4.1 Article

Fluorescent sensor for Zn2+ cations based on a 4-methoxy-1,8-naphthalimide derivative containing a dipicolylamine receptor fragment

Journal

RUSSIAN CHEMICAL BULLETIN
Volume 72, Issue 9, Pages 2154-2161

Publisher

SPRINGER
DOI: 10.1007/s11172-023-4011-y

Keywords

1,8-naphthalimide; sensor; zinc cation; fluorescence; photoinduced electron transfer

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This article describes the synthesis and characterization of a previously unknown fluorescent sensor for zinc cations, which demonstrates fluorescence enhancement upon complexation with Zn2+ due to the formation of ligand-metal complexes with a composition of 1:1.
A previously undescribed fluorescent sensor for zinc cations based on a 4-methoxynaphthalimide fluorophore and a receptor fragment represented by a dipicolylamine derivative was synthesized, and its spectral and luminescent properties were studied. The resulting fluorescent sensor demonstrated fluorescence enhancement upon complexation with Zn2+ cations due to the formation of ligand-metal complexes with a composition of 1: 1, in which the electron transfer process is suppressed.

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