Cobalt and holmium co-doped nickel ferrite nanoparticles: synthesis, characterization and photocatalytic application studies

Herein, nickel ferrite-based photocatalysts with enhanced light utilizing electrical charge transport properties have been reported for environmental remediation applications. The cobalt and holmium co-doped nickel ferrite [Ni1-x(Co) x Fe2-y(Ho) y O4] nanoparticles and bare nickel ferrite (NiFe2O4) nanoparticles have been prepared via surfactant-supported wet-chemical techniques. The as-prepared ferritic photocatalyst's structural, morphological, and light harvesting features have been examined in detail using well-known physical, electronic, and optical methods. The co-doped ferrite photocatalyst's tuned structural features enable it to absorb maximum wavelengths from the U.V. and visible regions. This is because the co-doped Ni1-x(Co) x Fe2-y(Ho) y O4 optical band gap is 1.73 eV; hence, the wavelength from the visible part possesses sufficient energies to trigger the electronic excitation in co-doped ferrite photocatalysts. Moreover, the co-doping-induced structural defects in the ferrite photocatalyst. These defects act as a reservoir for the charge species, mainly electrons, so the process of charge recombination is almost hampered for the Ni1-x(Co) x Fe2-y(Ho) y O4 photocatalyst. In application terms, the photomineralization capabilities of doped and bare ferrite photocatalysts have been explored using crystal violet (CV) dye. The comparative photocatalytic evaluation of both nickel ferrite-based photocatalysts shows that co-doped ferrite degraded 96.02 % of CV dye. In comparison, the undoped one only degraded 64.84 % after 80 min of W-lamp light exposure. The results demonstrated that the Ho and Co co-doped ferrite photocatalyst exhibits excellent photocatalytic activity, suggesting its potential for environmental remediation applications in textile industrial discharges.

Automated summary

This study reports nickel ferrite-based photocatalysts with enhanced light utilizing electrical charge transport properties. The co-doping of cobalt and holmium in the nickel ferrite nanoparticles enables the absorption of maximum wavelengths from the UV and visible regions, leading to improved photocatalytic activity. The co-doped ferrite photocatalyst also contains structural defects that act as reservoirs for charge species, preventing charge recombination and enhancing the degradation of crystal violet dye.