4.7 Article

Pt/SnO2-Pd nanoelectrode applied for hydrogen sensor with zero-power consumption and low detection limit

Journal

SENSORS AND ACTUATORS B-CHEMICAL
Volume 388, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2023.133848

Keywords

Hydrogen sensor; Nanoelectrode; Zero-power consumption; DFT calculation; High selectivity

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In this study, Pt/SnO2-Pd nanomaterial was prepared as a nanoelectrode for a fuel cell-type hydrogen sensor with zero power consumption. The results showed that this sensor has high selectivity and sensitivity to H2 gas, with an unprecedented low detection limit of 1 ppm, and is not affected by humidity.
The detection of low-concentration hydrogen at room temperature is still a challenge, which contributes to taking precautions as soon as possible when hydrogen leaks. In this study, we prepared Pt/SnO2-Pd nanomaterial as nanoelectrode applied for a fuel cell-type hydrogen sensor with zero power consumption. The sensing results show that such fuel cell-type H2 gas sensor has high selectivity and good sensitivity to H2 gas, with an un-precedented low detection limit of 1 ppm, and the humidity has little impact on the sensor's performance. Based on DFT calculations, the low adsorption energy and the electron transfer interaction between Pd and H promote the adsorption and dissociation processes of H2 molecules, which lead to the hydrogen oxidation reaction ac-celeration and shorter times of response and recovery. In addition, this Pt/SnO2-Pd based sensor has also ad-vantages of high selectivity and zero-power consumption, which may provide a broad application prospect for fuel cell vehicles and voltage transformers, etc.

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