Journal
CHEMICAL ENGINEERING JOURNAL
Volume 279, Issue -, Pages 639-647Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2015.05.049
Keywords
Schiff based ligand; Nano-composite adsorbent (NCA); Copper(II) ions; Optical capturing; Wastewater treatment
Categories
Funding
- Japan Society for the Promotion of Science [24860070]
- Deanship of Scientific Research at King Saud University [RGP-VPP-130]
Ask authors/readers for more resources
A novel Schiff base ligand based nano-composite adsorbent (NCA) was prepared for the detection and removal of copper (Cu(II)) ions in wastewater samples. Upon the addition of Cu(II) ions to NCA at optimum conditions, the clear color was visible to the naked-eye in the detection system. This NCA exhibited an obvious color change from yellowish to dark green in the presence of Cu(II) ions in aqueous solution. The limit of detection was found to be 0.16 mu g/L by optical detection. The NCA could detect the Cu(II) ions over other foreign ions with high sensitivity and selectivity. For adsorption behavior, influences several factors such as solution pH, contact time, concentration for Cu(II) ion adsorption was investigated by batch experiment in detail. The results showed that neutral solution pH was suitable to get optimum Cu(II) ions adsorption. Also an extending contact time was favorable for improving adsorption efficiency. The adsorption process of Cu(II) ions by the NCA was followed the Langmuir adsorption isotherm model. The maximum adsorption capacity of Cu(II) ions by the NCA from the Langmuir isotherm model was 173.62 mg/g. The mesoporous NCA exhibited higher adsorption capacity compared with some other reported diverse materials. In the multi-component system, the competing ions did not significantly interfere in the adsorption of Cu(II) ions. The adsorbed Cu(II) ions was effectively eluted with 0.25 M HCl and remain the almost same functionality for many cycles use. Even in seven consecutive cycles, the NCA showed great potential in the optical Cu(II) ions removal from wastewater. Then the proposed NCA could be used a promising adsorbent for the clean-up of Cu(II) ions in wastewater treatment. (C) 2015 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available