. By controlling the pH and using an amalgamated zinc anode, the cyclability and lifetime of the batteries can be significantly improved.

NATURE COMMUNICATIONS (2022)

Article Chemistry, Physical

Highly reversible Zn anode with a practical areal capacity enabled by a sustainable electrolyte and superacid interfacial chemistry

Chang Li et al.

Summary: This study introduces a novel additive that effectively solves the issues in aqueous zinc-metal batteries, leading to excellent cycling performance and efficient zinc deposition.

JOULE (2022)

Article Chemistry, Multidisciplinary

Spontaneous Construction of Nucleophilic Carbonyl-Containing Interphase toward Ultrastable Zinc-Metal Anodes

Pinji Wang et al.

Summary: Multifunctional interfacial engineering on the Zn anode, through the spontaneous construction of a carbonyl-containing layer (Zn@ZCO), effectively suppresses dendrite growth, hydrogen evolution, and sluggish kinetics associated with Zn deposition. The Zn@ZCO anode exhibits a long cycling lifespan, dendrite-free surface, and excellent rate performance in aqueous zinc-ion batteries.

ADVANCED MATERIALS (2022)

Article Multidisciplinary Sciences

Three-dimensional Zn-based alloys for dendrite-free aqueous Zn battery in dual-cation electrolytes

Huajun Tian et al.

Summary: Aqueous zinc-ion batteries have received much attention due to their high safety, environmental benignity, and low cost. However, the interface instability issues caused by detrimental side reactions impede their practical applications. In this study, an interface material consisting of a zinc-copper alloy with engineered surfaces is designed to regulate the zinc plating/stripping processes, leading to high-performance aqueous zinc-ion batteries. This work enhances the fundamental understanding of dual-cation intercalation chemistry in aqueous electrochemical systems and provides guidance for exploring high-performance aqueous zinc-ion batteries and beyond.

NATURE COMMUNICATIONS (2022)

Review Chemistry, Physical

Alloying Strategy for High-Performance Zinc Metal Anodes

Ruotong Li et al.

Summary: This article provides a comprehensive review of the application and research progress of zinc alloying strategies in aqueous zinc ion batteries (AZIBs), presenting different improvement mechanisms and discussing potential prospects for further enhancing the alloying of zinc anodes.

ACS ENERGY LETTERS (2022)

Article Multidisciplinary Sciences

Design principles for heterointerfacial alloying kinetics at metallic anodes in rechargeable batteries

Jingxu Zheng et al.

Summary: This study investigates the influence of surface chemistry on the reversibility of electrochemical transformations at rechargeable battery electrodes. The results show that a moderate strength of chemical interaction enables the highest reversibility and stability of the plating/stripping redox processes.

SCIENCE ADVANCES (2022)

Editorial Material Chemistry, Physical

Toward practical aqueous zinc-ion batteries for electrochemical energy storage

Chang Li et al.

Summary: This article introduces researchers from the University of Waterloo and Cornell University, as well as their research areas. Their research primarily focuses on electrolyte systems for zinc-ion batteries, electrochemical reversibility of zinc anodes, and other related fields.

JOULE (2022)

Review Chemistry, Multidisciplinary

Rechargeable Batteries for Grid Scale Energy Storage

Zhengxin Zhu et al.

Summary: This article discusses battery research in the field of energy storage, focusing on the importance of practical application requirements and battery performance matching. By systematically analyzing key parameters, standards and measures for GSES are proposed, and some promising battery technologies for practical applications are explored.

CHEMICAL REVIEWS (2022)

Article Materials Science, Multidisciplinary

Anisotropic response in corrosion behavior of laser powder bed fusion Al-Mn-Mg-Sc-Zr alloy

Zequn Zhang et al.

Summary: Corrosion behavior on both the building plane and building direction plane of LPBF Al-Mn-Mg-Sc-Zr alloy was investigated. Localized corrosion primarily occurred at the molten pool boundaries, where abundant micro-cathode precipitates played a dominant role.

CORROSION SCIENCE (2022)

Article Multidisciplinary Sciences

Self-repairing interphase reconstructed in each cycle for highly reversible aqueous zinc batteries

Wenyao Zhang et al.

Summary: This study reports a highly reversible aqueous zinc battery with a dynamic and self-repairing protective interphase formed by the addition of graphitic carbon nitride quantum dots. The system exhibits single Zn2+ conduction, dendrite-free Zn plating/stripping, and impressive cyclability, making it a promising alternative to lithium batteries in low-cost, large-scale applications.

NATURE COMMUNICATIONS (2022)

Article Multidisciplinary Sciences

Inhibiting intercrystalline reactions of anode with electrolytes for long-cycling lithium batteries

Peng Shi et al.

Summary: This study investigates the impact of grain boundary on the reactions of lithium metal anodes and proposes a heteroatom-concentrated grain boundary as a strategy to inhibit intercrystalline reactions. The scalable preparation of the grain boundary is demonstrated, leading to a significant improvement in the cycling performance of the lithium battery.

SCIENCE ADVANCES (2022)

Article Engineering, Environmental

Manipulating alloying reaction to achieve the stable and dendrite-free zinc metal anodes

Huachao Tao et al.

Summary: The Zn3Hg alloy anode shows excellent cycling stability and low voltage hysteresis by addressing dendrite and corrosion issues of zinc metal anodes. It provides a new development path for constructing stable and dendrite-free zinc metal anodes.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Multidisciplinary

A smelting-rolling strategy for ZnIn bulk phase alloy anodes

Yizhao Chai et al.

Summary: By preparing a ZnIn alloy anode, reversibility and stability of Zn metal in aqueous Zn-ion batteries are achieved. The bulk phase structure of the ZnIn alloy and the evenly dispersed indium nucleation enable stable Zn deposition and prevent further nucleation. This method improves the Zn stripping process and effectively inhibits Zn dendrite growth.

CHEMICAL SCIENCE (2022)

Article Chemistry, Multidisciplinary

Stimulating Cu-Zn alloying for compact Zn metal growth towards high energy aqueous batteries and hybrid supercapacitors

Minhyung Kwon et al.

Summary: This study successfully constructs a stable zinc metal anode by identifying the growth mechanism of densely packed micrometer-sized Zn particles on Cu foil, which contributes to improving the performance of aqueous Zn-ion batteries.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Multidisciplinary

An anticorrosive zinc metal anode with ultra-long cycle life over one year

Ping Xiao et al.

Summary: This study investigates the suppression of hydrogen evolution reaction (HER) on zinc anodes through modification with indium, leading to enhanced performance. The relationship between morphology evolution and HER is studied, and it is found that the modified zinc anodes exhibit an ultra-dense and rock-like plating structure. The cycle life of the modified zinc anodes is significantly improved, and the capacity retention of the full cells is also increased.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Multidisciplinary

Thermodynamics-driven interfacial engineering of alloy-type anode materials

Qizhang Yan et al.

Summary: A thermodynamically driven grain boundary engineering method is used to improve alloy-type anodes by the spontaneous formation of 2D interfacial phases. The addition of 2.8 at% Bi-doped SnSb enhances cycling stability and rate capability, despite the larger size and higher density compared to the undoped SnSb reference sample. The formation of a nanoscale liquid-like interfacial phase and suppressed intergranular cracking contribute to the improved performance.

CELL REPORTS PHYSICAL SCIENCE (2022)

Article Materials Science, Multidisciplinary

Insight into the corrosion behaviour and degradation mechanism of pure zinc in simulated body fluid

Shiyu Huang et al.

Summary: Zn is considered a promising degradable biomaterial, but concerns exist due to unclear degradation mechanism in physiological solutions. The corrosion product film displayed a laminated structure with complex layers, and localized corrosion initiated at grain boundaries affecting degradation rate.

CORROSION SCIENCE (2021)

Article Materials Science, Multidisciplinary

Corrosion behavior of biodegradable metals in two different simulated physiological solutions: Comparison of Mg, Zn and Fe

Hongzhou Dong et al.

Summary: Bio-absorbable metals, such as magnesium, iron, and zinc, show different degradation performance and corrosion rates in simulated body fluid solution and cell culture medium. The influence of electrolyte on corrosion behavior varies among different metals, with corrosion product layers being more uniform in the cell culture medium.

CORROSION SCIENCE (2021)

Article Multidisciplinary Sciences

Stable, high-performance, dendrite-free, seawater-based aqueous batteries

Huajun Tian et al.

Summary: This study proposes a universal strategy to overcome metal anode instability issues in aqueous batteries by designing alloyed materials, using Zn-M alloys as model systems. The results show that Zn-Mn alloy anodes can achieve stability over thousands of cycles even under harsh electrochemical conditions, setting a new milestone for developing durable electrodes for aqueous batteries and beyond.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Multidisciplinary

A Replacement Reaction Enabled Interdigitated Metal/Solid Electrolyte Architecture for Battery Cycling at 20 mA cm-2 and 20 mAh cm-2

Zhao Cai et al.

Summary: Metal anodes are a promising choice for high energy density rechargeable batteries, but face challenges like volume variation and side reactions. A novel interdigitated metal/solid electrolyte composite electrode was fabricated using a replacement reaction, providing a stable host structure and preventing side reactions. This design demonstrated stable electrochemical performance and low overpotential, outperforming other reported metal electrodes.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Materials Science, Multidisciplinary

Enhanced corrosion resistance of Zn-Cu-Ti alloy with addition of Cu-Ti amorphous ribbons in 3.5% NaCl solution

Ya Ni et al.

Summary: In this study, a Zn-0.3Cu-0.3Ti alloy was fabricated using a low-temperature melting method and subjected to corrosion testing in a 3.5% NaCl solution. Comparing samples I and II, it was found that sample I had lower weight gain, corrosion current density, and a higher slope of the cathode polarization curve. Additionally, after 8 days of corrosion, the corrosion products for sample I mainly consisted of Zn-5(OH)(8)Cl·H2O and ZnO, with a loose particle shape. The corrosion layer thickness for sample I increased from about 15 to 24 μm as the corrosion time increased from 2 days to 8 days.

MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION (2021)

Article Multidisciplinary Sciences

Dynamic interphase-mediated assembly for deep cycling metal batteries

Weidong Zhang et al.

Summary: This study presents a method utilizing anisotropic nanostructures to form dynamic interphases in battery electrolytes, achieving ordered assembly of metal electrodeposits and high anode reversibility. The research demonstrates the promotion of vertically aligned and spatially compact zinc electrodeposits with unprecedented reversibility, as well as uniform growth of compact magnesium and aluminum electrodeposits, offering a general pathway toward energy-dense metal batteries based on earth-abundant anode chemistries.

SCIENCE ADVANCES (2021)

Article Chemistry, Multidisciplinary

A highly reversible zinc deposition for flow batteries regulated by critical concentration induced nucleation

Shengnan Wang et al.

Summary: The morphology evolution of Zn deposited in ZFBs is influenced by the concentration of the electrolyte, resulting in dense blocky Zn in concentrated electrolyte and mossy Zn in dilute electrolyte. The dominant crystal plane of Zn also shifts from (002) to (101) with the change in electrolyte concentration. Furthermore, recombination of Zn crystals on the same crystal plane was observed during the experiment. The research proposes an operating critical concentration range and optimized electrolyte utilization rate to maintain high coulombic efficiency and long cycling stability for Zn anodes in electrochemical energy storage devices.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Materials Science, Multidisciplinary

Rechargeable aqueous zinc-ion batteries: Mechanism, design strategies and future perspectives

Huanyan Liu et al.

Summary: Rechargeable aqueous zinc-ion batteries (ZIBs) are considered a promising energy storage solution for grid-scale applications due to their safety, eco-friendliness, and cost-effectiveness. Despite significant progress in developing efficient cathodes, anodes, and electrolytes, the understanding of ZIBs and their energy storage mechanisms is still in its early stages and requires further investigation for practical implementation. This review provides a comprehensive summary of the development of ZIBs, design strategies, challenges, and opportunities for practical viability.

MATERIALS TODAY (2021)

Article Chemistry, Multidisciplinary

A progressive nucleation mechanism enables stable zinc stripping-plating behavior

Yihu Li et al.

Summary: This study demonstrates a new nucleation mechanism in aqueous zinc-ion batteries by introducing high-valence cations into the electrolyte to regulate zinc deposition behavior, resulting in more stable and long-lasting cycling performance. The effects of cation adsorption on zinc nucleation are deeply explored, leading to higher capacity retention and longer cycling life compared to additive-free electrolytes.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Review Chemistry, Multidisciplinary

Interfacial Design of Dendrite-Free Zinc Anodes for Aqueous Zinc-Ion Batteries

Qi Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Physical

The Current State of Aqueous Zn-Based Rechargeable Batteries

Ya-Ping Deng et al.

ACS ENERGY LETTERS (2020)

Article Energy & Fuels

Realizing high zinc reversibility in rechargeable batteries

Lin Ma et al.

NATURE ENERGY (2020)

Review Chemistry, Multidisciplinary

Dendrites in Zn-Based Batteries

Qi Yang et al.

ADVANCED MATERIALS (2020)

Review Chemistry, Multidisciplinary

Materials chemistry for rechargeable zinc-ion batteries

Ning Zhang et al.

CHEMICAL SOCIETY REVIEWS (2020)

Article Chemistry, Physical

Nanoscale Active Sites for the Hydrogen Evolution Reaction on Low Carbon Steel

L. C. Yule et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2019)

Article Chemistry, Multidisciplinary

Nanoscale Nucleation and Growth of Electrodeposited Lithium Metal

Allen Pei et al.

NANO LETTERS (2017)

Article Materials Science, Multidisciplinary

Corrosion of Zinc as a Function of pH

S. Thomas et al.

CORROSION (2012)

Article Chemistry, Multidisciplinary

ELECTROCHEMICAL STUDY ABOUT ZINC ELECTRODEPOSITION ONTO GCE AND HOPG SUBSTRATES

Madai Granados-Neri et al.

QUIMICA NOVA (2011)

Editorial Material Chemistry, Physical

Ti-Zn (titanium-zinc)

H. Okamoto

JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION (2008)

Article Chemistry, Physical

Large scale hydrothermal synthesis and electrochemistry of ammonium vanadium bronze nanobelts

Kai-Feng Zhang et al.

JOURNAL OF POWER SOURCES (2006)