☆ 4.8 Article

Highly Conductive Covalent-Organic Framework Films

SMALL (2023)

Related references

Note: Only part of the references are listed.

Article Chemistry, Multidisciplinary

Antiaromatic Covalent Organic Frameworks Based on Dibenzopentalenes

Josefine Sprachmann et al.

Summary: Despite being unstable, 4n pi systems have gained attention for their unique optical and electronic properties. The first antiaromatic framework materials were synthesized and a series of highly crystalline and porous COFs based on DBP were obtained. These antiaromatic COFs show potential applications in positive electrode materials for Li-organic batteries and exhibit photoconductivity upon visible light irradiation.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Add to Collection

Article Chemistry, Multidisciplinary

Janus Dione-Based Conjugated Covalent Organic Frameworks with High Conductivity as Superior Cathode Materials

Xiaoyi Xu et al.

Summary: In this study, a new kind of Janus dione-based COF was developed, which is fully sp2 carbon-conjugated through the connection by olefin units. These COFs exhibit high stability and possess well-ordered two-dimensional crystalline structures, excellent porosity, high conductivity, and abundant redox-active carbonyl units. They show great potential as high-performance cathode materials in lithium-ion batteries, with TFPPy-ICTO-COF achieving a record capacity of 338 mAh g-1 at a discharge rate of 0.1 C and demonstrating excellent stability with 100% capacity retention after 1000 cycles.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Add to Collection

Review Chemistry, Multidisciplinary

Macrocycle-Based Covalent Organic Frameworks

Yufei Yuan et al.

Summary: Macrocycles can be effectively utilized by incorporating them into covalent organic frameworks (COFs), overcoming the aggregation issue and enabling their unique activities in various fields such as catalysis, adsorption, optoelectronics, phototherapy, and structural design.

ADVANCED MATERIALS (2023)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Exploration of metal organic frameworks and covalent organic frameworks for energy-related applications

Rahim Shah et al.

Summary: Metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs) have attracted significant attention as highly crystalline advanced permeable materials with large surface area, ordered pores/channels, and controllable structure. However, their low structural stability and electrical conductivities limit their applications in photocatalysis and energy storage/conversion. Extensive research has focused on maximizing their advantages and overcoming these limitations. This review article provides a background and timeline of COF/MOF development, discusses synthetic procedures, recent achievements, and milestones in CO2 reduction, hydrogen production, lithium-ion batteries, and supercapacitors, and explores the challenges and future prospects for high-performance COF/MOF materials in photocatalysis and electrochemical energy storage.

COORDINATION CHEMISTRY REVIEWS (2023)

Add to Collection

Article Chemistry, Physical

Single-Atom Catalysts on Covalent Organic Frameworks for CO2 Reduction

Rui Wang et al.

Summary: The article discusses the solution to the long-unresolved issue of CO2 release and atmospheric change through the application of effective catalysts. It focuses on COF-based SACs, which are promising due to their stability, porosity, and designability. The synthesis methods, pros and cons, and factors influencing the catalytic performance of COF-based SACs are explored, with the aim of designing superior COF-based SACs.

ACS MATERIALS AU (2023)

Add to Collection

Article Chemistry, Physical

Band-like Transport of Charge Carriers in Oriented Two-Dimensional Conjugated Covalent Organic Frameworks

Samrat Ghosh et al.

Summary: This study developed crystalline pi-conjugated covalent organic frameworks (COFs) and demonstrated their potential in terms of conductivity and photoresponsivity, providing new active materials for multifunctional organic electronics.

CHEMISTRY OF MATERIALS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Piperazine-Linked Covalent Organic Frameworks with High Electrical Conductivity

Yan Yue et al.

Summary: A new kind of piperazine-linked covalent organic framework (COF) was successfully synthesized through nucleophilic substitution reaction. The COF exhibits excellent chemical stability and permanent porosity, and possesses high conductivity and carrier mobility.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Add to Collection

Article Engineering, Environmental

Ladder-type π-conjugated metallophthalocyanine covalent organic frameworks with boosted oxygen reduction reaction activity and durability for zinc-air batteries

Zhen Zhang et al.

Summary: pi-Conjugated two-dimensional covalent organic frameworks (COFs) have emerged as promising oxygen electrocatalysts due to their controllable architectures, excellent electrical conductivity, and highly exposed molecular active sites. In this study, a novel ladder type pi-conjugated two-dimensional benzoimidazobenzophenanthroline-linked iron-phthalocyanine COF (FePc-BBL COF) was synthesized and exhibited exceptional oxygen reduction reaction (ORR) activity and kinetics. The FePc-BBL COF showed a remarkable half-wave potential and a low Tafel slope in alkaline media. Additionally, it demonstrated a high turnover frequency and mass activity, surpassing the performance of Pt/C. When applied as a cathode electrocatalyst for zinc-air batteries, the FePc-BBL COF displayed superior power density, specific capacity, and long-term durability compared to Pt/C. This work provides a promising strategy for designing stable and efficient electrocatalysts for sustainable energy conversion and storage devices.

CHEMICAL ENGINEERING JOURNAL (2022)

Add to Collection

Article Multidisciplinary Sciences

Two-dimensional covalent organic framework films prepared on various substrates through vapor induced conversion

Minghui Liu et al.

Summary: This study reports the synthesis of large-area two-dimensional (2D) COF films with controllable thicknesses via vapor-induced conversion. The reversible Schiff base polycondensation reaction results in the formation of a uniform organic framework film directly on the growth substrate. Wafer-scale 2D COF films with different structures have been successfully synthesized by adjusting their building blocks.

NATURE COMMUNICATIONS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Oriented Thiophene-Extended Benzotrithiophene Covalent Organic Framework Thin Films: Directional Electrical Conductivity

Laura Frey et al.

Summary: In this study, covalent organic frameworks (COFs) based on a novel thiophene-extended benzotrithiophene (BTT) building block were successfully synthesized, showing high surface areas and in-plane electrical conductivity. The charge transport mechanism and directionality were investigated using techniques such as electrical conductivity measurements and conductive atomic force microscopy.

ADVANCED FUNCTIONAL MATERIALS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Light-Switchable and Self-Healable Polymer Electrolytes Based on Dynamic Diarylethene and Metal-Ion Coordination

Hui Nie et al.

Summary: Self-healing polymer electrolytes with light-switchable conductivity were developed using dynamic N-donor ligand-containing diarylethene (DAE) and multivalent Ni2+ metal-ion coordination. These electrolytes exhibit fast exchange kinetics and self-healing capabilities under mild conditions. Controllable binding strength of the polymer can be achieved through irradiation, leading to resistance modulation and recovery in solid films.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Free-Standing Covalent Organic Framework Membrane for High-Efficiency Salinity Gradient Energy Conversion

Shuhua Hou et al.

Summary: This study achieved efficient salinity gradient energy conversion by preparing a covalent organic framework membrane with high ion conductivity and selectivity.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Chemically Stable Polyarylether-Based Metallophthalocyanine Frameworks with High Carrier Mobilities for Capacitive Energy Storage

Chongqing Yang et al.

Summary: This study reports the synthesis of COFs with efficient charge transport and chemical stability, as well as the growth of thin films on various substrates. The thin films exhibit excellent semiconducting properties and significant increases in conductivity. Additionally, density functional theory calculations reveal the anisotropic nature of carrier transport in the framework.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Crystallizing Sub 10 nm Covalent Organic Framework Thin Films via Interfacial-Residual Concomitance

Ashok Kumar Mahato et al.

Summary: Using the residual crystallization (RC) method along with interfacial crystallization (IC) as a rate-controlling tool, and two different crystallization pathways - fiber-to-film (F-F) and sphere-to-film (S-F), high surface area, crystallinity, and conductivity COF thin films have been successfully synthesized.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Two-Dimensional Covalent Organic Frameworks with Cobalt(II)-Phthalocyanine Sites for Efficient Electrocatalytic Carbon Dioxide Reduction

Bin Han et al.

Summary: The study presents the design and synthesis of two-dimensional polyimide-linked phthalocyanine COFs with stable properties, showing potential applications in electrocatalysis.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

A Highly Conductive All-Carbon Linked 3D Covalent Organic Framework Film

Yizhou Yang et al.

Summary: An all-carbon linked 3D covalent organic framework is synthesized using a templated surface reaction in continuous flow, resulting in ultrasmooth films with high electrical conductivity and significant crystallinity, setting a new record for 3D COF materials. The combination of 3D nanosized channels and high conductivity opens up possibilities for various unexplored applications.

SMALL (2021)

Add to Collection

Article Chemistry, Analytical

Preparation and Research of Monolayer WS2 FETs Encapsulated by h-BN Material

Tao Han et al.

Summary: Functional devices utilizing vertical van der Waals heterostructure materials can combine the properties of single component materials effectively. Synthesis and characterization of WS2/h-BN vertical vdWs heterostructure materials are conducted using various methods and techniques to explore their electrical transmission properties. FET devices fabricated on this material are tested for their electrical performance, providing insights for electronic device applications using vdWs heterostructure materials.

MICROMACHINES (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Construction of Donor-Acceptor Heterojunctions in Covalent Organic Framework for Enhanced CO2 Electroreduction

Qiao Wu et al.

Summary: The TT-Por(Co)-COF, containing donor-acceptor heterojunctions, exhibits enhanced performance in electrocatalytic reduction of carbon dioxide to produce CO, thanks to its improved charge transfer capability and large amount of accessible active sites. This study demonstrates that integrating donor-acceptor heterojunctions in COFs can facilitate electron transfer and generate high current densities for CO2RR.

SMALL (2021)

Add to Collection

Article Chemistry, Multidisciplinary

A Two-Dimensional Poly(azatriangulene) Covalent Organic Framework with Semiconducting and Paramagnetic States

Vellanki Lakshmi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

A Stable and Conductive Metallophthalocyanine Framework for Electrocatalytic Carbon Dioxide Reduction in Water

Ning Huang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Article Chemistry, Multidisciplinary

High-Mobility Semiconducting Two-Dimensional Conjugated Covalent Organic Frameworks with p-Type Doping

Mingchao Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Donor-acceptor covalent organic frameworks of nickel(II) porphyrin for selective and efficient CO2 reduction into CO

Nanfeng Xu et al.

DALTON TRANSACTIONS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Two-Dimensional Chemiresistive Covalent Organic Framework with High Intrinsic Conductivity

Zheng Meng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Add to Collection

Article Multidisciplinary Sciences

Two-dimensional semiconducting covalent organic frameworks via condensation at arylmethyl carbon atoms

Shuai Bi et al.

NATURE COMMUNICATIONS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Semiconducting 2D Triazine-Cored Covalent Organic Frameworks with Unsubstituted Olefin Linkages

Shice Wei et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Unveiling Electronic Properties in Metal-Phthalocyanine-Based Pyrazine-Linked Conjugated Two-Dimensional Covalent Organic Frameworks

Mingchao Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Design and synthesis of two-dimensional covalent organic frameworks with four-arm cores: prediction of remarkable ambipolar charge-transport properties

Simil Thomas et al.

MATERIALS HORIZONS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Reticular Electronic Tuning of Porphyrin Active Sites in Covalent Organic Frameworks for Electrocatalytic Carbon Dioxide Reduction

Christian S. Diercks et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Porous Field-Effect Transistors Based on a Semiconductive Metal-Organic Framework

Guodong Wu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Add to Collection

Article Multidisciplinary Sciences

Two-dimensional sp2 carbon-conjugated covalent organic frameworks

Enquan Jin et al.

SCIENCE (2017)

Add to Collection

Article Chemistry, Physical

Oriented Covalent Organic Framework Film on Graphene for Robust Ambipolar Vertical Organic Field-Effect Transistor

Bing Sun et al.

CHEMISTRY OF MATERIALS (2017)

Add to Collection

Article Nanoscience & Nanotechnology

High Conductive Two-Dimensional Covalent Organic Framework for Lithium Storage with Large Capacity

Hui Yang et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

Add to Collection

Article Chemistry, Physical

A 2D porous porphyrin-based covalent organic framework for sulfur storage in lithium sulfur batteries

Huaping Liao et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Tunable electrical conductivity in oriented thin films of tetrathiafulvalene-based covalent organic framework

Song-Liang Cai et al.

CHEMICAL SCIENCE (2014)

Add to Collection

Article Chemistry, Multidisciplinary

High-Rate Charge-Carrier Transport in Porphyrin Covalent Organic Frameworks: Switching from Hole to Electron to Ambipolar Conduction

Xiao Feng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Add to Collection

Article Chemistry, Physical

Covalent Organic Frameworks with High Charge Carrier Mobility

Shun Wan et al.

CHEMISTRY OF MATERIALS (2011)

Add to Collection

Article Chemistry, Multidisciplinary

An n-Channel Two-Dimensional Covalent Organic Framework

Xuesong Ding et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Add to Collection

Article Chemistry, Multidisciplinary

A Belt-Shaped, Blue Luminescent, and Semiconducting Covalent Organic Framework

Shun Wan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Add to Collection

Article Materials Science, Multidisciplinary

Oxidation energies of transition metal oxides within the GGA+U framework

Lei Wang et al.

PHYSICAL REVIEW B (2006)

Add to Collection

Article Crystallography

First principles methods using CASTEP

SJ Clark et al.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE (2005)

Add to Collection

© Peeref 2019-2024. All rights reserved.