Journal
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
Volume 97, Issue 7, Pages 1438-1444Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036024423070221
Keywords
cyclic voltammetry; cathode reduction; peroxide; tetraoxane
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The behavior of a smooth gold electrode in aqueous solutions of the potassium salt of bridging 1,2,4,5-tetraoxane containing a biperoxide cyclic fragment was studied using cyclic voltammetry. The cathode process involving four electrons was analyzed in detail. The products of electrolysis of the potassium salt were studied, and a reaction mechanism was proposed.
The behavior of a smooth gold electrode in aqueous solutions of the potassium salt of bridging 1,2,4,5-tetraoxane containing a biperoxide cyclic fragment was studied by cyclic voltammetry. The cathode process was analyzed in detail. It was shown that the process involves four electrons. The products of electrolysis of the potassium salt were studied, and a reaction mechanism was proposed.
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