Journal
MOLECULES
Volume 21, Issue 7, Pages -Publisher
MDPI
DOI: 10.3390/molecules21070878
Keywords
radical chemistry; Smiles rearrangement; domino reactions; radical cascade; heterocycle
Funding
- Region Champagne-Ardenne
- CNRS
- University of Reims
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Over the decades the Smiles rearrangement and its variants have become essential synthetic tools in modern synthetic organic chemistry. In this mini-review we summarized some very recent results of the radical version of these rearrangements. The selected examples illustrate the synthetic power of this approach, especially if it is incorporated into a domino process, for the preparation of polyfunctionalized complex molecules.
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