4.6 Article

Green auto-combustion synthesis and characterization of TmVO4 nanostructures in the presence carbohydrate sugars and their application as Visible-light photocatalyst

Journal

SOLAR ENERGY
Volume 258, Issue -, Pages 372-382

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.solener.2023.04.030

Keywords

Visible-light photocatalyst; TmVO4 nanostructures; Water pollution; Auto-combustion; Natural fuels

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In order to improve the photocatalytic efficiency, researchers successfully prepared thulium vanadate (TmVO4) nanostructures by simplifying the preparation process. Multiple factors such as saccharides, calcination temperature, and molar ratio were considered, and various dyes and concentrations were studied to enhance catalyst performance. The results showed that TmVO4 could degrade 83.5% of methyl violet (MV) within 90 minutes and remained stable in the recycle test.
The development of photocatalysts with adequate functions, particularly in the visible range, is one of the most significant issues facing scientists since they are essential compounds for the protection of the environment. A primary objective of this work was to simplify the preparation of thulium vanadate (TmVO4) nanostructures in order to improve their photocatalytic efficiency. By using a facile auto-combustion route, this study presents a new method for fabricating TmVO4 nanostructures. In order to achieve the desired size and homogeneity of the products, multiple factors were considered. As part of these parameters, several saccharides, such as glucose, fructose, lactose, maltose, and cellulose are analyzed for the first time, as well as the calcination temperature and the molar ratio. Various dye types and dye concentrations were studied to enhance catalyst performance. According to the catalyst activity, TmVO4 was able to degrade 83.5% of the methyl violet (MV) after 90 min. TmVO4 was found to be stable in the recycle test, with an efficiency reduction of 14.6% after five cycles.

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