Journal
MOLECULES
Volume 21, Issue 1, Pages -Publisher
MDPI
DOI: 10.3390/molecules21010117
Keywords
metathesis; NHC ligands; stereogenic centers; ruthenium catalysts
Funding
- Ministero dell'Universita e della Ricerca Scientifica e Tecnologica
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The catalytic properties of olefin metathesis ruthenium complexes bearing N-heterocyclic carbene ligands with stereogenic centers on the backbone are described. Differences in catalytic behavior depending on the backbone configurations of symmetrical and unsymmetrical NHCs are discussed. In addition, an overview on asymmetric olefin metathesis promoted by chiral catalysts bearing C-2-symmetric and C-1-symmetric NHCs is provided.
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