Journal
SMALL
Volume -, Issue -, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.202305048
Keywords
fast diffusion; neutron scattering; soft phonons; superionic argyrodites; thermoelectrics
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The coexistence of rigid and mobile sublattices in superionic Argyrodites leads to low thermal conductivity and high electrical and ionic conductivities, making it attractive for various applications. However, the understanding of the underlying lattice and diffusive dynamics in terms of the interaction between phonons and mobile ions is still incomplete. In this study, inelastic neutron scattering and molecular dynamics simulations are used to reveal that phonon softening triggers fast diffusion of Ag ions in superionic Argyrodite Ag8GeSe6. This study demonstrates the microscopic connection between soft phonons and mobile ions and provides insights into the intertwined lattice and diffusive dynamics in superionic materials.
The structural coexistence of dual rigid and mobile sublattices in superionic Argyrodites yields ultralow lattice thermal conductivity along with decent electrical and ionic conductivities and therefore attracts intense interest for batteries, fuel cells, and thermoelectric applications. However, a comprehensive understanding of their underlying lattice and diffusive dynamics in terms of the interplay between phonons and mobile ions is missing. Herein, inelastic neutron scattering is employed to unravel that phonon softening on heating to T-c & AP; 350 K triggers fast Ag diffusion in the canonical superionic Argyrodite Ag8GeSe6. Ab initio molecular dynamics simulations reproduce the experimental neutron scattering signals and identify the partially ultrafast Ag diffusion with a large diffusion coefficient of 10(-4) cm(-2) s(-1). The study illustrates the microscopic interconnection between soft phonons and mobile ions and provides a paradigm for an intertwined interaction of the lattice and diffusive dynamics in superionic materials.
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