4.3 Article

Electrochemical oxidative transamidation of tertiary amines with N-acyl imides to access amide compounds

Journal

SYNTHETIC COMMUNICATIONS
Volume 53, Issue 17, Pages 1412-1425

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2023.2228947

Keywords

C-N bond cleavage; amides; electrooxidation; N-acyl imides; tertiary amines; transamidation

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This article describes a novel and efficient electrochemical oxidative transamidation of tertiary amines with N-acyl imides. The protocol is environmentally friendly and easy to handle, as tertiary amines are used as surrogates for secondary amines. The C-N bond of tertiary amines is cleaved, preparing amide compounds in a facile approach with 29 examples in yields ranging from 11% to 80%.
A novel and efficient electrochemical oxidative transamidation of tertiary amines with N-acyl imides is described. This protocol is environmentally friendly and ease to handle as tertiary amines are used as surrogates for secondary amines. The C-N bond of tertiary amines is cleaved, preparing amide compounds in a facile approach with 29 examples in 11-80% yields.

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