Hofmann-Type Cyanide Bridged Coordination Polymers for Advanced Functional Nanomaterials

Since the discovery of Hofmann clathrates of inorganic cyanide bridged coordination polymers (Hofmann-type CN-CPs), extensive research is done to understand their behavior during spin transitions caused by guest molecules or external stimuli. Lately, research on their nanoscale architectures for sensors and switching devices is of interest. Their potential is reported for producing advanced functional inorganic materials in two-dimensional (2D) morphology using a scalable solid-state thermal treatment method. For instance, but not restricted to, alloys, carbides, chalcogenides, oxides, etc. Simultaneously, their in situ crystallization at graphene oxide (GO) nanosheet surfaces, followed by a subsequent self-assembly to build layered lamellar structures, is reported providing hybrid materials with a variety of uses. Hence, an overview of the most recent developments is presented here in the synthesis of nanoscale structures, including thin films and powders, using Hofmann-type CN-CPs. Also thoroughly demonstrated are the most recent synthetic ideas with the modest control over the size and shape of nanoscale particles. Additionally, in order to create new functional hybrid materials for electrical and energy applications, their thermal decomposition in various environments and hybridization with GO and other guest molecules is examined. This review article also conveyed their spin transition, astounding innovative versatile adhesives, and structure features. The most recent developments in the synthesis of functional nanomaterials are reviewed using Hofmann-type CN-CPs. The synthetic techniques of their powders and thin films are thoroughly demonstrated. Their thermal degradation in various environments to produce nanostructured inorganic materials is studied, as well as their hybridization with carbon and other guest molecules. Finally, their adaptive adhesion, structural and spin transition features are conveyed.image

Automated summary

Hofmann-type CN-CPs have the potential to produce functional nanomaterials with nanoscale structures and various functionalities through thermal decomposition and hybridization with other substances. This article reviews the recent developments in this field, including synthesis techniques, properties of nanomaterials, and their potential applications in electrical and energy fields.