4.5 Article

Superconducting properties of new hexagonal and noncentrosymmetric cubic high entropy alloys

Journal

SUPERCONDUCTOR SCIENCE & TECHNOLOGY
Volume 36, Issue 11, Pages -

Publisher

IOP Publishing Ltd
DOI: 10.1088/1361-6668/acfac5

Keywords

high entropy alloy; superconductivity; noncentrosymmetric superconductor

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Superconducting high-entropy alloys (HEAs) are a newly burgeoning field of unconventional superconductors. In this study, we have synthesized and investigated the superconducting characteristics of two new transition elements based HEAs. The results confirm bulk type-II superconductivity in both alloys, and specific heat analysis supports the Bardeen-Cooper-Schrieffer explanation for the observed low-temperature behavior.
Superconducting high-entropy alloys (HEAs) are a newly burgeoning field of unconventional superconductors and raise intriguing questions about the presence of superconductivity in highly disordered systems, which lack regular phonon modes. In our study, we have synthesized and investigated the superconducting characteristics of two new transition elements based HEAs Re0.35Os0.35Mo0.10W0.10Zr0.10 crystallizing in noncentrosymmetric alpha-Mn structure, and Ru0.35Os0.35Mo0.10W0.10Zr0.10 crystallizing in hexagonal closed-packed structure (hcp). Due to its high hardness, transition-metal-based hexagonal hcp HEA is rare and highly desirable for practical applications. Bulk magnetization, resistivity, and specific heat measurements confirmed bulk type-II superconductivity in both alloys. Specific heat analysis up to the measured low-temperature range suffices for a Bardeen-Cooper-Schrieffer explanation.

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