Journal
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
Volume 49, Issue 6, Pages 338-344Publisher
PLEIADES PUBLISHING INC
DOI: 10.1134/S1070328423600171
Keywords
boron cluster anions; XRD; aqua complexes; acetonitrile
Categories
Ask authors/readers for more resources
The complexation of nickel(II) with the closo-decaborate anion in water and acetonitrile has been studied. Complexes [Ni(solv)(6)][B10H10] (solv = H2O (I) or CH3CN (II)) have been isolated and characterized by elemental analysis and IR spectroscopy. Complex [Ni(CH3CN)(5)(H2O)](0.75)[Ni(CH3CN)(4)(H2O)(2)](0.25)[B10H10]& BULL;0.5H(2)O (III) has been isolated from an acetonitrile-water system and its structure has been solved by X-ray diffraction (XRD) (CIF file CCDC no. 2224702). A mechanism of ligand metathesis in the complexation of nickel(II) has been proposed.
Nickel(II) complexation with the closo-decaborate anion in water and acetonitrile is studied. Complexes [Ni(solv)(6)][B10H10] (solv = H2O (I) or CH3CN (II)) are isolated. The complexes are characterized by elemental analysis and IR spectroscopy. Complex [Ni(CH3CN)(5)(H2O)](0.75)[Ni(CH3CN)(4)(H2O)(2)](0.25)[B10H10]& BULL;0.5H(2)O (III) is isolated from an acetonitrile-water system. The structure of complex III is solved by X-ray diffraction (XRD) (CIF file CCDC no. 2224702). A mechanism of ligand metathesis in the complexation of nickel(II) is proposed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available