Human and natural impacts on the US freshwater salinization and alkalinization: A machine learning approach

Ongoing salinization and alkalinization in U.S. rivers have been attributed to inputs of road salt and effects of human-accelerated weathering in previous studies. Salinization poses a severe threat to human and ecosystem health, while human derived alkalinization implies increasing uncertainty in the dynamics of terrestrial sequestration of atmo-spheric carbon dioxide. A mechanistic understanding of whether and how human activities accelerate weathering and contribute to the geochemical changes in U.S. rivers is lacking. To address this uncertainty, we compiled dissolved sodium (salinity proxy) and alkalinity values along with 32 watershed properties ranging from hydrology, climate, geomorphology, geology, soil chemistry, land use, and land cover for 226 river monitoring sites across the coterminous U.S. Using these data, we built two machine-learning models to predict monthly-aggregated sodium and alkalinity fluxes at these sites. The sodium-prediction model detected human activities (represented by population density and impervious surface area) as major contributors to the salinity of U.S. rivers. In contrast, the alkalinity-prediction model identified natural processes as predominantly contributing to variation in riverine alkalinity flux, including run-off, carbonate sediment or siliciclastic sediment, soil pH and soil moisture. Unlike prior studies, our analysis suggests that the alkalinization in U.S. rivers is largely governed by local climatic and hydrogeological conditions.

Automated summary

Ongoing salinization and alkalinization in U.S. rivers are mainly caused by inputs of road salt and natural processes, respectively. Human activities, represented by population density and impervious surface area, contribute significantly to the salinity of U.S. rivers. On the other hand, the alkalinization in U.S. rivers is predominantly influenced by local climatic and hydrogeological conditions, as well as various natural processes such as run-off and sediment composition.