Bisphenols and phthalates in Australian wastewater: A statistical approach for estimating contributions from diffuse and point sources

Chemicals associated with plastics, such as bisphenols and phthalates, enter sewerage from both diffuse (domestic/commercial) and point (industrial) sources. In this study, we aimed to devise a conservative, statistical baseline to estimate contributions from these source types when sampling of specific sources is not possible. Population-normalised mass loads of two bisphenols and nine phthalates were estimated in wastewater samples from 22 sewage treatment plants (STPs) in 2019. Two multiday (10 and 7 day) pools were created for each STP. Baseline (diffuse) release thresholds were set at the mean of the first quartile (Q1) plus 10 times the standard deviation (STDV) of this quartile [Q1 mean + (10 x STDV)], with contributions over this considered to come from point sources. Chemicals with at least one population-normalised mass load more than three times their baseline were classified as point-source dominant and the remaining as diffuse-source dominant. Eleven of the twelve chemicals examined were detected above limits of quantification in all wastewater samples. Bisphenol A (BPA), bisphenol S (BPS), di-isononyl phthalate (DiNP) and di-methyl phthalate (DMP) were classified as point-source dominant chemicals. The total annual mass loads entering STPs across Australia were estimated to be 4.2 tonnes/ year from diffuse sources and 4.5 tonnes/year from point sources for bisphenols, and 47 tonnes/year from diffuse sources and 5.9 tonnes/year from point sources for phthalates.

Automated summary

This study aimed to estimate the contributions of diffuse and point sources of chemicals associated with plastics in wastewater. A conservative baseline was devised to classify the chemicals as point-source dominant or diffuse-source dominant when specific sampling was not possible. The results showed that bisphenol A, bisphenol S, di-isononyl phthalate, and di-methyl phthalate were dominant point-source chemicals, while phthalates were dominant diffuse-source chemicals. The estimated annual mass loads of these chemicals in wastewater treatment plants demonstrated the significant contributions from both diffuse and point sources.