Sulphur-bearing species in the coma of comet 67P/Churyumov-Gerasimenko

Several sulphur-bearing species have already been observed in different families of comets. However, the knowledge on the minor sulphur species is still limited. The comet's sulphur inventory is closely linked to the pre-solar cloud and holds important clues to the degree of reprocessing of the material in the solar nebula and during comet accretion. Sulphur in pre-solar clouds is highly depleted, which is quite puzzling as the S/O ratio in the diffuse interstellar medium is cosmic. This work focuses on the abundance of the previously known species H2S, OCS, SO, S-2, SO2 and CS2 in the coma of comet 67P/Churyumov-Gerasimenko measured by Rosetta Orbiter Spectrometer for Ion and Neutral Analysis/Double Focusing Mass Spectrometer between equinox and perihelion 2015. Furthermore, we present the first detection of S-3, S-4, CH3SH and C2H6S in a comet, and we determine the elemental abundance of S/O in the bulk ice of (1.47 +/- 0.05) x 10(-2). We show that SO is present in the coma originating from the nucleus, but not CS in the case of 67P, and for the first time establish that S-2 is present in a volatile and a refractory phase. The derived total elemental sulphur abundance of 67P is in agreement with solar photospheric elemental abundances and shows no sulphur depletion as reported for dense interstellar clouds. Also the presence of S-2 at heliocentric distances larger than 3 au indicates that sulphur-bearing species have been processed by radiolysis in the pre-solar cloud and that at least some of the ice from this cloud has survived in comets up the present.