Journal
SEPARATION AND PURIFICATION TECHNOLOGY
Volume 323, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.seppur.2023.124484
Keywords
Triphenylimidazolium salts; Porous organic polymers; CO 2 cycloaddition reaction; Epoxides; Friedel-Crafts alkylation reaction
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Novel triazine-linked triphenylimidazole (TPIM) and triphenylimidazolium (TPIM-IL) monomers were synthesized and used to form PTPIM and PTPIM-IL networks via Friedel-Crafts alkylation reaction. The resulting networks exhibited high specific surface areas and PTPIM network could be easily transformed into PTPIM-IL network through post-modification. PTPIM-IL network showed high CO2 uptake capacity and excellent catalytic activity for the cycloaddition of CO2 to epoxides.
In this work, novel triazine-linked triphenylimidazole (TPIM) and triphenylimidazolium (TPIM-IL) monomers have been synthesized and fully characterized. Subsequently, their corresponding networks, namely PTPIM and PTPIM-IL, respectively, have been synthesized by Friedel-Crafts alkylation reaction. Owing to the dendritic-like, bulky and rigid structure of the two monomers, the resultant PTPIM and PTPIM-IL networks display relatively high specific surface areas of 982 m2/g and 570 m2/g, respectively. More importantly, PTPIM network can be readily transformed into PTPIM-IL network via a facile post-modification process. The presence of abundant CO2affinity sites, i.e., imidazolium and triazine rings, together with high nucleophilicity of iodine anion endows PTPIM-IL network with not only high CO2 uptake capacity (2.69 mmol g-1), but also high activity toward the cycloaddition of CO2 to epoxides. For example, PTPIM-IL network has proven very effective in converting epibromohydrin to its corresponding cyclic carbonate under mild conditions (60 degrees C, 0.1 MPa), yielding quantitative conversion (99%) and selectivity (99%). The catalytic activity of PTPIM-IL network is superior to most previously reported imidazolium-based heterogeneous catalysts.
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